(3+3)-Annulation of Carbonyl Ylides with Donor-Acceptor Cyclopropanes: Synergistic Dirhodium(II) and Lewis Acid Catalysis

Lewis Acid Catalyzed Stereoselective Dearomative Coupling of Indolylboron Ate Complexes with Donor-Acceptor Cyclopropanes and Alkyl Halides

(2018) Saikat Das et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

(3+3)-Annulation of Donor-Acceptor Cyclopropanes with Diaziridines

(2018) Alexey O. Chagarovskiy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Expeditious Route to trans -Configured Tetrahydrothiophenes Enabled by Fe(OTf)3 -Catalyzed [3+2] Cycloaddition of Donor-Acceptor Cyclopropanes with Thionoesters

(2018) Yohei Matsumoto et al.   CHEMISTRY-A EUROPEAN JOURNAL

Formal Insertion of Thioketenes into Donor–Acceptor Cyclopropanes by Lewis Acid Catalysis

(2018) André U. Augustin et al.   ORGANIC LETTERS

Kinetic Studies of Donor-Acceptor Cyclopropanes: Is Reactivity Predictably Related to Structural and Electronic Properties?

(2018) Daniel B. Werz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ionic Ga-Complexes of Alkylidene- and Arylmethylidenemalonates and Their Reactions with Acetylenes: An In-Depth Look into the Mechanism of the Occurring Gallium Chemistry

(2018) Roman A. Novikov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of 2-Unsubstituted Pyrrolidines and Piperidines from Donor–Acceptor Cyclopropanes and Cyclobutanes: 1,3,5-Triazinanes as Surrogates for Formylimines

(2017) Lennart K. B. Garve et al.   JOURNAL OF ORGANIC CHEMISTRY

[4 + 2] Annulation of Donor–Acceptor Cyclopropanes with Acetylenes Using 1,2-Zwitterionic Reactivity

(2017) Roman A. Novikov et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Three-Step Synthesis of Homo-β-proline: A Donor–Acceptor Cyclopropane as Key Intermediate

(2017) Ludwig K. A. Pilsl et al.   ORGANIC LETTERS

Application of oxygen/nitrogen substituted donor-acceptor cyclopropanes in the total synthesis of natural products

(2017) Santosh J. Gharpure et al.   TETRAHEDRON LETTERS

Dearomatization of electron poor six-membered N-heterocycles through [3 + 2] annulation with aminocyclopropanes

(2017) Johannes Preindl et al.   Chemical Science

Bimetallic catalysis for C–C and C–X coupling reactions

(2017) Dominic R. Pye et al.   Chemical Science

Collective Approach to Advancing C–H Functionalization

(2017) Huw M. L. Davies et al.   ACS Central Science

Dirhodium(II)-Catalyzed Annulation of Enoldiazoacetamides with α-Diazoketones: An Efficient and Highly Selective Approach to Fused and Bridged Ring Systems

(2016) Qing-Qing Cheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Ring Opening/Cyclization/Retro-Mannich Reaction of Cyclopropyl Ketones with Aryl 1,2-Diamines for the Synthesis of Benzimidazole Derivatives

(2016) Yong Xia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lewis Acid Catalyzed Selective Reactions of Donor-Acceptor Cyclopropanes with 2-Naphthols

(2016) Trinadh Kaicharla et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Temporary Generation of a Cyclopropyl Oxocarbenium Ion Enables Highly Diastereoselective Donor-Acceptor Cyclopropane Cycloaddition

(2016) Juliette Sabbatani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold carbenes, gold-stabilized carbocations, and cationic intermediates relevant to gold-catalysed enyne cycloaddition

(2016) R. J. Harris et al.   CHEMICAL SOCIETY REVIEWS

Divergent Reactivity of Thioalkynes in Lewis Acid Catalyzed Annulations with Donor-Acceptor Cyclopropanes

(2016) Sophie Racine et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ring-Opening Regio-, Diastereo-, and Enantioselective 1,3-Chlorochalcogenation of Cyclopropyl Carbaldehydes

(2016) Jan Wallbaum et al.   CHEMISTRY-A EUROPEAN JOURNAL

Multicomponent 1,3-Bifunctionalization of Donor–Acceptor Cyclopropanes with Arenes and Nitrosoarenes

(2016) Saikat Das et al.   ORGANIC LETTERS

[3 + 3]-Cycloaddition of Donor–Acceptor Cyclopropanes with Nitrile Imines Generated in Situ: Access to Tetrahydropyridazines

(2016) Lennart K. B. Garve et al.   ORGANIC LETTERS

Rh-Catalyzed Intermolecular Reactions of α-Alkyl-α-Diazo Carbonyl Compounds with Selectivity over β-Hydride Migration

(2015) Andrew DeAngelis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Modern Organic Synthesis with α-Diazocarbonyl Compounds

(2015) Alan Ford et al.   CHEMICAL REVIEWS

Recent Advances of Catalytic Asymmetric 1,3-Dipolar Cycloadditions

(2015) Takuya Hashimoto et al.   CHEMICAL REVIEWS

Ring Opening of Donor-Acceptor Cyclopropanes with the Azide Ion: A Tool for Construction of N-Heterocycles

(2015) Konstantin L. Ivanov et al.   CHEMISTRY-A EUROPEAN JOURNAL

Lewis Acid Catalyzed Annulation of Donor–Acceptor Cyclopropane and N-Tosylaziridinedicarboxylate: One-Step Synthesis of Functionalized 2H-Furo[2,3-c]pyrroles

(2015) Asit Ghosh et al.   JOURNAL OF ORGANIC CHEMISTRY

Asymmetric Annulation of Donor–Acceptor Cyclopropanes with Dienes

(2015) Hao Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dimerization of donor–acceptor cyclopropanes

(2015) Roman A. Novikov et al.   MENDELEEV COMMUNICATIONS

Chemoselective Intramolecular Carbonyl Ylide Formation through Electronically Differentiated Malonate Diesters

(2015) Mina C. Nakhla et al.   ORGANIC LETTERS

Late-stage C–H functionalization of complex alkaloids and drug molecules via intermolecular rhodium-carbenoid insertion

(2015) Jing He et al.   Nature Communications

Asymmetric Synthesis of 2,3-Dihydropyrroles by Ring-Opening/Cyclization of Cyclopropyl Ketones Using Primary Amines

(2014) Yong Xia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A New Golden Age for Donor-Acceptor Cyclopropanes

(2014) Tobias F. Schneider et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reactions of metallocarbenes derived from N-sulfonyl-1,2,3-triazoles

(2014) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

Ring-Opening 1,3-Dichlorination of Donor–Acceptor Cyclopropanes by Iodobenzene Dichloride

(2014) Lennart K. B. Garve et al.   ORGANIC LETTERS

TiCl4 Promoted Formal [3 + 3] Cycloaddition of Cyclopropane 1,1-Diesters with Azides: Synthesis of Highly Functionalized Triazinines and Azetidines

(2014) Huan-Huan Zhang et al.   ORGANIC LETTERS

Donor–Acceptor Substituted Cyclopropane to Butanolide and Butenolide Natural Products: Enantiospecific First Total Synthesis of (+)-Hydroxyancepsenolide

(2014) Santosh J. Gharpure et al.   ORGANIC LETTERS

Regio- and Diastereoselective Nickel-Catalyzed Cycloaddition of Activated Cyclopropanes with Allenes

(2014) Takuya Kurahashi et al.   SYNLETT

Highly stereoselective synthesis of cyclopentanes bearing four stereocentres by a rhodium carbene-initiated domino sequence

(2014) Brendan T Parr et al.   Nature Communications

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

(2013) Christopher K. Prier et al.   CHEMICAL REVIEWS

Intramolecular donor–acceptor cyclopropane ring-opening cyclizations

(2013) Marchello A. Cavitt et al.   CHEMICAL SOCIETY REVIEWS

Lewis Acids Promoted Formal Intramolecular [3 + 2] Parallel and Cross-Cycloadditions of Cyclopropane 1,1-Diesters with Allenes

(2013) Zhenjun Wang et al.   ORGANIC LETTERS

Donor-Substituted Nitrocyclopropanes: Immediate Ring-Enlargement to Cyclic Nitronates

(2013) Christian D. Schmidt et al.   ORGANIC LETTERS

Catalytic Enantiospecific [3+2] Annulation of Aminocyclopropanes with Ketones

(2012) Fides Benfatti et al.   CHEMISTRY-A EUROPEAN JOURNAL

Tandem Ring-Opening Decarboxylation of Cyclopropane Hemimalonates with Sodium Azide: A Short Route to γ-Aminobutyric Acid Esters

(2012) Michael R. Emmett et al.   JOURNAL OF ORGANIC CHEMISTRY

Side-Arm-Promoted Highly Enantioselective Ring-Opening Reactions and Kinetic Resolution of Donor–Acceptor Cyclopropanes with Amines

(2012) You-Yun Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synergistic catalysis: A powerful synthetic strategy for new reaction development

(2012) Anna E. Allen et al.   Chemical Science

Cyclopropyl Iminium Activation: Reactivity Umpolung in Enantioselective Organocatalytic Reaction Design

(2011) Christof Sparr et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Intermolecular Cycloaddition of Diazodiketoester-Derived Carbonyl Ylides with Indoles Using Chiral Dirhodium(II) Carboxylates

(2011) Naoyuki Shimada et al.   ORGANIC LETTERS

Cyclopropane−Aldehyde Annulations at Quaternary Donor Sites: Stereoselective Access to Highly Substituted Tetrahydrofurans

(2011) Austin G. Smith et al.   ORGANIC LETTERS

Heterocycles from cyclopropanes: applications in natural product synthesis

(2009) Cheryl A. Carson et al.   CHEMICAL SOCIETY REVIEWS

Catalytic Enantioselective Synthesis of Tetrahydrofurans: A Dynamic Kinetic Asymmetric [3 + 2] Cycloaddition of Racemic Cyclopropanes and Aldehydes

(2009) Andrew T. Parsons et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Influence of Solvent on Carbene Intersystem Crossing Rates

(2008) Jin Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Scope and Mechanism for Lewis Acid-Catalyzed Cycloadditions of Aldehydes and Donor−Acceptor Cyclopropanes: Evidence for a Stereospecific Intimate Ion Pair Pathway

(2008) Patrick D. Pohlhaus et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY