期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 80, 期 14, 页码 7235-7242出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b00705
关键词
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资金
- Department of Science and Technology, New Delhi [SR/FT/CS-84/2010]
- IIT Ropar
- CSIR, New Delhi
An efficient MgI2-catalyzed annulation between donor-acceptor cyclopropane and N-tosylaziridinedicarboxylate to access highly substituted 2H-furo[2,3-c]pyrrole bearing two rings and four stereocenters, including one quaternary carbon stereocenter, has been developed. This methodology can be used for the synthesis of biologically active compounds like IKM-159. This work also offers an insight into the mechanism of the annulation process.
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