Catalytic Enantioselective Intramolecular C(sp3 )−H Amination of 2-Azidoacetamides

Manganese-catalysed benzylic C(sp3)–H amination for late-stage functionalization

(2018) Joseph R. Clark et al.   Nature Chemistry

Selective formation of γ-lactams via C–H amidation enabled by tailored iridium catalysts

(2018) Seung Youn Hong et al.   SCIENCE

N-Heterocyclic Carbene Iron(III) Porphyrin-Catalyzed Intramolecular C(sp3 )-H Amination of Alkyl Azides

(2018) Ka-Pan Shing et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Octahedral Ruthenium Complex with Exclusive Metal-Centered Chirality for Highly Effective Asymmetric Catalysis

(2017) Yu Zheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemoselective, Enzymatic C–H Bond Amination Catalyzed by a Cytochrome P450 Containing an Ir(Me)-PIX Cofactor

(2017) Paweł Dydio et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Synthesis of N-Heterocycles via Direct C(sp3)–H Amination Using an Air-Stable Iron(III) Species with a Redox-Active Ligand

(2017) Bidraha Bagh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective, intermolecular benzylic C–H amination catalysed by an engineered iron-haem enzyme

(2017) Christopher K. Prier et al.   Nature Chemistry

Ruthenium Bisammine Complex and Its Reaction with Aryl Azides

(2017) Jin Yong Park et al.   ORGANOMETALLICS

Catalytic C–H amination at its limits: challenges and solutions

(2017) Damien Hazelard et al.   Organic Chemistry Frontiers

Catalytic transformation of esters of 1,2-azido alcohols into α-amido ketones

(2016) Yongjin Kim et al.   CHEMICAL COMMUNICATIONS

Mild metal-catalyzed C–H activation: examples and concepts

(2016) T. Gensch et al.   CHEMICAL SOCIETY REVIEWS

Expanding the family of bis-cyclometalated chiral-at-metal rhodium(iii) catalysts with a benzothiazole derivative

(2016) Jiajia Ma et al.   DALTON TRANSACTIONS

Robust and Porous β-Diketiminate-Functionalized Metal–Organic Frameworks for Earth-Abundant-Metal-Catalyzed C–H Amination and Hydrogenation

(2016) Nathan C. Thacker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Enamides by Ruthenium-Catalyzed Reaction of Alkyl Azides with Acid Anhydrides in Ionic Liquid

(2015) Han Kyu Pak et al.   ChemCatChem

Organic azides: “energetic reagents” for the intermolecular amination of C–H bonds

(2014) Daniela Intrieri et al.   CHEMICAL COMMUNICATIONS

Asymmetric Nitrene Transfer Reactions: Sulfimidation, Aziridination and C-H Amination Using Azide Compounds as Nitrene Precursors

(2014) Tatsuya Uchida et al.   CHEMICAL RECORD

Ligand-Controlled, Tunable Silver-Catalyzed C–H Amination

(2014) Juliet M. Alderson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular Redox-Active Ligand-to-Substrate Single-Electron Transfer: Radical Reactivity with a Palladium(II) Complex

(2014) Daniël L. J. Broere et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric photoredox transition-metal catalysis activated by visible light

(2014) Haohua Huo et al.   NATURE

P450-Catalyzed Intramolecular sp3 C–H Amination with Arylsulfonyl Azide Substrates

(2014) Ritesh Singh et al.   ACS Catalysis

Enantioselective Intramolecular CH Amination Catalyzed by Engineered Cytochrome P450 Enzymes In Vitro and In Vivo

(2013) John A. McIntosh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantio- and Regioselective Intermolecular Benzylic and Allylic CH Bond Amination

(2013) Yota Nishioka et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A 4-coordinate Ru(ii) imido: unusual geometry, synthesis, and reactivity

(2013) Amrendra K. Singh et al.   CHEMICAL COMMUNICATIONS

Hydrogen-bond mediated regio- and enantioselectivity in a C–H amination reaction catalysed by a supramolecular Rh(ii) complex

(2013) Thorsten Höke et al.   CHEMICAL COMMUNICATIONS

Group 5 Imides and Bis(imide)s as Selective Hydrogenation Catalysts

(2013) Thomas L. Gianetti et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Complex N-Heterocycle Synthesis via Iron-Catalyzed, Direct C-H Bond Amination

(2013) E. T. Hennessy et al.   SCIENCE

Recent development of direct asymmetric functionalization of inert C–H bonds

(2013) Chao Zheng et al.   RSC Advances

Metal-Catalyzed Nitrogen-Atom Transfer Methods for the Oxidation of Aliphatic C–H Bonds

(2012) Jennifer L. Roizen et al.   ACCOUNTS OF CHEMICAL RESEARCH

Characterization and Utility of N-Unsubstituted Imines Synthesized from Alkyl Azides by Ruthenium Catalysis

(2012) Jin Hee Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nitrene Chemistry in Organic Synthesis: Still in Its Infancy?

(2012) Geoffroy Dequirez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective Radical Amination of Electron-Deficient C(sp3)–H Bonds by Co(II)-Based Metalloradical Catalysis: Direct Synthesis of α-Amino Acid Derivatives via α-C–H Amination

(2012) Hongjian Lu et al.   ORGANIC LETTERS

Enantioselective Intramolecular Benzylic CH Bond Amination: Efficient Synthesis of Optically Active Benzosultams

(2011) Masami Ichinose et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective functionalisation of saturated C–H bonds with metalloporphyrin catalysts

(2011) Chi-Ming Che et al.   CHEMICAL SOCIETY REVIEWS

Catalytic C–H amination: the stereoselectivity issue

(2011) Florence Collet et al.   CHEMICAL SOCIETY REVIEWS

A Diruthenium Catalyst for Selective, Intramolecular Allylic C–H Amination: Reaction Development and Mechanistic Insight Gained through Experiment and Theory

(2011) Mark Edwin Harvey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Beyond Click-Chemistry: Transformation of Azides with Cyclopentadienyl Ruthenium Complexes

(2011) Julie Risse et al.   ORGANOMETALLICS

Studies in catalytic C–H amination involving nitrene C–H insertion

(2010) Florence Collet et al.   DALTON TRANSACTIONS

Catalytic C–H amination: recent progress and future directions

(2009) Florence Collet et al.   CHEMICAL COMMUNICATIONS

TERMINAL NITRIDO AND IMIDO COMPLEXES OF THE LATE TRANSITION METALS

(2009) John F. Berry   COMMENTS ON INORGANIC CHEMISTRY

Preparation of imine complexes of ruthenium and osmium stabilised by [MCl(η 6-p-cymene)(PR3)]+ fragments

(2009) Gabriele Albertin et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Enantioselective CH Amination Using Cationic Ruthenium(II)-pybox Catalysts

(2008) Erika Milczek et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Chiral Rhodium Carboxamidate Catalyst for Enantioselective C−H Amination

(2008) David N. Zalatan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Merging Photoredox Catalysis with Organocatalysis: The Direct Asymmetric Alkylation of Aldehydes

(2008) D. A. Nicewicz et al.   SCIENCE

A mechanistic analysis of the Rh-catalyzed intramolecular C–H amination reaction

(2008) Kristin Williams Fiori et al.   TETRAHEDRON