Synthesis of Chiral Olefin Ligands and their Application in Asymmetric Catalysis

Expanding the C1-Symmetric Bicyclo[2.2.1]heptadiene Ligand Family: Highly Enantioselective Synthesis of Cyclic β-Aryl-Substituted Carbonyl Compounds

(2012) Chia-Chen Liu et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Asymmetric Allylic Alkylation of Pyrroles and 4,7-Dihydroindoles with Alkene–Phosphine Ligands

(2012) Yilin Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to Nitroalkenes Using Olefin–Sulfoxide Ligands

(2012) Feng Xue et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed Asymmetric Formal Cycloadditions of Racemic Butadiene Monoxide with Imines

(2012) Zhaoqun Liu et al.   ORGANIC LETTERS

Enantioselective Rh(I)-Catalyzed Cyclization of Arylboron Compounds onto Ketones

(2012) Darryl W. Low et al.   ORGANIC LETTERS

Rh(I)-Catalyzed Asymmetric 1,2-Addition to α-Diketones with Chiral Sulfur–Alkene Hybrid Ligands

(2012) Xiangqing Feng et al.   ORGANIC LETTERS

Chiral sulfoxide–olefin ligands: tunable stereoselectivity in Rh-catalyzed asymmetric 1,4-additions

(2012) Guihua Chen et al.   TETRAHEDRON

Catalytic Asymmetric Intramolecular Hydroacylation with Rhodium/Phosphoramidite-Alkene Ligand Complexes

(2011) Thomas J. Hoffman et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed, Highly Enantioselective 1,2-Addition of Aryl Boronic Acids to α-Ketoesters and α-Diketones Using Simple, Chiral Sulfur-Olefin Ligands

(2011) Ting-Shun Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Sulfoxide-Olefin Ligands: Completely Switchable Stereoselectivity in Rhodium-Catalyzed Asymmetric Conjugate Additions

(2011) Guihua Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Rhodium-Catalyzed Allylic CH Activation for the Addition to Conjugated Dienes

(2011) Qian Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Design of N-sulfinyl homoallylic amines as novel sulfinamide-olefin hybrid ligands for asymmetric catalysis: application in Rh-catalyzed enantioselective 1,4-additions

(2011) Shen-Shuang Jin et al.   CHEMICAL COMMUNICATIONS

Design and synthesis of new chiral phosphorus–olefin bidentate ligands and their use in the rhodium-catalyzed asymmetric addition of organoboroxines to N-sulfonyl imines

(2011) Ryo Shintani et al.   CHEMICAL COMMUNICATIONS

Highly Enantioselective Rhodium-Catalyzed Asymmetric 1,4-Addition Reactions of Arylboronic Acids to Acyclic α,β-Unsaturated Compounds: The Formal Synthesis of (−)-Indatraline

(2011) Wei-Ting Wei et al.   CHEMISTRY-A EUROPEAN JOURNAL

Pd-Catalyzed Asymmetric Allylic Etherizations with Oximes by Chiral Alkene-Phosphine Ligands

(2011) Ziping Cao et al.   JOURNAL OF ORGANIC CHEMISTRY

A Class of Benzene Backbone-Based Olefin–Sulfoxide Ligands for Rh-Catalyzed Enantioselective Addition of Arylboronic Acids to Enones

(2011) Feng Xue et al.   JOURNAL OF ORGANIC CHEMISTRY

Chiral Allene-Containing Phosphines in Asymmetric Catalysis

(2011) Feng Cai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly effective chiral phosphorus amidite–olefin ligands for palladium-catalyzed asymmetric allylic substitutions

(2011) Zhaoqun Liu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Chiral N-tert-butanesulfinyl α,β-unsaturated ketimine: a simple and highly effective olefin/sulfinimide hybrid ligand for asymmetric 1,4-additions

(2011) Xiangqing Feng et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Design of N-cinnamyl sulfinamides as new sulfur-containing olefin ligands for asymmetric catalysis: achieving structural simplicity with a categorical linear framework

(2011) Shen-Shuang Jin et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Kinetic Resolution of Hindered Morita–Baylis–Hillman Adducts by Rh(I)-Catalyzed Asymmetric 1,4-Addition/β-Hydroxyelimination

(2011) Yazhou Wang et al.   ORGANIC LETTERS

Readily Accessible Chiral Diene Ligands for Rh-Catalyzed Enantioselective Conjugate Additions of Boronic Acids

(2011) Barry M. Trost et al.   ORGANIC LETTERS

α,β-Divinyl Tetrahydropyrroles as Chiral Chain Diene Ligands in Rhodium(I)-Catalyzed Enantioselective Conjugated Additions

(2011) Qian Li et al.   ORGANIC LETTERS

SimpleN-Sulfinyl-Based Chiral Sulfur–Olefin Ligands for Rhodium-Catalyzed Asymmetric 1,4-Additions

(2011) Xiangqing Feng et al.   ORGANIC LETTERS

Sulfoxide–Alkene Hybrids: A New Class of Chiral Ligands for the Hayashi–Miyaura Reaction

(2011) Tobias Thaler et al.   ORGANIC LETTERS

Design of Chiral Sulfoxide–Olefins as a New Class of Sulfur-Based Olefin Ligands for Asymmetric Catalysis

(2011) Wei-Yi Qi et al.   ORGANIC LETTERS

Pd-Catalyzed Asymmetric Allylic Alkylation of Indoles and Pyrroles by Chiral Alkene-Phosphine Ligands

(2011) Ziping Cao et al.   ORGANIC LETTERS

Indole-olefin-oxazoline (IndOlefOx)-ligands: synthesis and utilization in asymmetric Rh-catalyzed conjugate addition

(2011) Noora Kuuloja et al.   TETRAHEDRON-ASYMMETRY

Rhodium-Catalyzed Asymmetric Arylation

(2011) Ping Tian et al.   ACS Catalysis

One Step Synthesis of Chiral OlefinsviaAsymmetric Diamination and their Applications as Ligands for Rhodium(I)-Catalyzed 1,4-Additions

(2010) Xichao Hu et al.   ADVANCED SYNTHESIS & CATALYSIS

Chemoenzymatic Synthesis and Application of Bicyclo[2.2.2]octadiene Ligands: Increased Efficiency in Rhodium-Catalyzed Asymmetric Conjugate Additions by Electronic Tuning

(2010) Yunfei Luo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Applications oftert-Butanesulfinamide

(2010) MaryAnn T. Robak et al.   CHEMICAL REVIEWS

Synthetic and Mechanistic Studies on Pd(0)-Catalyzed Diamination of Conjugated Dienes

(2010) Baoguo Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Rhodium-Catalyzed Addition of Arylboronic Acids to Alkenylheteroarenes

(2010) Graham Pattison et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Development of Binaphthyl-Based Chiral Dienes for Rhodium(I)-Catalyzed Asymmetric Arylation ofN,N-Dimethylsulfamoyl-Protected Aldimines

(2010) Ziping Cao et al.   ORGANIC LETTERS

C1-Symmetric Dicyclopentadienes as New Chiral Diene Ligands for Asymmetric Rhodium-Catalyzed Arylation ofN-Tosylarylimines

(2010) Cheng Shao et al.   ORGANIC LETTERS

Vicinal-Diamine-Based Chiral Chain Dienes as Ligands for Rhodium(I)-Catalyzed Highly Enantioselective Conjugated Additions

(2010) Yazhou Wang et al.   ORGANIC LETTERS

Development of Chiral Terminal-Alkene−Phosphine Hybrid Ligands for Palladium-Catalyzed Asymmetric Allylic Substitutions

(2010) Zhaoqun Liu et al.   ORGANIC LETTERS

Olefin-Oxazolines (OlefOx): Highly Modular, Easily Tunable Ligands for Asymmetric Catalysis

(2009) Björn T. Hahn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Isatin derivatives, a novel class of transthyretin fibrillogenesis inhibitors

(2009) Asensio González et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

tert-Butanesulfinimines: structure, synthesis and synthetic applications

(2009) Franck Ferreira et al.   CHEMICAL SOCIETY REVIEWS

Rhodium-Catalyzed Formation of Stereocontrolled Trisubstituted Alkenes from Baylis-Hillman Adducts

(2009) Thomas Gendrineau et al.   CHEMISTRY-A EUROPEAN JOURNAL

Simple Chiral Chain Dienes as Ligands for Rh(I)-Catalyzed Conjugated Additions

(2009) Xichao Hu et al.   ORGANIC LETTERS

Novel, Efficient Alkene-Phosphinite Hybrid Ligand Based ond-Glucose

(2009) Tobias Minuth et al.   ORGANIC LETTERS

Rhodium-Catalyzed Functionalization of Sterically Hindered Alkenes

(2009) Thomas Gendrineau et al.   ORGANIC LETTERS

Catalytic Enantioselective Formation of Chiral-Bridged Dienes Which Are Themselves Ligands for Enantioselective Catalysis

(2009) M. Kevin Brown et al.   ORGANIC LETTERS

A Palladium-Catalyzed Dehydrogenative Diamination of Terminal Olefins

(2008) Bin Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Rhodium-Catalyzed Addition of Arylboronic Acids to α-Ketoesters

(2008) Hai-Feng Duan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Olefins as Steering Ligands in Asymmetric Catalysis

(2008) Christian Defieber et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Tetrafluorobenzobarrelenes as Highly Efficient Ligands for the Rhodium-catalyzed Asymmetric 1,4-Addition of Arylboronic Acids

(2008) Takahiro Nishimura et al.   CHEMISTRY LETTERS

Catalytic Asymmetric Allylic and Homoallylic Diamination of Terminal Olefins via Formal C−H Activation

(2008) Haifeng Du et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Simple Chiral Diene Ligands Provide High Enantioselectivities in Transition-Metal-Catalyzed Conjugate Addition Reactions

(2008) Kazuhiro Okamoto et al.   ORGANIC LETTERS

More than Bystanders: The Effect of Olefins on Transition-Metal-Catalyzed Cross-Coupling Reactions

(2007) Jeffrey B. Johnson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION