4.6 Article

Perovskite La1-xSrxFe1-yMnyO3 hollow nanospheres: Synthesis and application in catalytic hydrogen peroxide decomposition

期刊

MATERIALS LETTERS
卷 111, 期 -, 页码 89-92

出版社

ELSEVIER SCIENCE BV
DOI: 10.1016/j.matlet.2013.08.083

关键词

La1-xSrxFe1-yMnyO3; Hollow nanosphere; Hydrogen peroxide; Microstructure; Nanoparticles

资金

  1. Natural Science Foundation of China [21106143, 21076211]

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Perovskite-type LaFeO3 and La1-xSrxFe1-yMnyO3 hollow nanospheres were prepared, for the first time, via a urea-assisted one-pot solvothermal method. The chemical compositions, crystalline phases, specific surface areas and morphologies of the materials as-prepared were characterized by ICP-OES, XRD, nitrogen adsorption and TEM, respectively. It was found that the presence of urea greatly decreased the nucleation temperature which led to the smaller particle sizes of products. As a potential application, the materials as-prepared exhibited superior activity and good stability in the catalytic decomposition of hydrogen peroxide. The excellent activity of La1-xSrxFe1-yMnyO3 hollow nanospheres can be rationalized by their high specific surface areas and hollow nanoparticle morphology. The high stability of these materials can be attributed to their perovskite-type crystal structures. (C) 2013 Elsevier B.V. All rights reserved.

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