Article
Chemistry, Applied
Huijing Chen, Fuquan Chen, Qiong Xiao, Menghao Cai, Qiuming Yang, Huifen Weng, Anfeng Xiao
Summary: The novel amphiphilic agar modified with octenyl succinic anhydride (OSAR) showed higher transparency and freeze-thaw stability, as well as improved emulsion stability and oil loading capacity compared to native agar (NA). With DS values of 0.06 and 0.12, OSAR exhibited increased gel transparency and decreased syneresis, lower interface tension and average molecular weight, decreased thermal stability, enhanced gel springiness, more liquid-like properties with low gel strength, and lower turbidity and melting temperatures than NA.
CARBOHYDRATE POLYMERS
(2021)
Article
Biochemistry & Molecular Biology
Gordana Gojgic-Cvijovic, Dragica Jakovljevic, Ljiljana Zivkovic, Vladan Cosovic, Vladimir Pavlovic, Ivana Nikolic, Nikola Maravic, Ljubica Dokic
Summary: In this study, levan from Bacillus licheniformis NS032 was modified with octenyl succinic anhydride (OSA) in an aqueous medium, and the properties of the resulting derivatives were investigated. The optimum conditions for the synthesis reaction were found to be 40 degrees C and a polysaccharide slurry concentration of 30%. The derivatives with degrees of substitution of 0.025 and 0.036 exhibited retained porous structure and better colloidal stability compared to the native polysaccharide. These OSA-modified levans have the potential to be used in new formulations of emulsion-based systems.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Polymer Science
Wei Zhang, Bei Cheng, Jiahui Li, Zaixi Shu, Pingping Wang, Xuefeng Zeng
Summary: The esterification of high-amylose Japonica rice starch with octenyl succinic anhydride (OSA) improved its functional properties, including decreased relative crystallinity, increased pasting viscosity, swelling power, emulsifying stability, and resistant starch (RS) content. The OSA-modified high-amylose starch could be used as an emulsifier, thickener, and fat replacer in food systems.
Article
Biochemistry & Molecular Biology
Wei Gao, Jie Sui, Pengfei Liu, Bo Cui, A. M. Abd El-Aty
Summary: The synthetic mechanism of octenyl succinic anhydride (OSA) modified corn starch (OSCS) and granule shells (OSCs) based on shells separation pretreatment (SSP) was investigated in this study. The SSP process resulted in higher degree of substitution values and lower average molecular weight for OSCs compared to OSCS. Additionally, SSP was found to significantly increase the reaction efficiency of OSA modification process of CS.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2021)
Article
Biochemistry & Molecular Biology
Bozhi Tan, Yao Li, Xu Fei, Jing Tian, Longquan Xu, Yi Wang
Summary: The synthesis efficiency and side reactions of Octenyl succinic anhydride (OSA) starch can be improved by using lipase immobilized on polydopamine magnetic hydrogel microspheres (PMHM) as a biocatalyst. The prepared L-PMHM can be uniformly dispersed in starch slurry, leading to full contact between lipase and starch. L-PMHM exhibits better affinity to the substrate and achieves a higher degree of substitution compared to free lipase. Moreover, L-PHMM can maintain its activity after multiple reuses and can be easily separated from the product.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2022)
Article
Polymer Science
Angela Myrra Puspita Dewi, Umar Santoso, Yudi Pranoto, Djagal W. Marseno
Summary: This study investigated the effect of moisture level on the physicochemical properties of OSA starch during heat moisture treatment (HMT) pretreatment. Results showed that a higher moisture content led to a decrease in crystallinity and gelatinization enthalpy, as well as surface damage and cracking of the starch granules. However, when HMT was performed with the right moisture content, OSA starch with the maximum DS value and reaction efficiency was obtained. The OSA esterification after HMT-25% MC resulted in the highest DS value (0.0086) and reaction efficiency (35.86%). The H25-OSA starch exhibited good water resistance and high cold water solubility. FTIR analysis confirmed the substitution of hydroxyl groups in HMT starch with carbonyl and carboxyl ester groups of OSA.
Article
Chemistry, Applied
Shengyang Ji, Tao Xu, Weisu Huang, Sunan Gao, Yongheng Zhong, Xuan Yang, Mohamed Ahmed Hassan, Baiyi Lu
Summary: Atmospheric pressure plasma jet (APPJ) pretreatment of cassava starch (CS) followed by esterification with octenyl succinic anhydride (OSA) resulted in improved degree of substitution, reaction efficiency, emulsion stability, and emulsion activity compared to unpretreated CS. Morphological characteristics and crystallinity of CS were changed by APPJ pretreatment, leading to further improvements in properties after OSA modification. This study demonstrated that APPJ could serve as a novel approach to facilitate starch modification with OSA.
Article
Biochemistry & Molecular Biology
Yuxue Zheng, Huiling Zhang, Xiaobo Wei, Haitian Fang, Jinhu Tian
Summary: This study found that the encapsulation efficiency of curcumin can be improved by using OSA-ultrasonic treated rice starch, which also showed good stability during in vitro digestion. This research provides a way to develop new emulsion-based delivery systems.
Article
Biochemistry & Molecular Biology
Pingping Wang, Chun Chen, Xiong Fu
Summary: In order to produce stable Pickering emulsion suitable for targeted delivery in the small intestine under stomach acid conditions, the emulsifying ability and pH responsiveness mechanisms of octenyl succinate anhydride modified amylose (OSA-AM) in formless and nanoparticle form were compared. The results showed that OSA-AM nanoparticles exhibited stronger ability to form stable Pickering emulsion compared to OSA-AMs. Additionally, the stability of the Pickering emulsion was found to be dependent on the pH environment, with OSA-AM nanoparticles showing increased stability in acidic conditions.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Biochemistry & Molecular Biology
Yuying Fu, Yuan Li, David W. Everett, Shuni Weng, Yun Zhai, Mengtin Wang, Teng Li
Summary: This study employed octenyl succinic anhydride (OSA) modification to improve the dispersibility and ice recrystallization inhibition activity of amyloid proteins fibrils (APFs). The modification mainly reacted with the amino groups of APFs without significantly changing their morphology. The modified fibrils had lower pI, carried more negative charges, and were more hydrophobic. The OSA modification showed a pH-dependent effect on the dispersibility of the fibrils, with stronger aggregation at acidic pH values.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Chemistry, Applied
Ya-ting Song, Jun-ru Qi, Xiao-quan Yang, Jin-song Liao, Zi-wei Liu, Cheng-wei Ruan
Summary: In this study, the modification of fiber acquired from citrus processing residue via esterification with octenyl succinic anhydride was reported. The esterification reaction significantly improved the hydration properties of the fiber, especially the water holding capacity. The OSA-CF showed higher crystallinity and slightly lower thermal stability compared to the original fiber, as well as a more folded and porous surface structure. Additionally, emulsion prepared by OSA-CF exhibited superior emulsifying abilities and smaller particle size.
FOOD HYDROCOLLOIDS
(2022)
Article
Agriculture, Multidisciplinary
Li Zhao, Qunyi Tong, Yutong Liu, Ziwei Geng, Lichen Yin, Wentian Xu, Abdur Rehman
Summary: In this study, Cur-OSAP micelles were successfully prepared using an anti-solvent co-precipitation method. These micelles showed the highest encapsulation efficiency and loading capacity of curcumin when the OSAP to curcumin mass ratio was 10:1 and the degree of substitution of OSAP was 0.0469. The micelles were roughly spherical in shape with diameters in the approximate range of 30-60 nm.
JOURNAL OF THE SCIENCE OF FOOD AND AGRICULTURE
(2022)
Article
Food Science & Technology
Jie Lin, Shasha Fan, Yuyue Ruan, Dingtao Wu, Ting Yang, Yichen Hu, Wei Li, Liang Zou
Summary: In this study, Tartary buckwheat starch was modified with octenyl succinate anhydride (OS-TBS) to explore its potential for stabilizing Pickering nanoemulsions. The results showed that higher levels of octenyl succinate led to decreased amylose content and gelatinization temperature, while increasing solubility of OS-TBS. Compared to the original starch, OS-TBS exhibited higher surface hydrophobicity, uniform particle size, and improved emulsification stability. These findings suggest that OS-TBS could serve as an excellent stabilizer for nanoscale Pickering emulsions and expand the use of Tartary buckwheat starch in various industrial processes.
Article
Chemistry, Applied
Shangyun Liang, Jing Du, Yan Hong, Li Cheng, Zhengbiao Gu, Zhaofeng Li, Caiming Li
Summary: In this study, nanoparticles composed of curcumin and octenyl succinic anhydride-modified debranched starch were prepared and characterized. The nanoparticles showed improved stability and sustained release of curcumin, making them potential delivery systems for curcumin.
FOOD HYDROCOLLOIDS
(2023)
Article
Biochemistry & Molecular Biology
Chuanjie Liu, Ruxia Ning, Fuhou Lei, Pengfei Li, Kun Wang, Jianxin Jiang
Summary: By esterifying fenugreek galactomannan (FG) with octenyl succinic anhydride (OSA), the mechanical strength of borax-crosslinked FG hydrogels was improved, leading to a broader application field. The optimum process conditions for OSA-modified FG (OFG) were determined as follows: FG concentration 1.5 wt%, n (OSA): n (FG) = 2, n (4-dimethylamino-pyridine, DMAP): n (FG) = 4, and reaction time 12 h. The resulting OSA-modified FG hydrogel exhibited significantly higher mechanical strength, self-healing properties, injectability, and electrical conductivity, expanding its potential applications in sensors, drug delivery, and wound dressing.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2022)