Article
Chemistry, Multidisciplinary
Rajdeep Mondal, Ananthu Shanmughan, A. Murugeswari, Sankarasekaran Shanmugaraju
Summary: This review article systematically introduces the applications of various fluorescence chemosensors in the fluorescence detection of organoarsenic feed additives. The sensors are classified and grouped according to their structures and functions, and a detailed report on the structure, photophysics, and fluorescence sensing properties of different chemosensors is provided. Finally, future prospects for the design and development of practically useful sensor systems for selectively and discriminatively detecting organoarsenic compounds are stated.
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Rajdeep Mondal, Ananthu Shanmughan, A. Murugeswari, Sankarasekaran Shanmugaraju
Summary: Organoarsenic compounds are commonly used feed additives, but their degradation produces toxic inorganic arsenic, causing severe soil and groundwater pollution. Therefore, it is necessary to develop methods for trace detection of organoarsenic additives in wastewater. Fluorescence-based sensing has become popular for detecting water and environmental contaminants, and various fluorescence chemosensors have been designed for the detection and quantification of organoarsenic additives in different environmental samples. This review discusses the recent developments in fluorescence-based chemosensing of organoarsenic feed additives. Future perspectives on the design of sensor systems for selective and discriminative sensing of organoarsenic compounds are also discussed.
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Corinne A. Lutomski, Tarick J. El-Baba, Joshua D. Hinkle, Idlir Liko, Jack L. Bennett, Neha V. Kalmankar, Andrew Dolan, Carla Kirschbaum, Kim Greis, Leonhard H. Urner, Parth Kapoor, Hsin-Yung Yen, Kevin Pagel, Christopher Mullen, John E. P. Syka, Carol V. Robinson
Summary: By using an infrared laser in a high-pressure linear ion trap, researchers were able to remove detergent micelles and obtain good sequence coverage for membrane proteins and their complexes through top-down mass spectrometry.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Xiaosheng Zhang, Xiaoqi Xu, Xiaoya Wu, Tao Geng, Xinda Chen, Lei Liu
Summary: A novel layered magnesium phosphate (MgP) was synthesized using an ionothermal approach. Adding the MgP to lithium grease resulted in superior lubrication compared to the typical lubricant MoS2. The crystal structure and resource endowment of layered materials were discussed to understand the lubrication mechanism. This finding could aid in the development of new high-efficiency solid lubricants.
CHEMISTRY-AN ASIAN JOURNAL
(2023)
Article
Microbiology
Steven J. Biller, Rachel A. Lundeen, Laura R. Hmelo, Kevin W. Becker, Aldo A. Arellano, Keven Dooley, Katherine R. Heal, Laura T. Carlson, Benjamin A. S. Van Mooy, Anitra E. Ingalls, Sallie W. Chisholm
Summary: Extracellular vesicles are small membrane-bound structures released by cells and abundantly found in oceans. They can transport various cellular compounds and play important roles in mediating extracellular biogeochemical reactions in marine ecosystems.
ENVIRONMENTAL MICROBIOLOGY
(2022)
Article
Engineering, Chemical
Xiaoliang Ma, Chaoliang Gan, Xiaopeng Li, Yuting Li, Peng Feng, Xiaoqiang Fan, Xiangyuan Ye, Minhao Zhu
Summary: Core-shell structural SiO2@Cu and SiO2@MoS2 microspheres as lubricant additives show improved tribological properties, with SiO2@Cu microspheres outperforming SiO2@MoS2 due to their structural advantage and the synergistic effect of hard SiO2 core and Cu shell.
Article
Biochemical Research Methods
Ahmed M. M. Abdel-Megied, Isaac A. A. Monreal, Limian Zhao, Alex Apffel, Hector C. C. Aguilar, Jace W. W. Jones
Summary: Emerging and re-emerging zoonotic viral diseases, particularly enveloped viruses like SARS-CoV-2, have a significant impact on public health. The lipid composition of the viral envelope and changes in host cell lipid metabolism during viral infection provide an opportunity to understand how these viruses infect cells. In this study, the lipid composition of VeroE6-TMPRSS2 cells infected with SARS-CoV-2 was characterized, with a focus on the ceramide to sphingomyelin ratio. This lipid profile can help in the development of antiviral strategies and vaccines.
ANALYTICAL AND BIOANALYTICAL CHEMISTRY
(2023)
Article
Dentistry, Oral Surgery & Medicine
B. K. Connizzo, L. Sun, N. Lacin, A. Gendelman, I. Solomonov, I. Sagi, A. J. Grodzinsky, G. R. S. Naveh
Summary: The study reveals significant differences in structure and mechanical properties between the furcation and collar regions of the periodontal ligament (PDL). The dense collar region is stiffer and acts as a scaffold for tooth stabilization, while the furcation region contains more proteins related to remodeling and load transfer, suggesting a critical role in these processes.
JOURNAL OF DENTAL RESEARCH
(2021)
Article
Engineering, Mechanical
J. Umer, N. J. Morris, R. Rahmani, H. Rahnejat, S. Howell-Smith, S. Balakrishnan
Summary: This paper presents an experimental case study of a new generation of fully formulated engine lubricants, focusing on the key interactions and frictional behavior of the dispersant and friction modifiers at different operating temperatures.
JOURNAL OF TRIBOLOGY-TRANSACTIONS OF THE ASME
(2021)
Article
Food Science & Technology
Marzieh Kamankesh, Fatemeh Barzegar, Nabi Shariatifar, Abdorreza Mohammadi
Summary: In this study, a combination of HF-EME and DLLME followed by GC/MS was applied to analyze the biogenic amines in non-alcoholic beers. The method showed advantages in improving selectivity and enrichment factor, which could help beverage industries to monitor and control the concentration of biogenic amines in beers.
Article
Materials Science, Ceramics
Yu-Xuan Li, Ping Li, Yu-Zhe Wu, Zhen-Liang Xu, Ming-Ling Huang
Summary: A novel TiO2 thin film was prepared on ceramic hollow fibers using sol-gel method with PVP and PVA as additives. The effects of different PVP and PVA contents on the properties of TiO2 sol and the performance of ultrafiltration membranes were thoroughly investigated. The membrane with 1.0 wt% PVP and 0.8 wt% PVA showed superior separation performance and antifouling properties.
CERAMICS INTERNATIONAL
(2021)
Article
Chemistry, Applied
Yufei Yang, Shudong He, Yi Zhang, Xingjiang Li, Haiyan Liu, Qiming Li, Xiaodong Cao, Yongkang Ye, Hanju Sun
Summary: Different extraction protocols were compared for extracting prolamins from kidney beans, showing that 70-80% ethanol concentrations and a two-step protocol were beneficial for higher protein content. Variations in protein subunits and properties were observed, with potential applications in food packaging materials due to the hydrophobic nature of kidney bean prolamins.
Article
Green & Sustainable Science & Technology
Da Sun, Everson Kandare, Subashani Maniam, Annan Zhou, Dilan Robert, Nathaphon Buddhacosa, Filippo Giustozzi
Summary: This study evaluated the effectiveness of a thermal-based model in predicting the rubber chemical composition of end-of-life vehicle tyres (EOLT)-derived crumb rubber. The thermal model successfully predicted the composition of EOLT-derived crumb rubber enabling rapid screening of such products to match engineering applications.
JOURNAL OF CLEANER PRODUCTION
(2022)
Article
Chemistry, Analytical
Samin Fathalinejad, Esben Taarning, Peter Christensen, Jan H. Christensen
Summary: This study developed a GC-MS identification workflow for carbohydrate fragmentation compounds, built a library of compounds detected by five different GC-MS methods, investigated and compared compound coverage among the methods, and explored possible reaction pathways for some analytes. A total of 389 compounds were detected, with solid-phase microextraction detecting the highest number of analytes and derivatization GC-MS technique detecting the lowest but largest molecules.
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
(2021)
Article
Chemistry, Applied
Xiaoyan Tan, Xinle Tan, Enpeng Li, Yeming Bai, Thoa T. L. Nguyen, Robert G. Gilbert
Summary: The study aimed to explore the relationships between the molecular fine structure of starch and the composition of storage proteins and metabolic enzymes in chickpea seeds. Results showed that storage proteins and starch biosynthetic enzymes influence each other, with a positive correlation between amylopectin size and total protein content. Higher seed globulin content may indicate higher amylose content and more short-medium amylose chains. This research could aid in selecting chickpea varieties with desired qualities, such as low starch digestibility.
CARBOHYDRATE POLYMERS
(2021)