Article
Chemistry, Physical
Supaphorn Palitsakun, Kitsirirat Koonkuer, Boossayamas Topool, Anusorn Seubsai, Kandis Sudsakorn
Summary: In this study, SrO in combination with a hydration technique was added to modify eggshell-derived CaO catalysts for transesterification of Jatropha oil with methanol. A Box-Behnken design experiment was used to determine the optimal conditions for achieving a maximum methyl ester content of 99.71%. The results showed that the catalyst remained active with a methyl ester content of approximately 90% for several cycles before gradually deactivating due to the losses of active metals.
CATALYSIS COMMUNICATIONS
(2021)
Article
Materials Science, Multidisciplinary
Natkanin Supamathanon, Kornkanok Boonserm, Sireerat Lisnund, Narong Chanlek, Bunyarat Rungtaweevoranit, Pongtanawat Khemthong, Jatuporn Wittayakun, Nattawut Osakoo
Summary: By adding Al metal during the synthesis of geopolymer, a modified Geo with larger pore size was obtained, exhibiting strong basicity of the catalysts due to strong interaction of calcium species with the aluminosilicate network. Experimental results showed that the catalyst based on CaO/Geo achieved a FAME yield of 93.12%, significantly higher than that of unfoamed Geo. The 30% CaO/Geo catalyst could be reused for at least 3 runs, demonstrating its potential as a cost-effective catalyst for biodiesel production.
MATERIALS TODAY COMMUNICATIONS
(2021)
Article
Materials Science, Multidisciplinary
D. Murguia-Ortiz, I. Cordova, M. E. Manriquez, E. Ortiz-Islas, R. Cabrera-Sierra, J. L. Contreras, B. Alcantar-Vazquez, M. Trejo-Rubio, J. T. Vazquez-Rodriguez, L. V. Castro
Summary: Mexican dolomites doped with sodium nitrate were calcined to generate mixed metal oxides for catalytic transesterification of canola oil. Among all catalysts, Na-CaO/MgO exhibited the highest conversion rate of 95.4% and the optimal theoretical conversion rate of 97.46% was obtained through nonlinear programming.
Review
Chemistry, Multidisciplinary
Manish Kumar Bharti, Sonia Chalia, Preeti Thakur, S. N. Sridhara, Atul Thakur, P. B. Sharma
Summary: The depletion and pollution of fossil fuels are prompting the use of alternative, renewable energies such as biofuels. Nanoferrites heterogeneous catalysts have been reviewed for producing biodiesel efficiently. Using transesterification, high conversion yields, low cost, and reusable catalysts can be achieved, with over 90% conversion yields possible with moderate alcohol/oil ratios.
ENVIRONMENTAL CHEMISTRY LETTERS
(2021)
Article
Energy & Fuels
Xiaohang Wang, Kun Yang, Rui Cai, Yujie ChenYang, Zhixing Huang, Benyong Han
Summary: Eleven ionic liquids composed of tetraethylammonium and amino acids were synthesized and evaluated for their catalytic capability in transesterification reactions. Tetraethylammonium arginine showed the highest catalytic activity. By adjusting the reaction conditions, a biodiesel conversion rate of 98.4% was achieved in 60 minutes.
Article
Green & Sustainable Science & Technology
Shaige Xia, Jian Li, Guanyi Chen, Junyu Tao, Wanqing Li, Guangbin Zhu
Summary: In this study, acid-base bi-functional Co doped Fe2O3-CaO nanocatalysts were prepared and optimized for biodiesel production, showing enhanced catalytic activity and FFA resistance. The biodiesel yield from soybean oil and WFO was significantly improved, along with better stability and reusability of the catalyst.
Article
Energy & Fuels
Jing Huang, Yun Zou, Muhammad Yaseen, Huiying Qu, Ruining He, Zhangfa Tong
Summary: The hollow cage-like CaO catalyst prepared by the precise calcination temperature and N2 atmosphere exhibited high catalytic activity and stability for biodiesel production through transesterification of soybean oil with methanol.
Article
Energy & Fuels
Wenlei Xie, Quan Wang, Lihong Guo, Qiaofei Zhang
Summary: This study successfully converted low-grade acidic oils to biodiesel using the composite catalyst ZrMo-AAS. The catalyst showed dual Bronsted-Lewis acidic sites and mesoporous structure, leading to high catalytic activity and stability, making it suitable for biodiesel production from low-grade acidic oils.
BIOENERGY RESEARCH
(2023)
Article
Chemistry, Multidisciplinary
Mosharof Hossain, Nuzhat Muntaha, Lipiar Khan Mohammad Osman Goni, Mohammad Shah Jamal, Mohammad Abdul Gafur, Dipa Islam, Abu Naieum Muhammad Fakhruddin
Summary: In this study, biodiesel was successfully synthesized from multi-stage frying waste soybean oil using chicken eggshell-derived heterogeneous catalysts. By optimizing reaction parameters, a high yield of biodiesel was obtained. The results showed that waste eggshell-derived heterogeneous catalysts have significant catalytic activity under low K+ doping and catalyst loading conditions.
Article
Chemistry, Applied
Marcia G. Ventura, Thomas Pullert, Rubia Risso, Ines Matos, I. Fonseca, Joaquim M. Vital
Summary: Composite materials based on CaO from egg shells and anionic sulfated linear polysaccharide k-carrageenan from red seaweeds were successfully used as a heterogeneous catalyst for transesterification reaction of soybean oil with methanol. The prepared composites exhibited excellent thermal stability and catalytic activity, with an internal structure consisting of meso and macropores that widen with the addition of a crosslinker HMDI.
Article
Energy & Fuels
Nagaraju Pasupulety, Abdurahim A. Al-zahrani, Muhammad A. Daous, Hafedh Driss, Hesham Alhumade
Summary: Mesoporous tantalum-zirconium oxide (TZ) solid acid catalysts were synthesized and employed for biodiesel production from higher water and palmitic acid added oil feedstocks. The results showed that the yield of methyl palmitate and soybean oil fatty acid methyl ester (FAME) was significantly improved with the addition of tantalum to ZrO2. The high ester yield on TZ catalysts was attributed to the improved acidity and interaction between the catalyst and methanol and triglycerides.
Article
Chemistry, Physical
Renata N. Vilas-Boas, Leonardo Lucchetti, Lindoval D. Fernandes, Marcos A. da S. Costa, Marisa F. Mendes
Summary: The study synthesized HAp, Na/HAp, and CaOCeO2/HAp materials and applied them in biodiesel production. The results showed that HAp catalyst was not efficient in complete transesterification, while Na/HAp and CaOCeO2/HAp catalysts exhibited good activity. CaOCeO2/HAp catalyst had the best catalytic activity in the transesterification reaction using VODD as raw material.
Article
Green & Sustainable Science & Technology
Kristine Lazdovica, Valdis Kampars, Anastasija Gaile
Summary: Designing a cost-effective and environmentally friendly heterogeneous catalyst is necessary for biodiesel production. In this study, new catalysts of 0.3-CaO-MgO/SBA-15 and 0.8-CaO-MgO/SBA-15 were prepared and compared. The 0.3-CaO-MgO/SBA-15 catalyst exhibited higher purity, larger surface area, and pore volume, leading to excellent catalytic activity for biodiesel production.
ENVIRONMENTAL PROGRESS & SUSTAINABLE ENERGY
(2023)
Article
Engineering, Chemical
Ayse Hilal Ulukardesler
Summary: The global energy demand is increasing and fossil fuels will eventually be depleted. Renewable biofuels, such as biodiesel, have the potential to meet the world's current energy demand. This study aims to optimize the biodiesel production process and reduce production cost by using waste cooking oil as a raw material.
Article
Green & Sustainable Science & Technology
Vinicius Mateo e Melo, Gabriela Filipini Ferreira, Leonardo Vasconcelos Fregolente
Summary: This article discusses the challenges faced in biodiesel production and the advantages of using heterogeneous catalysts. Research has shown that catalysts derived from sugarcane bagasse biochar have good activity and stability, and can be reused for multiple cycles. However, further studies are needed to reduce calcium ion leaching and explore the potential of using catalysts derived from sugarcane bagasse biochar.
RENEWABLE & SUSTAINABLE ENERGY REVIEWS
(2024)