4.6 Article

Fabrication of 3-Dimensional Porous Graphene Materials for Lithium Ion Batteries

期刊

ELECTROCHIMICA ACTA
卷 146, 期 -, 页码 437-446

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2014.09.059

关键词

Porous graphene material; Covalent grafting; Potassium hydroxide etching; Anode material; Lithium ion battery

资金

  1. Outstanding Talent and Team Plans Program of South China University of Technology
  2. Fundamental Research Funds for the Central Universities of SCUT [2014ZM0066]
  3. National Natural Science Foundation of China [11474101]
  4. Recruitment Program of Global Experts

向作者/读者索取更多资源

A 3-dimensional porous graphene material (PGM) has been synthesized using a simple two-step process: hydrothermal reaction and calcination. Hydrothermal reaction of graphene oxide (GO) in the presence of resorcinol and glutaraldehyde leads to covalent grafting of partially reduced GO with glutaraldehyde and the deposition of phenolic resin. Subsequent calcination of the composite consisting of phenolic resin deposited on partially reduced GO in the presence of KOH produces structurally stable, highly porous graphene material with a specific surface area of similar to 1,066 +/- 2 m(2) g (1). When used as an active electrode material in a lithium battery, the PGM exhibits an initial discharge capacity of similar to 1,538 mAh g (1), which is significantly higher than those of graphite and other carbonaceous materials reported previously. More importantly, when cycled at higher discharge/charge rates, the PGM-based electrodes still deliver large capacities and excellent cycling performance, demonstrating great potential for high-performance lithium-ion batteries. The attractive electrochemical performance of the PGM is attributed to its unique porous structure with large specific surface area and the presence of more disordered carbon atoms produced by the KOH activation. (C) 2014 Elsevier Ltd. All rights reserved.

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