期刊
ELECTROCHIMICA ACTA
卷 136, 期 -, 页码 330-339出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2014.05.116
关键词
acid-sonication pretreatment; cobalt oxide-graphene composite; in-plane vacancies; lithium-ion batteries; ultra-high loading
资金
- Natural Science Foundation of China (NSFC) [21203132, 51272168, 21203134]
Ultra-high loading Co3O4 nanoparticles (NPs) with the particle size of ca. 10 nm anchoring on the acid-sonication pretreated graphene oxide with induced in-plane vacancies (deGO) are in-situ synthesized through a low-temperature hydrothermal reaction. These in-plane vacancies can act as active sites for the formation of Co3O4 NPs since Co2+ ions have a strong bonding effect with the carboxylate groups decorating the defect edge sites, in which nucleation, growth and crystallization of Co3O4 NPs are well separated and confined in a several nanometer region. Although the content is extremely low (7 wt%), deRGO can not only provide a support for anchoring Co3O4 NPs and work as a conductive matrix enabling good contact between them, but also prevent the particle aggregation and keep the integrity of the composite during long-term cycles. The as-prepared deRGO/Co3O4 anode exhibits a high specific capacity and superior rate performance with charge capacities of 727.1 mAh g(-1) at 2 C, 559.4 mAh g(-1) at 5 C and 70.45 mAhg(-1) at 30 C. Meanwhile, no capacity fade can be observed after 100 cycles at 1 C, revealing a stable cycling ability. Therefore this material has great potential application for advanced Li-ion batteries. (C) 2014 Elsevier Ltd. All rights reserved.
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