期刊
ELECTROCHIMICA ACTA
卷 144, 期 -, 页码 406-411出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2014.08.092
关键词
Reduced graphene oxide; Lithium iron phosphate; solvothermal method; Lithium-ion batteries
资金
- National Basic Research Program of the Ministry of Science &Technology of China [2012CB825800, 2014CB848900]
- Science Fund for Creative Research Groups, NSFC [11321503]
- Knowledge Innovation Program of Chinese Academy of Sciences [KJCX2-YW-N42]
- National Natural Science Foundation of China [NSFC 11179001, 11275227, U1232131, 51222202]
- Fundamental Research Funds for Central Universities [2012QNQA4005, WK2310000035]
We present a new olivine LiFePO4(LFP)@C/reduced graphene oxide(RGO) nanocomposite synthesized by a solvothermal method. In this hybrid nanocomposite, the cooperation of the LiFePO4 with a carbon coating and the reduction of the graphene oxide has been tuned to produce an effective three-dimensional (3D) conductive network. Compared with conventional LFP@C nanocomposites, the experimental results of LFP@C/RGO nanocomposites show their outstanding electrochemical performance with higher rate capability and better cycability. In particularly, no obvious capacity fading after 200 cycles at a current of 10 degrees C is observed and a discharge capacity of 119 mAh/g can be still delivered at 20 degrees C, pointing out that the electronic conductivity of electrode particles also contribute to achieve a high-rate performance. This study may play a key role in large power sources when applied in industrial productions, such as electric vehicles. (C) 2014 Elsevier Ltd. All rights reserved.
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