期刊
ELECTROCHIMICA ACTA
卷 142, 期 -, 页码 167-172出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2014.07.104
关键词
Graphene; Mixed ionic liquids; Platinum nanoparticles; Electrocatalyst; Methanol oxidation
资金
- National Natural Science Foundation of China [21275082, 81102411, 21203228]
- Natural Science Foundation of Shandong [ZR2011BZ004, ZR2011BQ005]
- National Key Basic Research Development Program of China (973 special preliminary study plan) [2012CB722705]
- Taishan Scholar Program of Shandong Province
- Natural Science Foundation of Qingdao [13-1-4-128-jch, 13-1-4-202-jch]
A kind of mixed ionic liquids (ILs) of 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF4],IL1) and hexafluorophosphate ([bmim][PF6], IL2) was introduced to the functionalization of graphene (GN) nanosheets, which was used to the synthesis of platinum nanoparticles (Pt NPs) to obtain the Pt/IL1-IL2/GN nanocomposite. The interaction between mixed ILs and GN achieved a stable performance due to the excellent electronic and interfacial property of the fabricated nanocomposites, which was favorable for effective loading of Pt NPs on the IL1-IL2/GN support. The as-prepared Pt/IL1-IL2/GN composites exhibited highly electrocatalytic activity (764.3 mA mg(pt)(-1) at 0.6 V vs. SCE) and stability toward methanol oxidation, demonstrating their promising potential as the anode catalyst for direct methanol fuel cells (DMFCs). (C) 2014 Elsevier Ltd. All rights reserved.
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