期刊
ELECTROCHIMICA ACTA
卷 106, 期 -, 页码 534-540出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2013.05.035
关键词
Lithium vanadium oxide; Graphite; Reversible capacity; Cyclic stability
资金
- State Key Basic Research Program of PRC [2011CB935903]
- National Natural Science Foundation of China [20925312]
- Shanghai Science Technology Committee [08DZ2270500]
Graphite-anchored lithium vanadium oxide (Li1.1V0.9O2) has been synthesized via a one-pot in situ method. The effects of the synthesis conditions, such as the ratio of reaction components and calcination temperature, on the electrochemical performance are systematically investigated by means of scanning electron microscopy (SEM), X-ray diffraction (XRD), electrochemical impedance spectroscopy (EIS), galvanostatic discharge/charge tests and differential scanning calorimetry (DSC). Compared with the simple mixture of graphite and lithium vanadium oxide, the graphite-anchored lithium vanadium oxide delivers an enhanced reversible capacity, rate capability and cyclic stability. It also shows better thermal stability. (C) 2013 Elsevier Ltd. All rights reserved.
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