期刊
ELECTROCHIMICA ACTA
卷 66, 期 -, 页码 67-74出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2012.01.059
关键词
Lithium battery; Functionalized cation; Ionic liquid; Electrolyte
资金
- National Natural Science Foundation of China [21103108, 21173148]
- Key Lab of Novel Thin Film Solar Cells, Chinese Academy of Sciences [KF201110]
Two new functionalized ILs based on pyrazolium cations and bis(trifluoromethylsulfonyl)imide anions (TFSI-) were synthesized and characterized. Their physicochemical and electrochemical properties, including melting point, thermal stability, density, viscosity, conductivity, and electrochemical window were investigated. The two ILs had low melting points and wide electrochemical windows. Behaviors of lithium redox, chemical stability against lithium metal, and charge-discharge cycle performance of lithium battery were also examined for the two IL electrolytes with 0.4 mol kg(-1) LiTFSI. The IL electrolytes showed good chemical stability against lithium metal, and Li/LiFeO4 cells using the two IL electrolytes without additives owned good capacity and cycle property at the current rate of 0.1 C. (C) 2012 Elsevier Ltd. All rights reserved.
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