Article
Agricultural Engineering
Hongwei Wu, Qing Li, Haolin Yu, Minmin Gu, Yudie Wang, Chensen Xu, Zhixin Liao
Summary: This work explores an eco-friendly approach to extracting cashew nut shell liquid (CNSL) and refining cardanol from cashew nuts produced in Hainan, China. CNS, which is usually considered waste from agricultural processing, can be extracted into valuable CNSL using solvent extraction or supercritical CO2 extraction. The composition of extracted CNSL varies with different conditions, and less polar solvents extract more CNSL. Supercritical CO2 extraction also shows superior performance in CNSL extraction as an environmentally friendly method. CNSL from Hainan cashew nuts contains a high amount of anacardic acid. The extracted CNSL can be decarboxylated and separated to obtain a mixture of cardanol consisting of four olefins with different numbers of double bonds. Cardanol can be converted to saturated cardanol and high purity cardanol monoene through catalytic hydrogenation and catalytic transfer hydrogenation, respectively. Both saturated cardanol and cardanol monoene have promising prospects due to their chemical structure.
INDUSTRIAL CROPS AND PRODUCTS
(2023)
Article
Biochemistry & Molecular Biology
Sandra-Yaneth Gaitan-Jimenez, Luz-Patricia Restrepo-Sanchez, Fabian Parada-Alfonso, Carlos-Eduardo Narvaez-Cuenca
Summary: Cashew nut-shell liquid (CNSL) and its components have the potential to act as natural antioxidants, with cardols and cardanols being effective antioxidants for soybean oil.
Article
Multidisciplinary Sciences
James Nyirenda, Kadango Zombe, George Kalaba, Chipo Siabbamba, Inyambo Mukela
Summary: This study demonstrates the extraction of cashew nut shell liquid (CNSL) from cashew nut shell waste and the use of residues for activated carbon generation to remove heavy metals and methylene blue. The results show the potential industrial applications and environmental significance of this process.
SCIENTIFIC REPORTS
(2021)
Article
Chemistry, Multidisciplinary
Harshitha Anchan, Snehal Jadhav, Saikat Dutta
Summary: Activated carbon (AC) produced from waste cashew nut husk and shell using phosphoric acid as the activating agent exhibited high specific surface area and excellent adsorption capacity for methylene blue. The synthesis of AC from these waste materials is a promising approach for the cashew nut processing industry, providing value addition and improving economic prospects.
Review
Chemistry, Multidisciplinary
Ermelinda Bloise, Maria Rosaria Lazzoi, Lucia Mergola, Roberta Del Sole, Giuseppe Mele
Summary: Cashew nut shell liquid (CNSL), a byproduct of the cashew industry, is an important natural source of phenolic compounds that can be used as an alternative to synthetic substances in various industrial applications. The unique functional groups of CNSL components allow for the design of interesting nanostructures with tunable properties for bioactive applications.
Article
Green & Sustainable Science & Technology
Shumaila Masood, Anujit Ghosal, Fahmina Zafar, Manawwer Alam, Nahid Nishat
Summary: Phenalkamines (PhAA) are used as curing agents for epoxies and polyureas. This study focused on the polymerization and conversion of PhAA resin to anti-corrosive coatings for mild steel substrate. PolyPhAA resin was prepared using cashew nut shell liquid, aldehyde, and amine, and showed excellent coating properties. The PolyPhAA2 coating exhibited hydrolytic stability, anti-icing ability, strong adhesion, and corrosion protection, making it a potential alternative to petroleum-based coatings.
MATERIALS TODAY SUSTAINABILITY
(2023)
Review
Biochemistry & Molecular Biology
Elisa Uliassi, Andressa Souza de Oliveira, Luciana de Camargo Nascente, Luiz Antonio Soares Romeiro, Maria Laura Bolognesi
Summary: Alzheimer's disease is a complex neurodegenerative disorder with a multifaceted pathogenesis, making the development of effective drugs challenging. Researchers have recently turned to Brazilian biodiversity to develop new molecules derived from CNSL as potential treatments for AD, with rational modifications showing promise in creating novel drug candidates.
Article
Green & Sustainable Science & Technology
Antonia F. J. Uchoa, Weslley S. Rocha, Johnny P. M. Feitosa, Debora H. A. Brito, Lilian M. Gondim, Nagila M. P. S. Ricardo, Jorge B. Soares, Sandra A. Soares
Summary: This study evaluates the potential of cashew nut shell liquid (CNSL) as a renewable and low-cost resource to synthesize bio-based epoxy for asphalt binders. The epoxidized material (ECL) showed enhanced elasticity and improved rutting and fatigue resistance in the modified binders, making it a promising alternative to petrochemical-based additives.
JOURNAL OF CLEANER PRODUCTION
(2021)
Review
Biotechnology & Applied Microbiology
Srinivasan Kandaswamy, Venkatesa Murthy Swarupa, Souvik Sur, Gautam Choubey, Yuvarajan Devarajan, Ruby Mishra
Summary: This article discusses the viability of using cashew nutshell liquid biodiesel (CNSLBD) as an alternative energy source. The findings suggest that CNSLBD has the potential to benefit both the cashew nut industry and the energy industry.
BIOTECHNOLOGY AND BIOENGINEERING
(2023)
Article
Chemistry, Organic
Yuka Yokoyama, Tatsuya Yasui, Akihiro Takeda, Shinji Kanehashi, Kenji Ogino
Summary: Cardanol, the main component of CNSL, was hydrogenated and converted to Bis-CNSL using aldehydes in the presence of an acid catalyst without a solvent. High selectivity for Bis-CNSL was achieved using aldehydes with alkyl chains of 2 or more carbons. A large-scale preparation process using propionaldehyde with reduced aldehyde amount and recrystallization from methanol resulted in Bis-CNSL purity over 99%.
TETRAHEDRON LETTERS
(2023)
Article
Energy & Fuels
Adama Coulibaly, Mohamed K. Sako, Doudjo Soro, Sayon Sidibe, Richardson Yohan
Summary: This study investigates the valuation of cashew nut shell liquid (CNSL) mixed with diesel fuel as an energy source, and verifies its feasibility through combustion tests on a diesel engine. The results indicate that using purified CNSL as fuel up to 60% is possible, but improvement in purification techniques is still needed.
Article
Chemistry, Medicinal
Cigdem Sahin, Lilia Magomedova, Thais A. M. Ferreira, Jiabao Liu, Jens Tiefenbach, Priscilla S. Alves, Fellipe J. G. Queiroz, Andressa S. de Oliveira, Mousumi Bhattacharyya, Julie Grouleff, Patricia C. N. Nogueira, Edilberto R. Silveira, Daniel C. Moreira, Jose Roberto Souza de Almeida Leite, Guilherme D. Brand, David Uehling, Gennady Poda, Henry Krause, Carolyn L. Cummins, Luiz A. S. Romeiro
Summary: Metabolic diseases are increasing at alarming rates globally. This study explored the potential use of phenolic lipid derivatives from cashew nut shell liquid as drugs for the treatment of diabetes and obesity. The compounds showed PPAR activity and tissue-specific effects, making them promising candidates for further development.
JOURNAL OF MEDICINAL CHEMISTRY
(2022)
Article
Biochemistry & Molecular Biology
Son A. Hoang, Khanh D. Pham, Nhung H. Nguyen, Ha T. Tran, Ngoc Hoang, Chi M. Phan
Summary: This study presents a sustainable alternative to traditional lubricating grease thickeners by synthesizing a thickener from abundant agricultural waste, cashew nut shell liquor. The process offers an economical and environmentally friendly solution to replace thickeners derived from castor oil.
Article
Polymer Science
Ketan Makwana, Amol B. Ichake, Vinayak Valodkar, G. Padmanaban, Manohar V. Badiger, Prakash P. Wadgaonkar
Summary: This study investigates the effect of different amine/epoxy ratios on the cure characteristics of epoxy thermosets with the addition of diglycidyl ether of cardol (DGEC) in commercially available diglycidyl ether of bisphenol A (DGEBA). The results show that DGEC addition can modify the thermal and mechanical properties.
EUROPEAN POLYMER JOURNAL
(2022)
Article
Energy & Fuels
B. Deepanraj, N. Senthilkumar, D. Mala, A. Sathiamourthy
Summary: This study evaluates the performance of a diesel engine running on a blend of cashew nut shell liquid with an oxygenated additive and diesel, optimizing for brake thermal efficiency and specific fuel consumption. It is found that adding an appropriate amount of diethyl ether and lowering injection pressure can improve brake thermal efficiency, while blended fuel and higher additive addition are more advantageous for specific fuel consumption.
BIOMASS CONVERSION AND BIOREFINERY
(2022)
Article
Biochemistry & Molecular Biology
Aluisio Marques da Fonseca, Sadrack Queque Cabongo, Bernardino Joaquim Caluaco, Regilany Paulo Colares, Carla Freire Celedonio Fernandes, Helcio Silva dos Santos, Pedro de Lima-Neto, Emmanuel Silva Marinho
Summary: The global pandemic caused by Sars-CoV-2 has posed a significant health problem, and previous studies have identified the main protease (Mpro) as a potential target for this virus. In this study, researchers used a de novo molecular design method with the help of artificial intelligence to construct new bioactive compounds for inhibition. The simulation results showed that Hit 998 had the highest bioaffinity value and synthetic viability of 50%.
JOURNAL OF BIOMOLECULAR STRUCTURE & DYNAMICS
(2023)
Article
Chemistry, Physical
Daniela Mirela Lima Pinheiro, Lucas Lima Bezerra, Ana Aline Coelho Alcanfor, Filipe Xavier Feitosa, Norberto Kassio Vieira Monteiro, Adriana N. Correia, Pedro de Lima Neto, Hosiberto Batista de Sant'Ana
Summary: The thermodynamic and electrochemical properties of Ag+ ions in ChCl and G mixture were investigated, and MD and DFT methods were used for computational simulation. The specific mass, speed of sound, viscosity, and refractive index of the solution were measured at different temperatures. The electrochemical behavior of Ag+ ions was analyzed by cyclic voltammetry, and silver coatings were successfully electrodeposited on the Au surface. SEM analysis revealed the surface morphologies of the electrodeposits. The computational calculation showed that adding silver nitrate to the eutectic solvent had a predominant repulsive effect and negligible influence on sound velocity and refractive index. MD simulations demonstrated a strong interaction between Ag+ ions and Cl ions.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Polymer Science
Luisa Macedo de Vasconcelos, Niedja Fittipaldi Vasconcelos, Diego Lomonaco, Morsyleide de Freitas Rosa, Enrique Rodriguez-castellon, Fabia Karine Andrade, Rodrigo Silveira Vieira
Summary: Bacterial cellulose (BC) membrane is a biopolymer with high purity and excellent properties. In this study, microwave-assisted chemical modification was used to oxidize wet BC membranes, while preserving their physical and mechanical properties. The results showed that microwave heating method can better protect the structure of cellulose, improve the oxidation effect, and have less impact on the crystalline structure of cellulose.
Article
Biochemistry & Molecular Biology
Leonardo P. da Silva, Francisco Wagner Q. Almeida-Neto, Lucas L. Bezerra, Jacilene Silva, Norberto K. V. Monteiro, Marcia M. Marinho, Helcio S. dos Santos, Alexandre M. R. Teixeira, Emmanuel S. Marinho, Pedro de Lima-Neto
Summary: Chagas disease is a tropical disease caused by the parasite Trypanosoma cruzi, transmitted by the barber insect. This study evaluates the antichagasic potential of five sulfonamide molecules derived from anacardic acid using molecular approach. The results show that SA1, SA2, and SA4 exhibit better interactions with the target enzyme, indicating their potential as antichagasic agents.
JOURNAL OF MOLECULAR MODELING
(2023)
Article
Materials Science, Multidisciplinary
Ronnie A. R. Semedo, Ana Aline C. Alcanfor, Natalia G. Sousa, Paulo N. S. Casciano, Adriana N. Correia, Juliermes C. Pereira, Pedro de Lima-Neto
Summary: Znx-Mn1-x coatings were successfully electrodeposited on a rotating 1020 carbon steel electrode using a choline chloride and urea mixture without additives. The corrosion performance of the coatings was evaluated and showed better corrosion protection than the pure Zn coating. The Zn84Mn16 coating had the best performance, lasting 3 times longer than the pure Zn coating in immersion tests.
MATERIALS CHEMISTRY AND PHYSICS
(2023)
Article
Chemistry, Analytical
Helio Oliveira do Nascimento, Maria Zillene Franklin da Silva, Jessica Beserra Alexandre, Tulio Italo da Silva Oliveira, Ari Clecius Alves de Lima, Ronaldo Ferreira do Nascimento
Summary: This study proposes a new methodology that combines chromatographic data with chemometric tools to differentiate original and counterfeit whiskeys. Two chromatographic methods, SPME-GC-BID and HPLC-DAD, were used to analyze counterfeit and original whiskey samples, and chemometric tools such as PCA, HCA, and PLS-DA were employed for data analysis. The results showed that the proposed method can successfully differentiate between original and counterfeit whiskeys.
MICROCHEMICAL JOURNAL
(2023)
Article
Chemistry, Physical
Joao Brandao Junior, Jean Gleison Andrade do Nascimento, Michael Pablo Franca Silva, Eliane de Aquino Lima Brandao, Viviane de Castro Bizerra, Kaiany Moreira dos Santos, Juliana de Franca Serpa, Jose Cleiton Sousa dos Santos, Aluisio Marques da Fonseca, Diego Lomonaco Vasconcelos de Oliveira, Maria Cristiane Martins de Souza
Summary: In this study, biodiesel was produced from vegetable oils through enzymatic esterification. The results showed that the enzyme catalysts had better performance compared to chemical catalysts.
Article
Energy & Fuels
Adriano Lincoln Albuquerque Mattos, Diego Lomonaco, Beatriz Silva de Oliveira, Lloyd Ryan Viana Kotzebue, Jonas Durval da Silva Vieira, Maira Saldanha Duarte, Renato Carrha Leitao
Summary: This study presents an alternative method for fabricating green medium density fiberboard using bio-oil based benzoxazine resins. The sugarcane bagasse fiber is used instead of wood fiber, and the fossil-based resin is replaced by the bio-based benzoxazine resin. The results indicate the promising potential of using sugarcane bagasse for the development of bio-based materials with technological application.
BIOMASS CONVERSION AND BIOREFINERY
(2023)
Article
Chemistry, Physical
Laudenor Amorim, Renato Verissimo de Oliveira, Lucas Lima Bezerra, Lucas Pinheiro Coutinho, Pierre Basilio Almeida Fechine, Adriana Nunes Correia, Amison Rick Lopes da Silva, Pedro de Lima-Neto, Norberto Kassio de Vieira Monteiro
Summary: This study analyzed the behavior of Fe2+ and Mn2+ ions in water and a deep eutectic solvent (DES) based on choline chloride and ethylene glycol. The results showed stronger interaction between the metal ions and water compared to their interaction in the DES. The study provides insights into the coordination possibilities and behavior of these systems.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2023)
Article
Metallurgy & Metallurgical Engineering
Francisco Evaristo Uchoa Reis, Luis Paulo Mourao dos Santos, Lorena Braga Moura, Mirela Oliveira de Castro, Pedro de Lima Neto, Jorge Luiz Cardoso, Hamilton Ferreira Gomes de Abreu
Summary: The mechanical properties and corrosion resistance of annealed superferritic stainless steel model alloy 25Cr-6Mo-5Ni were studied in 0.6 M NaCl solution. The microstructure exhibited a ferrite matrix and eutectoid phase with a lamellar structure distributed at grain boundaries and within the ferrite grains with a spherical morphology. The model alloy displayed brittle behavior according to tensile and impact results. Fractography analysis revealed the presence of cleavage facets, river patterns, and micro-cracks at grain boundaries and across the ferrite grains. Pitting corrosion initiated within the eutectoid phase containing chrome depletion zones. Electrochemical impedance spectroscopy measurements indicated that the breakdown of passive films was more susceptible in the eutectoid phase.
INTERNATIONAL JOURNAL OF MATERIALS RESEARCH
(2023)
Article
Chemistry, Physical
Natalia G. Sousa, Renato V. de Oliveira, Ana Aline C. Alcanfor, Filipe X. Feitosa, Hosiberto B. de Sant'Ana, Walther Schwarzacher, Pedro de Lima-Neto, Norberto K. V. Monteiro, Adriana N. Correia
Summary: The objective of this study was to electrodeposit Sn-In coatings using a deep eutectic solvent and to characterize the electrolytes employed. Experimental results showed that Sn2+ and In3+ ions interacted more strongly with Cl- ions than with ethylene glycol and choline.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Chemistry, Physical
Ana G. N. Camara, Francisco W. Q. Almeida-Neto, Yana L. C. Silva, Fatima M. Nunes, Marcos C. Mattos, Jair Mafezoli, Francisco G. Barbosa, Emmanuel S. Marinho, Pedro Lima-Neto, Maria C. F. Oliveira
Summary: This study characterized the spectroscopic properties of norbadione A (2), a naphtalenoid pulvinic acid derivative isolated from Pisolithus tinctorius, and confirmed its proposed chemical structure through comparison of experimental and theoretical data. The electronic properties of pulvinic acid (1) and its derivatives were also investigated using quantum chemical calculations.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Chemistry, Multidisciplinary
Karen P. S. Lopes, Maria C. C. Lucena, Thiago Inacio B. Lopes, Amison R. L. da Silva, Leonardo P. da Silva, Norberto K. V. Monteiro, Pedro de Lima-Neto, Nagila M. P. S. Ricardo
Summary: This study aims to use infrared (IR) in silico data as a standard database for preliminary analysis of new synthetic seized drugs. Computational chemistry was used to compare ten of the most common synthetic illicit substances on the Brazilian market and evaluate infrared data from a standard electronic library, experimental data from seized samples, and data simulated by Density Functional Theory (DFT). The results suggest that using computational methodology is a feasible way to analyze the structures of new synthetic drugs and obtain preliminary infrared profiles.
JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY
(2023)
Article
Electrochemistry
Abdul Qayoom Mugheri, Shaista Khan, Ali Asghar Sangah, Aijaz Ahmed Bhutto, Muhammad Younis Laghari, Nadeem Ahmed Mugheri, Asif Ali Jamali, Arsalan Ahmed Mugheri, Nagji Sodho, Abdul Waheed Mastoi, Aftab Kandhro
Summary: Green hydrogen has the potential to transition to a pollution-free energy infrastructure. This study proposes a solution to produce hydrogen during the photoelectrochemical process, offering greater stability and control over chemical reactions. Techno-economic assessments show the efficiency and economic feasibility of co-producing value-added chemicals to enhance green hydrogen production.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Danpeng Cheng, Wuxin Sha, Qigao Han, Shun Tang, Jun Zhong, Jinqiao Du, Jie Tian, Yuan-Cheng Cao
Summary: LiNixCoyMn1-x-yO2 (NCM) is a critical cathode material for lithium-ion batteries in electric vehicles. The aging of cathode/electrolyte interfaces leads to capacity degradation and long-term cycle instability. A novel neural network model called ACGNet is developed to predict electrochemical stability windows of crystals, allowing for high-throughput screening of coating materials. LiPO3 is identified as a promising coating material with high oxidation voltage and low cost, which significantly improves the cycle stability of NCM batteries. This study demonstrates the accuracy and potential of machine learning in battery materials.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
P. Mohana, R. Yuvakkumar, G. Ravi, S. Arunmetha
Summary: This study successfully fabricates a non-noble CuO/NiO/rGO nanocomposite and investigates its electrocatalytic performance for oxygen evolution reaction in alkaline environment. The experimental results demonstrate that the electrocatalyst exhibits high activity and good stability, offering a new synthetic approach for sustainable energy production.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Qiong Qu, Jing Guo, Hongyu Wang, Kai Zhang, Jingde Li
Summary: In this study, a bifunctional electrode host design consisting of carbon nanofibers implanted ordered porous Co-decorated Al2O3 supported on carbon nanotube film (CNTF) was proposed to address the shuttling effect of lithium polysulfides (LiPSs) and dendrite formation of metal lithium anode in lithium-sulfur (Li-S) batteries. The electrode exhibited excellent conductivity, efficient confinement of LiPSs, and catalytic conversion performance, resulting in high initial capacity and good capacity retention during cycling. As an anode, the electrode showed excellent Li+ diffusion performance and uniform lithium growth behavior, achieving a dendrite-free lithium electrode. The flexible pack cell assembled from these electrodes delivered a specific capacity of 972 mAh g(-1) with good capacity retention.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Hong Zhang, Jin-Peng Yu, Chen Chen, Cheng-Yong Shu, Guang-Yu Xu, Jie Ren, Kai Cui, Wen-Fang Cai, Yun-Hai Wang, Kun Guo
Summary: Spray coating of acetylene black nanoparticles onto stainless steel mesh can enhance its biofilm formation ability and current density, making it a promising electrode material for microbial electrochemical systems. The spray coating method is simple, cost-effective, and suitable for large-size stainless steel electrodes.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Binpeng Hou, Jingjin Chen, Li-Hong Zhang, Xiaowen Shi, Zizhong Zhu
Summary: The electrochemical performance of Li1.20Mn0.44Ni0.32Co0.04O2 and its oxygen-deficient phase Li1.20Mn0.44Ni0.32Co0.04O1.83 was studied through first-principles calculations. The results show that the oxygen-deficient phase has a higher theoretical capacity but lower voltage platform and higher chemical activity compared to the pristine phase.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Yating Du, Sayoko Shironita, Daisuke Asakura, Eiji Hosono, Yoshitsugu Sone, Yugo Miseki, Eiichi Kobayashi, Minoru Umeda
Summary: This study investigates the effect of high- and low-temperature environments on the charge-discharge performance of a Li-ion battery. The deterioration mechanisms of the battery at different temperatures are analyzed through various characterization techniques. The results indicate that the battery performance deteriorates more significantly at a low-temperature environment of 5 degrees C compared to higher temperatures. The understanding of the deterioration mechanisms can contribute to the development of safer battery usage methods.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Si-Si Shi, Zhi-Xiang Yuan, Fei Zhang, Ping Chen
Summary: In this study, a new nano-electrocatalyst was prepared, which exhibited superior electrocatalytic activity for the reduction of NO2- to ammonia in a neutral electrolyte, potentially due to the synergistic enhancement between Co3O4-x and Co.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Berna Dalkiran, Havva Bekirog
Summary: This study reports the use of deep eutectic solvents (DES) based on ethylene glycol and urea as low-cost and green electrolytes for enhancing electrochemical detection of natural antioxidants. The study successfully developed a disposable and effective electrochemical sensing platform for simultaneous determination of ascorbic acid (AA) and gallic acid (GA) using NaOH nanorods on a pencil graphite electrode. The proposed electrode showed improved analytical performance, with higher peak currents and shifted oxidation potentials in DES compared to BR buffer medium.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Sijun Ren, Jianguo Huang
Summary: In this study, a novel bio-inspired nanofibrous WO3/carbon composite was synthesized using a facile hydrothermal method. The three-dimensional network structure of the composite alleviated the volume expansion of WO3 nanorods and enhanced the charge-transport kinetics. The optimized composite exhibited superior lithium storage properties.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Zhilong Zheng, Yu Chen, Hongxia Yin, Hengbo Xiao, Xiangji Zhou, Zhiwen Li, Ximin Li, Jin Chen, Songliu Yuan, Junjie Guo, Haibin Yu, Zhen Zhang, Lihua Qian
Summary: This study found that interstitial Zn cations in CoMoO4 can modulate the dissolution kinetics of Mo cations and improve the OER performance. The interstitial Zn cations can prevent the dissolution of Co cations at high potential, enhancing the durability of the catalyst.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Xiaobo Lin, Shern R. Tee, Debra J. Searles, Peter T. Cummings
Summary: Molecular dynamics simulations using the constant potential method were used to investigate the charging dynamics and charge storage of supercapacitors. The simulations revealed that the water-in-salt electrolyte exhibited the highest charge storage and significantly higher capacitance on the negative electrode. The varying contributions of different electrode regions to supercapacitor performance were also demonstrated.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Wiktoria Lipinska, Vita Saska, Katarzyna Siuzdak, Jakub Karczewski, Karol Zaleski, Emerson Coy, Anne de Poulpiquet, Ievgen Mazurenko, Elisabeth Lojou
Summary: The spatial distribution of enzymes on electrodes is important for bioelectrocatalysis. In this study, controlled spatial distribution of gold nanoparticles on Ti nanodimples was achieved. The efficiency of enzymatic O2 reduction was found to be influenced by the size of the gold nanoparticles and their colocalization with TiO2. The highest stability of enzymatic current was observed with the largest gold nanoparticles.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Tariq M. Al-Hejri, Zeenat A. Shaikh, Ahmed H. Al-Naggar, Siddheshwar D. Raut, Tabassum Siddiqui, Hamdan M. Danamah, Vijaykumar V. Jadhav, Abdullah M. Al-Enizi, Rajaram S. Mane
Summary: This study explores a promising self-growth approach for the synthesis of nickel hydroxide (Ni(OH)2) nanosponge-balls on the surface of a nickel-foam (NiF) electrode. The modified NiF electrode, named Ni(OH)2@NiF, shows distinctive nanosponge-ball morphology and demonstrates excellent energy storage capability and electrocatalytic performance in both hydrogen and oxygen evolution reactions.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Rafael Del Olmo, Gregorio Guzman-Gonzalez, Oihane Sanz, Maria Forsyth, Nerea Casado
Summary: The use of Lithium-Ion Batteries (LIBs) is becoming increasingly extensive, and it is important to optimize the devices to achieve their maximum practical specific capacity. In this study, mixed ionic-electronic conducting (MIEC) binders based on PEDOT:PSS and PEDOT: PDADMA-TFSI were developed for Li-ion cathodes, and their performance was compared with conventional formulations. The influence of electrode formulations, including the addition of conducting carbon and an Organic Ionic Plastic Cristal (OIPC), was also analyzed. The proposed binders showed improved performance compared to conventional formulations with different electrolyte types and active materials.
ELECTROCHIMICA ACTA
(2024)