期刊
ELECTROCHIMICA ACTA
卷 55, 期 16, 页码 4789-4798出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2010.03.037
关键词
Dopamine; Zirconia; Phosphonate; Monolayers; Antifouling capability
资金
- China of Science and Technology Ministry of China [2007AA05Z143, 2007AA05Z159]
- National Natural Science Foundation of China [20873065]
- Priming Scientific Research Foundation for Advanced Talents in Nanjing Normal University [2010103XGQ0057]
Electrochemical oxidation of dopamine (DA) generally leads to electrode passivation due to accumulation of reaction products. Addition of ethylenediamine-tetramethylene phosphonic acid (EDTMP) to the supporting electrolyte can decrease the formal potential (E-0') of DA oxidation and enhance the antifouling capability of bare Au electrode due to the strong interaction between EDTMP and DA. Subsequently, an EDTMP modified zirconia films electrode is synthesized by using self-assembly method. The electrochemical measurements reveal the modified electrode possesses the excellent antifouling capability for DA oxidation and long-termed stability. In addition, the EDTMP modified zirconia films electrode can be used as a functional interface to sensitively and selectively detect DA in the presence of highly concentrated ascorbic acid (AA) due to the electrostatic interactions between the negatively charged phosphonic acid groups with DA. (C) 2010 Elsevier Ltd. All rights reserved.
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