期刊
ELECTROCHIMICA ACTA
卷 54, 期 26, 页码 6184-6189出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2009.05.087
关键词
Antioxidants; Cyclic voltammetry; 1,3-Dinitrobenzene; Homogeneous bi-molecular rate constant; Scavenging trends
资金
- Higher Education Commission, Pakistan
Interactions of five antioxidants(AO), quercetin (Q), morin (M), rutin(R), ascorbic acid (AA) and beta-carotene (beta-C) with anion radical and dianion of 1,3-dinitrobenzene (1,3-DNB) in two aprotic solvents - dimethyl formamide (DMF) and dimethyl sulfoxide (DMSO) - have been studied by cyclic voltammetry using glassy carbon electrode. Electrochemical parameters - peak potential (E-p), half-wave potential (E-1/2), and peak current (i(p)) - for the reduction of 1,3-DNB before and after the addition of various concentrations of antioxidants, were evaluated. A gradual decrease in the oxidation peak current and finally irreversibility in 1,3-DNB radical anion and dianion systems upon the addition of antioxidant, reveals their interactions. The homogeneous bi-molecular rate constant (k(2)) Was determined from electrochemical data. In comparison to all other antioxidants used, enhanced homogeneous second order rate constant for the interaction of morin with 1,3-DNB anion radical and dianion, was observed. This aspect is attributable to protonation initiated by hydrogen bonding and greater acidic nature of morin. (C) 2009 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据