Review
Engineering, Environmental
He Guo, Yawen Wang, Liuni Liao, Zhen Li, Shijia Pan, Chengdong Puyang, Yingying Su, Ying Zhang, Tiecheng Wang, Jingyu Ren, Jie Li
Summary: This review discusses the application of discharge plasma technology in soil remediation, emphasizing its significance in effectively degrading organic pollutants and preventing secondary pollution. Various aspects such as the discharge structure, influencing factors, presence of catalysts, degradation efficiency, and mechanism were analyzed and summarized. Perspectives on the challenges and opportunities in the use of discharge plasma technology for soil remediation were intensively emphasized.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Engineering, Environmental
Wenyi Yuan, Junying Xie, Xiaoyan Wang, Qing Huang, Kaiyou Huang
Summary: Mechanochemical method using ball milling and nanoscale zero-valent iron (nZVI)-CaO-Ca3(PO4)2 (NCC) showed enhanced stabilization and degradation efficiency of heavy metals (Cu, Pb, Cd) and organic pollutants (PBDEs and PCBs).
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Engineering, Environmental
Yueyue Liu, Jianping Liang, Xiongfeng Zhou, Hao Yuan, Yuwei Li, Dalei Chang, Kun Yang, Dezheng Yang
Summary: In this study, a parallel tubes-array dielectric barrier discharge reactor was developed to degrade persistent organic pollutants in soil. The results showed that the degradation efficiency of pyrene can be greatly improved by tuning the applied voltage, initial concentration, and catalysts.
CHEMICAL ENGINEERING JOURNAL
(2022)
Review
Chemistry, Multidisciplinary
Salim Boulkhessaim, Amel Gacem, Samreen Heena Khan, Abdelfattah Amari, Virendra Kumar Yadav, Hamed N. Harharah, Abubakr M. Elkhaleefa, Krishna Kumar Yadav, Sami-ullah Rather, Hyun-Jo Ahn, Byong-Hun Jeon
Summary: This review discusses the use of nanotechnology for the remediation of persistent organic pollutants (POPs). It emphasizes the importance of nanocatalysis, nanofiltration, and nanoadsorption processes. Nanoparticles such as clays, zinc oxide, and iron oxide have shown high efficiency in removing POPs. Nanofiltration and ultrafiltration have also shown potential in POPs remediation. Future research will address the cost issue of nanotechnology and make it a sustainable solution for POPs.
Review
Engineering, Environmental
Wei Lun Ang, Patrick J. McHugh, Mark D. Symes
Summary: Sonoelectrochemical pollutant degradation is a promising method for water treatment, which combines both electrochemical and ultrasonic techniques to efficiently convert pollutants into harmless substances. The synergistic effects of electrochemistry and ultrasonication lead to faster degradation rates and improved mass transport, making it an attractive approach for pollutant removal in water.
CHEMICAL ENGINEERING JOURNAL
(2022)
Review
Chemistry, Multidisciplinary
Yuxin Chen, Dan Zhi, Yaoyu Zhou, Anqi Huang, Shikang Wu, Bin Yao, Yifei Tang, Chaoran Sun
Summary: The paper reviews the progress of EK remediation technology for POPs in soil in recent years, highlighting the need for further research and evaluation of some technologies and the impact of field conditions on remediation effectiveness. Emerging technologies such as advanced oxidation and nanotechnology have demonstrated high POPs removal rates when combined with EK remediation technology.
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2021)
Article
Environmental Sciences
Kien A. Vu, Catherine N. Mulligan
Summary: This study explored the use of a biosurfactant foam/nanoparticle mixture for remediating oil-contaminated soil. The results showed that the mixture effectively removed oil contaminants, with a maximum treatment efficiency of 67%. The stability of the foam was influenced by the foam quality, biosurfactant concentration, and nanoparticle dosage.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2022)
Review
Environmental Sciences
Qing Lin, Xiaofei Tan, Eydhah Almatrafi, Yang Yang, Wenjun Wang, Hanzhuo Luo, Fanzhi Qi, Chengyun Zhou, Guangming Zeng, Chen Zhang
Summary: This study summarizes the research on the effects of biochar-based materials on soil organisms in the past ten years. It discusses the impact of these materials on the bioavailability of soil organic pollutants and highlights the potential biological effects of different types of biochar-based materials on soil organisms. Possible mechanisms are presented based on the characteristics of these materials and their environmental interactions. The study also identifies the challenges and future prospects for the risk assessment of biochar-based materials.
SCIENCE OF THE TOTAL ENVIRONMENT
(2022)
Article
Engineering, Environmental
Hafeez Ur Rahim, Muhammad Qaswar, Maolin Wang, Xudong Jing, Xiyuan Cai
Summary: This review discusses the potential of reduced sulfur species and their composites in remediation of XOCs and immobilization of heavy metal ions. These materials show promising results in degrading and detoxifying halogenated pesticides, as well as in soil and water remediation of heavy metal ions through various mechanisms. The study also proposes future research recommendations for improving sulfur-based materials and their applications in environmental remediation.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Review
Environmental Sciences
Nisha Gaur, Dhiraj Dutta, Ayushi Singh, Rama Dubey, Dev Vrat Kamboj
Summary: The growing needs of the human population are being met by rapid industrialization and globalization, resulting in severe environmental pollution by discharge of highly toxic waste, especially persistent organic pollutants. Photocatalytic degradation is a promising method to tackle these pollutants, but faces challenges such as high capital intensity and energy consumption.
FRONTIERS IN ENVIRONMENTAL SCIENCE
(2022)
Article
Engineering, Environmental
Yujie Yan, Zhang Ling, Wen Shu, Tao Huang, Rich Crane
Summary: A novel 3D electrokinetic remediation (3D EKR) system using FeOx/granular activated carbon (GAC) composite as a third electrode was studied for Cr removal from contaminated soil. The inclusion of third electrode particles in the soil improved the current density and reduced polarization compared to the conventional 2D EKR system. The enhanced oxidation of Cr(III) to Cr(VI) and electromigration towards the anode contributed to higher Cr removal.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Environmental Sciences
Guangping Fan, Zhenhua Zhang, Yuchun Ai, Yan Gao, Dongmei Zhou, Long Cang
Summary: Soil contaminated by combinations of heavy metals and organic pollutants is a prominent environmental issue. The use of electrokinetics (EK) coupled with acidic permanganate (PM) can efficiently remove co-existing pollutants, with the presence of copper and pyrene promoting the removal efficiency.
Review
Chemistry, Physical
J. Isidro, R. Lopez-Vizcaino, A. Yustres, C. Saez, V Navarro, M. A. Rodrigo
Summary: This work reviews the recent progress in physical and mathematical modelling of electrochemically assisted soil remediation processes, emphasizing the importance of modelling in understanding and managing the remediation of polluted sites. It highlights the information generated in the last few years and provides insight into the improvements made in these treatments. The article discusses the main challenges in mathematical and physical modelling and presents future trends in electrochemically assisted soil remediation modelling.
CURRENT OPINION IN ELECTROCHEMISTRY
(2022)
Article
Environmental Sciences
Daniela Negrete-Bolagay, Camilo Zamora-Ledezma, Cristina Chuya-Sumba, Frederico B. De Sousa, Daniel Whitehead, Frank Alexis, Victor H. Guerrero
Summary: Persistent Organic Pollutants (POPs) have become a serious environmental issue due to their toxicity and resistance to degradation, primarily originating from industrial and agricultural activities. This review article discusses the types, impacts, and removal methods of POPs, focusing on promising technologies such as bioremediation, advanced oxidation, ionizing radiation, and nanotechnology. Alternative approaches to control the use of pollutants and mitigate their effects on water sources are also suggested.
JOURNAL OF ENVIRONMENTAL MANAGEMENT
(2021)
Review
Chemistry, Multidisciplinary
Wukui Zheng, Tian Cui, Hui Li
Summary: Organic-contaminated soils are a major health issue, and remediation requires the use of multiple techniques. Physical-chemical methods are the most commonly used, but they are expensive and alter soil properties. Adding a biological treatment can alleviate these issues. Combined biological-microbial methods, relying on bioengineering, are a newer approach.
ENVIRONMENTAL CHEMISTRY LETTERS
(2022)
Review
Green & Sustainable Science & Technology
Mokgehle R. Letsoalo, Thandiwe Sithole, Steven Mufamadi, Zvanaka Mazhandu, Mika Sillanpaa, Ajeet Kaushik, Tebogo Mashifana
Summary: The presence of pharmaceutical contaminants (PCs) in the environment, including water and aquatic life, is a continuous threat to human health and the natural cycle. In particular, the accumulation of non-degradable water-soluble residues in water streams and groundwater has raised serious concerns and is now a focus of the United Nations' Sustainable Development Goals 2030. This article explores the challenges and potential solutions for the selective detection and efficient remediation of PCs in wastewater using nano-enabled functional systems.
JOURNAL OF CLEANER PRODUCTION
(2023)
Article
Biochemistry & Molecular Biology
Muhammad Pervaiz, Muti Ur Rehman, Faisal Ali, Umer Younas, Mika Sillanpaa, Rizwan Kausar, Asma A. Alothman, Mohamed Ouladsmane, Mohammad Abdul Mazid
Summary: Cellulose/MoS2/GO nanocomposite was synthesized using a hydrothermal method. The formation of the nanocomposite was confirmed by UV-visible and FTIR spectroscopy, and its particle size and morphology were characterized. The nanocomposite exhibited promising biomolecule protective and photocatalytic potential, making it suitable for environmental remediation.
BIOINORGANIC CHEMISTRY AND APPLICATIONS
(2023)
Article
Thermodynamics
Yiran Yang, Gang Li, Tao Luo, Mohammed Al-Bahrani, Essam A. Al-Ammar, Mika Sillanpaa, Shafaqat Ali, Xiujuan Leng
Summary: This study aims to predict building energy consumption by using neural networks such as support vector machine, gated recurrent unit, extreme learning machine, long short-term memory, and shuffled frog leaping algorithm as an optimizer. Statistical results indicate that long short-term memory and support vector machine are the best neural networks for cooling and heating load forecast, respectively.
Article
Engineering, Environmental
Mohua Li, Liang Bai, Shengtao Jiang, Mika Sillanpaa, Yingping Huang, Yanbiao Liu
Summary: Selective electrochemical reduction of oxygen (O-2) via 3e(-) pathway to produce hydroxyl radicals (HO) is a promising alternative to conventional electro-Fenton processes. A nitrogen-doped CNT-encapsulated Ni nanoparticle electrocatalyst (Ni@N-CNT) was developed, which exhibited high selectivity towards O-2 reduction and generation of HO•via 3e(-) pathway. The exposed graphitized N on the CNT shell and Ni nanoparticles encapsulated within the tip of the N-CNT played crucial roles in the generation of *HOOH through a 2e(-) oxygen reduction reaction. The encapsulated Ni nanoparticles at the tip of the N-CNT also facilitated the direct decomposition of electrogenerated *H2O2, leading to sequential generation of HO• through a 1e(-) reduction reaction on the N-CNT shell without inducing Fenton reaction. Improved bisphenol A (BPA) degradation efficiency was observed compared to conventional batch systems (97.5% vs 66.4%). Trials using Ni@N-CNT in a flow-through configuration demonstrated complete removal of BPA within 30 minutes (k = 0.12 min(-1)) with a limited energy consumption of 0.068 kW.h.g(-1) TOC.
JOURNAL OF HAZARDOUS MATERIALS
(2023)
Article
Biochemistry & Molecular Biology
Atef El Jery, Hayder Mahmood Salman, Rusul Mohammed Al-Khafaji, Maadh Fawzi Nassar, Mika Sillanpaa
Summary: Hydrogen production using polymer membrane electrolyzers is an effective method for generating environmentally friendly energy. The study analyzed the performance of the electrolyzers in the water electrolysis process and investigated the impact of variables such as radiation intensity and current density on hydrogen production. Machine-learning-based predictions were also conducted to forecast efficiency and hydrogen production rate in different scenarios.
Article
Green & Sustainable Science & Technology
Rajesh Babu Katiyar, Suresh Sundaramurthy, Anil Kumar Sharma, Suresh Arisutha, Moonis Ali Khan, Mika Sillanpaa
Summary: Urbanization and population growth lead to a substantial increase in solid waste generation. Vermicomposting, which employs earthworms to recycle solid waste, proves to be a sustainable solution. This study explores the impact of earthworm-processed solid waste manure (vermicompost) on the growth, productivity, and chemical characteristics of chili and brinjal plants in different wooden reactors. The findings reveal that polyculture reactors with vermicompost soil exhibit significantly higher yields of both chili and brinjal compared to monoculture reactors.
Article
Horticulture
Mervat A. Ali, Samir G. Farag, Mika Sillanpaa, Saleh Al-Farraj, Mohamed E. A. El-Sayed
Summary: The addition of superabsorbent polymers (SAPs) to soil improves soil properties and increases plant yields. The goal of the study was to investigate the effectiveness of SAPs in reducing mineral fertilizer usage and producing high-quality grapes. The study was conducted in a private vineyard in Egypt over three seasons and found that increasing the amount of applied polymer significantly enhanced bud burst, growth parameters, nutrient content, and yield.
Article
Chemistry, Physical
Abir Melliti, Murat Yilmaz, Mika Sillanpaa, Bechir Hamrouni, Radek Vurm
Summary: In this study, low-cost activated carbon (AC-DPF) made from date palm fiber waste was used to remove lead and copper from water systems. AC-DPF had a large surface area and high adsorption capacity, with removal efficiencies of 92% for Pb(II) and 80% for Cu(II). The adsorption kinetics and thermodynamics of AC-DPF were investigated, and competitive and antagonistic effects were observed in the multicomponent system. Overall, AC-DPF showed great potential as a highly promising, effective, and feasible adsorbent for heavy metal removal.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2023)
Article
Chemistry, Analytical
Shilpi Verma, Mamleshwar Kumar, Ramanpreet Kaur, Praveen Kumar, Mika Sillanpaa, Urska Lavrencic Stangar
Summary: This study analyzed the combustion and pyrolysis behaviors of PTA wastewater sludge and observed reaction orders, exothermic reactions, and auto gasification. The sludges were found to be promising for energy recovery due to their high calorific values. The experimental results were successfully validated using an artificial neural network model.
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
(2023)
Article
Engineering, Environmental
Jingyao Zhang, Jiadong Liu, Bo Gao, Mika Sillanpaa, Jin Han
Summary: This study utilized biochar produced from dehydrated excess sludge to catalytically ozonate pollutants from landfill leachate. The biochar contained necessary catalytic sites originating from inorganic metals and organic matters in the sludge. These sites promoted the generation of reactive oxygen species and the removal rates of pollutants were enhanced by the synergistic interaction between microorganisms. The study provides insight into the mechanism of catalytic ozonation and offers a new approach for practical landfill leachate treatment.
JOURNAL OF HAZARDOUS MATERIALS
(2023)
Article
Chemistry, Physical
Imran Ali, Yu Pakharukov, F. K. Shabiev, E. Galunin, R. F. Safargaliev, S. A. Vasiljev, B. S. Ezdin, A. E. Burakov, Zeid A. Alothman, Mika Sillanpaa
Summary: In this study, graphene-based nanofluids were synthesized and their viscosities were determined. The molecular interactions of graphene nanoparticles were theoretically analyzed to understand the mechanisms affecting the viscosity of nanofluids. An analytical function describing the dependence of the relative viscosity on the concentration of graphene nanoparticles was obtained based on experimental results. It was found that the viscosity of the nanofluid was influenced by the structure of the graphene sheets, and the self-assembly of the nanoparticles played a crucial role in the viscosity changes.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Chemistry, Physical
Anasheh Mardiroosi, Ali Reza Mahjoub, Amir Hossein Cheshme Khavar, Rabah Boukherroub, Mika Sillanpaeae, Parminder Kaur
Summary: This study synthesizes a variety of perovskite-type titanates (MTiO3, M = Zn, and Mn) and loads them onto functionalized magnetic graphene oxide (EDFG) to produce MTiO3 @EDFG nanocomposites. The materials were fully characterized, and the MTiO3 @EDFG nanocomposites were found to exhibit enhanced photocatalytic activity for the degradation of Rhodamine B under visible light irradiation. The enhanced activity was attributed to the inhibition of nanoparticle aggregation, improved electron transfer, increased surface area, and extended absorption range.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Biochemistry & Molecular Biology
Imran Ali, Anastasya Gaydukova, Tatiana Kon'kova, Zeid Abdullah ALOthman, Mika Sillanpaa
Summary: This study investigated the acid leaching process of grinding waste from a heat-resistant nickel alloy. Optimal conditions for acid dissolution were established to maximize the extraction of nickel, the main component of the alloy. These results are significant for industry professionals in metal recovery and environmentalists in waste treatment.
Review
Engineering, Civil
B. K. Pandey, C. Shukla, M. Sillanpaeae, S. K. Shukla
Summary: The aim of this study was to evaluate the global research trends in the application of electrokinetics in soil stabilization and remediation. A total of 1562 articles published from 1960 to 2022 were analyzed using the Scopus database. The results show that publication output has significantly increased in the last 5 years, with China, USA, Spain, and South Korea being the top contributing countries.
INNOVATIVE INFRASTRUCTURE SOLUTIONS
(2023)
Article
Engineering, Chemical
Shabnam Ahmadi, Soumya Ghosh, Alhadji Malloum, Mika Sillanpaa, Chinenye Adaobi Igwegbe, Prosper E. Ovuoraye, Joshua O. Ighalo
Summary: Molecular modelling and simulation were used to investigate the removal of amoxicillin (AMX) from water using iron nanoparticles (Fe3O4-NPs). The optimal conditions for adsorption were determined. The results showed that AMX molecules have high chemical potential and electrophilicity index, making them reactive. The adsorption of AMX onto Fe3O4-NPs was highly efficient under optimal conditions of pH 3, dosage of 0.5 g/L, AMX concentration of 60 mg/L, and a contact time of 60 min. Langmuir isotherm and pseudo-second-order kinetics provided the best fit to the adsorption data.
INDIAN CHEMICAL ENGINEER
(2023)
Article
Electrochemistry
Abdul Qayoom Mugheri, Shaista Khan, Ali Asghar Sangah, Aijaz Ahmed Bhutto, Muhammad Younis Laghari, Nadeem Ahmed Mugheri, Asif Ali Jamali, Arsalan Ahmed Mugheri, Nagji Sodho, Abdul Waheed Mastoi, Aftab Kandhro
Summary: Green hydrogen has the potential to transition to a pollution-free energy infrastructure. This study proposes a solution to produce hydrogen during the photoelectrochemical process, offering greater stability and control over chemical reactions. Techno-economic assessments show the efficiency and economic feasibility of co-producing value-added chemicals to enhance green hydrogen production.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Danpeng Cheng, Wuxin Sha, Qigao Han, Shun Tang, Jun Zhong, Jinqiao Du, Jie Tian, Yuan-Cheng Cao
Summary: LiNixCoyMn1-x-yO2 (NCM) is a critical cathode material for lithium-ion batteries in electric vehicles. The aging of cathode/electrolyte interfaces leads to capacity degradation and long-term cycle instability. A novel neural network model called ACGNet is developed to predict electrochemical stability windows of crystals, allowing for high-throughput screening of coating materials. LiPO3 is identified as a promising coating material with high oxidation voltage and low cost, which significantly improves the cycle stability of NCM batteries. This study demonstrates the accuracy and potential of machine learning in battery materials.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
P. Mohana, R. Yuvakkumar, G. Ravi, S. Arunmetha
Summary: This study successfully fabricates a non-noble CuO/NiO/rGO nanocomposite and investigates its electrocatalytic performance for oxygen evolution reaction in alkaline environment. The experimental results demonstrate that the electrocatalyst exhibits high activity and good stability, offering a new synthetic approach for sustainable energy production.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Qiong Qu, Jing Guo, Hongyu Wang, Kai Zhang, Jingde Li
Summary: In this study, a bifunctional electrode host design consisting of carbon nanofibers implanted ordered porous Co-decorated Al2O3 supported on carbon nanotube film (CNTF) was proposed to address the shuttling effect of lithium polysulfides (LiPSs) and dendrite formation of metal lithium anode in lithium-sulfur (Li-S) batteries. The electrode exhibited excellent conductivity, efficient confinement of LiPSs, and catalytic conversion performance, resulting in high initial capacity and good capacity retention during cycling. As an anode, the electrode showed excellent Li+ diffusion performance and uniform lithium growth behavior, achieving a dendrite-free lithium electrode. The flexible pack cell assembled from these electrodes delivered a specific capacity of 972 mAh g(-1) with good capacity retention.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Hong Zhang, Jin-Peng Yu, Chen Chen, Cheng-Yong Shu, Guang-Yu Xu, Jie Ren, Kai Cui, Wen-Fang Cai, Yun-Hai Wang, Kun Guo
Summary: Spray coating of acetylene black nanoparticles onto stainless steel mesh can enhance its biofilm formation ability and current density, making it a promising electrode material for microbial electrochemical systems. The spray coating method is simple, cost-effective, and suitable for large-size stainless steel electrodes.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Binpeng Hou, Jingjin Chen, Li-Hong Zhang, Xiaowen Shi, Zizhong Zhu
Summary: The electrochemical performance of Li1.20Mn0.44Ni0.32Co0.04O2 and its oxygen-deficient phase Li1.20Mn0.44Ni0.32Co0.04O1.83 was studied through first-principles calculations. The results show that the oxygen-deficient phase has a higher theoretical capacity but lower voltage platform and higher chemical activity compared to the pristine phase.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Yating Du, Sayoko Shironita, Daisuke Asakura, Eiji Hosono, Yoshitsugu Sone, Yugo Miseki, Eiichi Kobayashi, Minoru Umeda
Summary: This study investigates the effect of high- and low-temperature environments on the charge-discharge performance of a Li-ion battery. The deterioration mechanisms of the battery at different temperatures are analyzed through various characterization techniques. The results indicate that the battery performance deteriorates more significantly at a low-temperature environment of 5 degrees C compared to higher temperatures. The understanding of the deterioration mechanisms can contribute to the development of safer battery usage methods.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Si-Si Shi, Zhi-Xiang Yuan, Fei Zhang, Ping Chen
Summary: In this study, a new nano-electrocatalyst was prepared, which exhibited superior electrocatalytic activity for the reduction of NO2- to ammonia in a neutral electrolyte, potentially due to the synergistic enhancement between Co3O4-x and Co.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Berna Dalkiran, Havva Bekirog
Summary: This study reports the use of deep eutectic solvents (DES) based on ethylene glycol and urea as low-cost and green electrolytes for enhancing electrochemical detection of natural antioxidants. The study successfully developed a disposable and effective electrochemical sensing platform for simultaneous determination of ascorbic acid (AA) and gallic acid (GA) using NaOH nanorods on a pencil graphite electrode. The proposed electrode showed improved analytical performance, with higher peak currents and shifted oxidation potentials in DES compared to BR buffer medium.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Sijun Ren, Jianguo Huang
Summary: In this study, a novel bio-inspired nanofibrous WO3/carbon composite was synthesized using a facile hydrothermal method. The three-dimensional network structure of the composite alleviated the volume expansion of WO3 nanorods and enhanced the charge-transport kinetics. The optimized composite exhibited superior lithium storage properties.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Zhilong Zheng, Yu Chen, Hongxia Yin, Hengbo Xiao, Xiangji Zhou, Zhiwen Li, Ximin Li, Jin Chen, Songliu Yuan, Junjie Guo, Haibin Yu, Zhen Zhang, Lihua Qian
Summary: This study found that interstitial Zn cations in CoMoO4 can modulate the dissolution kinetics of Mo cations and improve the OER performance. The interstitial Zn cations can prevent the dissolution of Co cations at high potential, enhancing the durability of the catalyst.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Xiaobo Lin, Shern R. Tee, Debra J. Searles, Peter T. Cummings
Summary: Molecular dynamics simulations using the constant potential method were used to investigate the charging dynamics and charge storage of supercapacitors. The simulations revealed that the water-in-salt electrolyte exhibited the highest charge storage and significantly higher capacitance on the negative electrode. The varying contributions of different electrode regions to supercapacitor performance were also demonstrated.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Wiktoria Lipinska, Vita Saska, Katarzyna Siuzdak, Jakub Karczewski, Karol Zaleski, Emerson Coy, Anne de Poulpiquet, Ievgen Mazurenko, Elisabeth Lojou
Summary: The spatial distribution of enzymes on electrodes is important for bioelectrocatalysis. In this study, controlled spatial distribution of gold nanoparticles on Ti nanodimples was achieved. The efficiency of enzymatic O2 reduction was found to be influenced by the size of the gold nanoparticles and their colocalization with TiO2. The highest stability of enzymatic current was observed with the largest gold nanoparticles.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Tariq M. Al-Hejri, Zeenat A. Shaikh, Ahmed H. Al-Naggar, Siddheshwar D. Raut, Tabassum Siddiqui, Hamdan M. Danamah, Vijaykumar V. Jadhav, Abdullah M. Al-Enizi, Rajaram S. Mane
Summary: This study explores a promising self-growth approach for the synthesis of nickel hydroxide (Ni(OH)2) nanosponge-balls on the surface of a nickel-foam (NiF) electrode. The modified NiF electrode, named Ni(OH)2@NiF, shows distinctive nanosponge-ball morphology and demonstrates excellent energy storage capability and electrocatalytic performance in both hydrogen and oxygen evolution reactions.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Rafael Del Olmo, Gregorio Guzman-Gonzalez, Oihane Sanz, Maria Forsyth, Nerea Casado
Summary: The use of Lithium-Ion Batteries (LIBs) is becoming increasingly extensive, and it is important to optimize the devices to achieve their maximum practical specific capacity. In this study, mixed ionic-electronic conducting (MIEC) binders based on PEDOT:PSS and PEDOT: PDADMA-TFSI were developed for Li-ion cathodes, and their performance was compared with conventional formulations. The influence of electrode formulations, including the addition of conducting carbon and an Organic Ionic Plastic Cristal (OIPC), was also analyzed. The proposed binders showed improved performance compared to conventional formulations with different electrolyte types and active materials.
ELECTROCHIMICA ACTA
(2024)
