Article
Electrochemistry
Lorlyn Reidy, Chen Wang, Charles L. Hussey
Summary: The anodic dissolution of copper in chloroaluminate ionic liquids was studied, revealing different reaction mechanisms in Lewis acidic and basic compositions. In Lewis acidic IL, the reaction is under mixed kinetic-mass transport control, while in basic IL, the reaction transitions to mass transport control with the formation of [CuCl2](-).
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2021)
Article
Environmental Sciences
Hassan H. Shaarawy, Hala S. Hussein, Nabila H. Hussien, Ghada A. Al Bazedi, Salwa Hawash
Summary: This study presents the results of preparing nanometric titanium dioxide through anodic dissolution and calcination process. The optimized anodic dissolution conditions and thermal calcination process resulted in high-purity anatase titanium dioxide nanopowder. The chemical and physical characterizations confirmed the potential applications of these nanoparticles in photocatalysis, semiconductors, and wastewater treatment.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Article
Engineering, Environmental
Yushuai Sang, Yuhan Ma, Gen Li, Kai Cui, Mingze Yang, Hong Chen, Yongdan Li
Summary: The dissolution and solvolysis processes of enzymatic hydrolysis lignin (EHL) in ethylene glycol were investigated. Ethylene glycol exhibited high EHL solubility and achieved complete EHL dissolution at room temperature. The interactions between ethylene glycol and EHL, such as van de Waals interactions, were found to break the pi-pi stacking in EHL, resulting in complete EHL dissolution. When NaOH and Ni were used as co-catalysts, EHL was efficiently depolymerized at 200 degrees C, and the overall monomer yield reached 18.8 wt%. Fourier transform infrared spectroscopy (FT-IR) and molecular dynamics simulation results showed that the adsorption of ethylene glycol over Ni surface hindered the adsorption of lignin fragments and monomers. Thus, EHL catalytic solvolysis in ethylene glycol occurred in the liquid phase, where OH- of NaOH promoted the EHL linkage breakage and active hydrogen atoms formed on Ni surface stabilized the active monomers.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Electrochemistry
Mohammad Ebrahim Haji Naghi Tehrani, Hojat Naderi, Fereshteh Rashchi
Summary: The research demonstrates that adding a certain proportion of ethylene glycol can decrease the dissolution rate of chalcopyrite in sulfuric acid, but excessive ethylene glycol will increase the dissolution rate. In addition, adding iron ions can affect the polarization impedance value and exacerbate the dissolution rate.
ELECTROCHIMICA ACTA
(2021)
Article
Chemistry, Physical
Takuma Kureha, Kazuma Takahashi, Mion Kino, Hikaru Kida, Takuto Hirayama
Summary: A new strategy of controlling the toughness of hydrogels by modulating the side-chain length has been discovered. In this study, this strategy was applied to biocompatible poly(oligo(ethylene glycol) methyl ether methacrylate) with long ethylene-oxide side chains.
Article
Chemistry, Analytical
Sergio Cancho-Gonzalez, Paul Ferguson, Julie M. Herniman, G. John Langley
Summary: Poly(ethylene glycols) are complex polymers commonly added to pharmaceutical formulations for improved drug solubility and delivery. This study employs a supercritical fluid chromatography-mass spectrometry approach to selectively ionize poly(ethylene glycols) as ammoniated molecules, simplifying data analysis and enabling batch-to-batch comparisons.
JOURNAL OF SEPARATION SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Rubi Resendiz-Ramirez, Aaron Rodriguez-Lopez, Jesus A. Diaz-Real, Humberto F. Delgado-Arenas, Azucena Osornio-Villa, Rosalba Hernandez-Leos, Vincent Vivier, Rene Antano-Lopez
Summary: This study investigates the electrochemical synthesis of magnetite nanoparticles through analysis of electrochemical impedance spectroscopy (EIS). Three models are proposed and their EIS spectra predicted, with a new model involving up to three adsorbed intermediate species providing the best fit to experimental data. However, the existing mechanisms do not fully explain all experimental results, highlighting the need for further refinement in understanding the reaction mechanism.
Article
Energy & Fuels
S. Ibeh, P. Jaeger
Summary: The study analyzes the interfacial tension, fluid mixture densities and drop volumes of TEG and TEG + water in CO(2) medium. The static interfacial tension of TEG-CO2 and TEG + water-CO2 shows a decreasing trend as the pressure increases, but it strongly increases with higher temperatures. Dynamic interfacial tension reaches a constant value after a certain time, and the drop volume increases with a volumetric expansion. Static values of interfacial tension can be applied with reasonable precision for process design.
JOURNAL OF PETROLEUM EXPLORATION AND PRODUCTION TECHNOLOGY
(2023)
Article
Materials Science, Multidisciplinary
Yuecheng Dong, Shuai Huang, Yuyang Wang, Biao Zhang, I. V. Alexandrov, Hui Chang, Zhenhua Dan, Li Ma, Lian Zhou
Summary: In this study, stress corrosion cracking (SCC) of TC4 ELI alloy in 3.5% NaCl solution was investigated using slow strain rate test (SSRT) with an in-site electrochemical experiment. The results showed that both lamellar microstructure (LM) and equiaxed microstructure (EM) of TC4 ELI alloy exhibited a certain stress corrosion sensitivity at specific strain rates, with higher sensitivity observed in the LM. The higher alpha phase content and presence of triangular grain boundaries in the LM were attributed to the increased stress corrosion sensitivity.
MATERIALS CHARACTERIZATION
(2022)
Article
Multidisciplinary Sciences
Yan-Hom Li, Yen-Ju Chen
Summary: The study explores the impact of magnetic field configuration on gas bubble movement from platinum electrodes. Oxygen and hydrogen bubbles exhibit different behaviors in the magnetic field, enhancing electrolysis efficiency. Optimal electrode and magnetic field layout can increase conductivity and effectiveness of water electrolysis.
SCIENTIFIC REPORTS
(2021)
Article
Chemistry, Multidisciplinary
Ekkachai Martwong, Yvette Tran
Summary: The study reports on the synthesis and temperature-responsive properties of poly(PEGMA) hydrogel thin films. Surface-attached poly(PEGMA) hydrogel films were synthesized using a simple, versatile, and well-controlled thiol-ene click reaction method, with the transition temperature finely tunable by adjusting the number of PEG units. The LCST properties of the hydrogel films are not sensitive to salt, holding promise for applications in biology such as injectable hydrogels, drug delivery systems, microfluidic valves, and flow switches for biotechnologies.
Article
Chemistry, Physical
Milad Moradi, Hossein Sayari, Fleming Martinez, Hongkun Zhao, Jalal Hanaee, Elaheh Rahimpour, Abolghasem Jouyban
Summary: The research determined the equilibrium solubility of naproxen in ethylene glycol+water at different temperatures using various mathematical models. The apparent thermodynamic quantities of the dissolution and solvation processes were calculated, and preferential solvation parameters of NAP by EG molecules were estimated based on inverse Kirkwood-Buff integrals.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Chemistry, Physical
Atefeh Sheikhi-Sovari, Abolghasem Jouyban, Fleming Martinez, Salar Hemmati, Elaheh Rahimpour
Summary: The solubility of mesalazine in ethylene glycol-water mixtures was studied at different temperatures, showing an increase with higher ethylene glycol mass fraction. The solubility also increased with temperature variations. Five solubility models were used to correlate experimental data and investigate accuracy. Additionally, apparent thermodynamic properties were calculated and discussed. Mesalazine was observed to be preferentially solvated by water and ethylene glycol in certain mixtures.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Chemistry, Physical
Abhishek Kumar, Ritu Bhardwaj, Joyanta Choudhury
Summary: This research successfully established a catalytic transfer hydrogenation process for the conversion of chemically captured CO2 into MeOH using ethylene glycol as the hydride donor. The Ru(II)-CNN pincer catalyst and TMEDA were found to be the most effective combination, resulting in a MeOH yield of up to 64% and 112 catalytic turnovers. The use of a dilute CO2 stream (10% in N2) also provided a similar MeOH yield of approximately 70% in this integrated protocol.
Article
Materials Science, Multidisciplinary
Jixiang Xu, Jun Ou, Chris D. Lane, Steve L. Cockcroft, Daan M. Maijer, Ainul Akhtar, Yossi Marciano
Summary: The dissolution behavior of Ti-N solids in liquid titanium was investigated using experimental and numerical methods. The study found that the volume fraction of dissolved solid increases with increasing immersion time. A numerical model was developed to accurately predict the volume loss for different immersion times and derived an effective mass transfer coefficient.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2022)
Article
Biochemistry & Molecular Biology
Kenji Tajima, Koutaro Tahara, Junya Ohba, Ryo Kusumoto, Ryota Kose, Hiroyuki Kono, Tokuo Matsushima, Koji Fushimi, Takuya Isono, Takuya Yamamoto, Toshifumi Satoh
Article
Chemistry, Inorganic & Nuclear
Yuichi Kitagawa, Marina Kumagai, Takayuki Nakanishi, Koji Fushimi, Yasuchika Hasegawa
INORGANIC CHEMISTRY
(2020)
Article
Chemistry, Multidisciplinary
Yuichi Kitagawa, Marina Kumagai, Pedro Paulo Ferreira da Rosa, Koji Fushimi, Yasuchika Hasegawa
Summary: A design for an efficient molecular luminescent thermometer based on long-range electronic coupling in lanthanide coordination polymers was proposed. By controlling the electronic coupling through changing the concentration of Gd-III ion in the coordination polymers, enhanced temperature sensing properties were achieved.
CHEMISTRY-A EUROPEAN JOURNAL
(2021)
Article
Chemistry, Multidisciplinary
Yuichi Kitagawa, Satoshi Wada, M. D. Jahidul Islam, Kenichiro Saita, Masayuki Gon, Koji Fushimi, Kazuo Tanaka, Satoshi Maeda, Yasuchika Hasegawa
COMMUNICATIONS CHEMISTRY
(2020)
Article
Electrochemistry
Akihiro Fujimura, Yuichi Kitagawa, Yasuchika Hasegawa, Takashi Doi, Koji Fushimi
Summary: Electrochemical ellipso-microscopy combined with the channel flow triple electrode method was used to evaluate the active-passive transition behavior of Fe-6% Cr in acidic sodium sulfate solutions. The study found that forced convection of the electrolyte solution affected the mass-transport process of Cr(III) species on the SE surface in the latter half of the active region.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2021)
Article
Multidisciplinary Sciences
Pedro Paulo Ferreira da Rosa, Yuichi Kitagawa, Sunao Shoji, Hironaga Oyama, Keisuke Imaeda, Naofumi Nakayama, Koji Fushimi, Hidehiro Uekusa, Kosei Ueno, Hitoshi Goto, Yasuchika Hasegawa
Summary: Soft-crystal copolymerization of Tb(III) and Dy(III) complexes is achieved, and long-range energy transfer from one crystal to the other is studied.
NATURE COMMUNICATIONS
(2022)
Article
Electrochemistry
Akihiro Fujimura, Sunao Shoji, Yuichi Kitagawa, Yasuchika Hasegawa, Takashi Doi, Koji Fushimi
Summary: A quasi-on-time system for analyzing electrode reaction products is developed by combining ICP-OES with a hydrodynamic electrochemical technique. The shorter the distance between the electrode end and the OES detector, the shorter the time response and the higher the detection efficiency (98.1%). Application of this system to analyze reaction species generated from a Cu electrode in a chloride-containing solution demonstrates the effective inhibition of Cu dissolution by adding BTA above a critical concentration of 10 mol m-3.
ELECTROCHIMICA ACTA
(2022)
Article
Chemistry, Physical
Sourav Kr. Saha, Tomoya Takano, Koji Fushimi, Masatoshi Sakairi, Ryosuke Saito
Summary: The curing behavior of cement paste and formation of passive film on iron were studied using electrochemical techniques and X-ray photoelectron spectroscopy (XPS). The open circuit potential of iron was monitored in cement paste with a pH of -13 for 56 days, and the results showed that the iron was kept in a passive state. The results of electrochemical impedance spectroscopy revealed an increasing trend of film and cement paste resistance with curing time. XPS analysis provided evidence that the formation of ferric hydroxide and ferric oxide was efficient in passivating the iron. The iron surface receded from corrosion due to the high-alkaline environment of cement paste and the formation of a passive film.
SURFACES AND INTERFACES
(2023)
Article
Electrochemistry
K. Fushimi, H. Yanagimoto, S. Nakatsuji, S. Shoji, Y. Kitagawa, Y. Hasegawa, K. Baba
Summary: A liquid-phase ion gun (LPIG) was used to create a local H2S enriched environment near the surface of Cr-containing steel in Na2S solutions, aiming to induce sulfide stress cracking on the specimen surface. Acidification of the local solution below pH 4, creating a pseudo-sour environment, was achieved by anodically polarizing the LPIG Pt microelectrode at a potential of 1.90 V vs SHE in a 1.5 mM Na2S solution. Under this pseudo-sour environment, sulfides were formed on the specimen surface depending on the concentration of Cr, specimen potential, and chloride ion in solution. When subjected to tensile stress and operated with LPIG, cracks were formed on the surface of Cr-containing steels using a four-point bending tester.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2023)
Article
Chemistry, Multidisciplinary
Yuichi Kitagawa, Kaori Shima, Takuma Nakai, Marina Kumagai, Shun Omagari, Pedro Paulo Ferreira da Rosa, Sunao Shoji, Koji Fushimi, Yasuchika Hasegawa
Summary: In this study, a photosensitizer design strategy using a dinuclear luminescent lanthanide complex was demonstrated, which exhibited thermally-assisted photosensitized emission. The complex consisted of Tb(III) ions, six tetramethylheptanedionates, and a phosphine oxide bridge containing a phenanthrene frameworks. The phenanthrene ligand and Tb(III) ions acted as the energy donor and acceptor parts, respectively. The efficient thermally-assisted photosensitized emission of the Tb(III) acceptor resulted in a pure-green colored emission with a high photosensitized emission quantum yield of 73%.
COMMUNICATIONS CHEMISTRY
(2023)
Article
Electrochemistry
Yudai Yamamoto, Andrei Ionut Mardare, Jan Philipp Kollender, Cezarina Cela Mardare, Dominik Recktenwald, Koji Fushimi, Achim Walter Hassel
Summary: An aluminium-samarium binary library was produced using a thermal co-evaporation technique, showing changes in surface structure and atomic arrangements with increasing Sm content. Nucleation of AlSm2 intermetallic phase was observed above a Sm concentration threshold of 8 at.%. Samarium was found to contribute to anodization process, with increased dissolution rates at Sm concentrations above the threshold.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2021)
Article
Chemistry, Multidisciplinary
Yuichi Kitagawa, Fumiya Suzue, Takayuki Nakanishi, Koji Fushimi, Tomohiro Seki, Hajime Ito, Yasuchika Hasegawa
COMMUNICATIONS CHEMISTRY
(2020)
Article
Chemistry, Inorganic & Nuclear
Makoto Tsurui, Yuichi Kitagawa, Koji Fushimi, Masayuki Gon, Kazuo Tanaka, Yasuchika Hasegawa
DALTON TRANSACTIONS
(2020)
Article
Chemistry, Inorganic & Nuclear
Yuichi Kitagawa, Marina Kumagai, P. P. Ferreira da Rosa, Koji Fushimi, Yasuchika Hasegawa
DALTON TRANSACTIONS
(2020)
Article
Chemistry, Inorganic & Nuclear
Yuichi Kitagawa, Marina Kumagai, Takayuki Nakanishi, Koji Fushimi, Yasuchika Hasegawa
DALTON TRANSACTIONS
(2020)
Article
Electrochemistry
Abdul Qayoom Mugheri, Shaista Khan, Ali Asghar Sangah, Aijaz Ahmed Bhutto, Muhammad Younis Laghari, Nadeem Ahmed Mugheri, Asif Ali Jamali, Arsalan Ahmed Mugheri, Nagji Sodho, Abdul Waheed Mastoi, Aftab Kandhro
Summary: Green hydrogen has the potential to transition to a pollution-free energy infrastructure. This study proposes a solution to produce hydrogen during the photoelectrochemical process, offering greater stability and control over chemical reactions. Techno-economic assessments show the efficiency and economic feasibility of co-producing value-added chemicals to enhance green hydrogen production.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Danpeng Cheng, Wuxin Sha, Qigao Han, Shun Tang, Jun Zhong, Jinqiao Du, Jie Tian, Yuan-Cheng Cao
Summary: LiNixCoyMn1-x-yO2 (NCM) is a critical cathode material for lithium-ion batteries in electric vehicles. The aging of cathode/electrolyte interfaces leads to capacity degradation and long-term cycle instability. A novel neural network model called ACGNet is developed to predict electrochemical stability windows of crystals, allowing for high-throughput screening of coating materials. LiPO3 is identified as a promising coating material with high oxidation voltage and low cost, which significantly improves the cycle stability of NCM batteries. This study demonstrates the accuracy and potential of machine learning in battery materials.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
P. Mohana, R. Yuvakkumar, G. Ravi, S. Arunmetha
Summary: This study successfully fabricates a non-noble CuO/NiO/rGO nanocomposite and investigates its electrocatalytic performance for oxygen evolution reaction in alkaline environment. The experimental results demonstrate that the electrocatalyst exhibits high activity and good stability, offering a new synthetic approach for sustainable energy production.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Qiong Qu, Jing Guo, Hongyu Wang, Kai Zhang, Jingde Li
Summary: In this study, a bifunctional electrode host design consisting of carbon nanofibers implanted ordered porous Co-decorated Al2O3 supported on carbon nanotube film (CNTF) was proposed to address the shuttling effect of lithium polysulfides (LiPSs) and dendrite formation of metal lithium anode in lithium-sulfur (Li-S) batteries. The electrode exhibited excellent conductivity, efficient confinement of LiPSs, and catalytic conversion performance, resulting in high initial capacity and good capacity retention during cycling. As an anode, the electrode showed excellent Li+ diffusion performance and uniform lithium growth behavior, achieving a dendrite-free lithium electrode. The flexible pack cell assembled from these electrodes delivered a specific capacity of 972 mAh g(-1) with good capacity retention.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Hong Zhang, Jin-Peng Yu, Chen Chen, Cheng-Yong Shu, Guang-Yu Xu, Jie Ren, Kai Cui, Wen-Fang Cai, Yun-Hai Wang, Kun Guo
Summary: Spray coating of acetylene black nanoparticles onto stainless steel mesh can enhance its biofilm formation ability and current density, making it a promising electrode material for microbial electrochemical systems. The spray coating method is simple, cost-effective, and suitable for large-size stainless steel electrodes.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Binpeng Hou, Jingjin Chen, Li-Hong Zhang, Xiaowen Shi, Zizhong Zhu
Summary: The electrochemical performance of Li1.20Mn0.44Ni0.32Co0.04O2 and its oxygen-deficient phase Li1.20Mn0.44Ni0.32Co0.04O1.83 was studied through first-principles calculations. The results show that the oxygen-deficient phase has a higher theoretical capacity but lower voltage platform and higher chemical activity compared to the pristine phase.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Yating Du, Sayoko Shironita, Daisuke Asakura, Eiji Hosono, Yoshitsugu Sone, Yugo Miseki, Eiichi Kobayashi, Minoru Umeda
Summary: This study investigates the effect of high- and low-temperature environments on the charge-discharge performance of a Li-ion battery. The deterioration mechanisms of the battery at different temperatures are analyzed through various characterization techniques. The results indicate that the battery performance deteriorates more significantly at a low-temperature environment of 5 degrees C compared to higher temperatures. The understanding of the deterioration mechanisms can contribute to the development of safer battery usage methods.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Si-Si Shi, Zhi-Xiang Yuan, Fei Zhang, Ping Chen
Summary: In this study, a new nano-electrocatalyst was prepared, which exhibited superior electrocatalytic activity for the reduction of NO2- to ammonia in a neutral electrolyte, potentially due to the synergistic enhancement between Co3O4-x and Co.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Berna Dalkiran, Havva Bekirog
Summary: This study reports the use of deep eutectic solvents (DES) based on ethylene glycol and urea as low-cost and green electrolytes for enhancing electrochemical detection of natural antioxidants. The study successfully developed a disposable and effective electrochemical sensing platform for simultaneous determination of ascorbic acid (AA) and gallic acid (GA) using NaOH nanorods on a pencil graphite electrode. The proposed electrode showed improved analytical performance, with higher peak currents and shifted oxidation potentials in DES compared to BR buffer medium.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Sijun Ren, Jianguo Huang
Summary: In this study, a novel bio-inspired nanofibrous WO3/carbon composite was synthesized using a facile hydrothermal method. The three-dimensional network structure of the composite alleviated the volume expansion of WO3 nanorods and enhanced the charge-transport kinetics. The optimized composite exhibited superior lithium storage properties.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Zhilong Zheng, Yu Chen, Hongxia Yin, Hengbo Xiao, Xiangji Zhou, Zhiwen Li, Ximin Li, Jin Chen, Songliu Yuan, Junjie Guo, Haibin Yu, Zhen Zhang, Lihua Qian
Summary: This study found that interstitial Zn cations in CoMoO4 can modulate the dissolution kinetics of Mo cations and improve the OER performance. The interstitial Zn cations can prevent the dissolution of Co cations at high potential, enhancing the durability of the catalyst.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Xiaobo Lin, Shern R. Tee, Debra J. Searles, Peter T. Cummings
Summary: Molecular dynamics simulations using the constant potential method were used to investigate the charging dynamics and charge storage of supercapacitors. The simulations revealed that the water-in-salt electrolyte exhibited the highest charge storage and significantly higher capacitance on the negative electrode. The varying contributions of different electrode regions to supercapacitor performance were also demonstrated.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Wiktoria Lipinska, Vita Saska, Katarzyna Siuzdak, Jakub Karczewski, Karol Zaleski, Emerson Coy, Anne de Poulpiquet, Ievgen Mazurenko, Elisabeth Lojou
Summary: The spatial distribution of enzymes on electrodes is important for bioelectrocatalysis. In this study, controlled spatial distribution of gold nanoparticles on Ti nanodimples was achieved. The efficiency of enzymatic O2 reduction was found to be influenced by the size of the gold nanoparticles and their colocalization with TiO2. The highest stability of enzymatic current was observed with the largest gold nanoparticles.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Tariq M. Al-Hejri, Zeenat A. Shaikh, Ahmed H. Al-Naggar, Siddheshwar D. Raut, Tabassum Siddiqui, Hamdan M. Danamah, Vijaykumar V. Jadhav, Abdullah M. Al-Enizi, Rajaram S. Mane
Summary: This study explores a promising self-growth approach for the synthesis of nickel hydroxide (Ni(OH)2) nanosponge-balls on the surface of a nickel-foam (NiF) electrode. The modified NiF electrode, named Ni(OH)2@NiF, shows distinctive nanosponge-ball morphology and demonstrates excellent energy storage capability and electrocatalytic performance in both hydrogen and oxygen evolution reactions.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Rafael Del Olmo, Gregorio Guzman-Gonzalez, Oihane Sanz, Maria Forsyth, Nerea Casado
Summary: The use of Lithium-Ion Batteries (LIBs) is becoming increasingly extensive, and it is important to optimize the devices to achieve their maximum practical specific capacity. In this study, mixed ionic-electronic conducting (MIEC) binders based on PEDOT:PSS and PEDOT: PDADMA-TFSI were developed for Li-ion cathodes, and their performance was compared with conventional formulations. The influence of electrode formulations, including the addition of conducting carbon and an Organic Ionic Plastic Cristal (OIPC), was also analyzed. The proposed binders showed improved performance compared to conventional formulations with different electrolyte types and active materials.
ELECTROCHIMICA ACTA
(2024)