A kinetico-mechanistic study on the C–H bond activation of primary benzylamines; cooperative and solid-state cyclopalladation on dimeric complexes

Ligand-Controlled C(sp3)-H Arylation and Olefination in Synthesis of Unnatural Chiral  -Amino Acids

(2014) J. He et al.   SCIENCE

Cyclopalladation and Reactivity of Amino Esters through CH Bond Activation: Experimental, Kinetic, and Density Functional Theory Mechanistic Studies

(2013) Eduardo Laga et al.   CHEMISTRY-A EUROPEAN JOURNAL

Dicyclopalladated Complexes of Asymmetrically Substituted Azobenzenes: Synthesis, Kinetics and Mechanisms

(2013) Marina Juribašić et al.   INORGANIC CHEMISTRY

NH2 As a Directing Group: From the Cyclopalladation of Amino Esters to the Preparation of Benzolactams by Palladium(II)-Catalyzed Carbonylation of N-Unprotected Arylethylamines

(2013) Joan Albert et al.   ORGANOMETALLICS

Insertion of benzyne into the Pd–C bond. Synthesis of unnatural amino acid derivatives by sequential insertion of benzyne and CO: 2,2′-functionalized biaryls containing alkylamino and carboxymethyl substituents. Isolation of stable carbopalladated-benzyne intermediates

(2012) José-Antonio García-López et al.   CHEMICAL COMMUNICATIONS

A DFT and TD-DFT Approach to the Understanding of Statistical Kinetics in Substitution Reactions of M3Q4 (M=Mo, W; Q=S, Se) Cuboidal Clusters

(2012) Andrés G. Algarra et al.   CHEMISTRY-A EUROPEAN JOURNAL

Providing Support in Favor of the Existence of a PdII/PdIVCatalytic Cycle in a Heck-Type Reaction

(2012) Francisco Juliá-Hernández et al.   CHEMISTRY-A EUROPEAN JOURNAL

Kinetico-mechanistic studies of cyclometalating C–H bond activation reactions on Pd(ii) and Rh(ii) centres: The importance of non-innocent acidic solvents in the process

(2012) Jaume Granell et al.   DALTON TRANSACTIONS

Characterization of DMSO Coordination to Palladium(II) in Solution and Insights into the Aerobic Oxidation Catalyst, Pd(DMSO)2(TFA)2

(2012) Tianning Diao et al.   INORGANIC CHEMISTRY

New Insights in the Formation of Five- Versus Seven-Membered Platinacycles: A Kinetico-Mechanistic Study

(2012) Paul V. Bernhardt et al.   INORGANIC CHEMISTRY

Understanding Reactivity and Stereoselectivity in Palladium-Catalyzed Diastereoselective sp3 C–H Bond Activation: Intermediate Characterization and Computational Studies

(2012) Ramesh Giri et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Connecting Binuclear Pd(III) and Mononuclear Pd(IV) Chemistry by Pd–Pd Bond Cleavage

(2012) David C. Powers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of remote meta-C–H bonds assisted by an end-on template

(2012) Dasheng Leow et al.   NATURE

High-valent organometallic copper and palladium in catalysis

(2012) Amanda J. Hickman et al.   NATURE

Ortho Palladation of the Phenethylamines of Biological Relevance l-Tyrosine Methyl Ester and Homoveratrylamine. Reactivity of the Palladacycles toward CO and Isocyanides. Synthesis of the Natural Alkaloid Corydaldine

(2012) María-José Oliva-Madrid et al.   ORGANOMETALLICS

Kinetico-Mechanistic Studies on Intramolecular C–X Bond Activation (X = Br, Cl) of Amino-Imino Ligands on Pt(II) Compounds. Prevalence of a Concerted Mechanism in Nonpolar, Polar, and Ionic Liquid Media

(2012) Teresa Calvet et al.   ORGANOMETALLICS

Synthesis of a Palladium(IV) Complex by Oxidative Addition of an Aryl Halide to Palladium(II) and Its Use as Precatalyst in a CC Coupling Reaction

(2011) José Vicente et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective Orthopalladation of (Z)-2-Aryl-4-Arylidene-5(4H)-Oxazolones: Scope, Kinetico-Mechanistic, and Density Functional Theory Studies of the C–H Bond Activation

(2011) Gheorghe-Doru Roiban et al.   INORGANIC CHEMISTRY

Structure of Complexes Formed by Dissolution of Palladium Diacetate in Methanol and Chloroform. In Situ NMR Study

(2011) Valentina M. Nosova et al.   INORGANIC CHEMISTRY

Sensitive and Selective Chromogenic Sensing of Carbon Monoxide via Reversible Axial CO Coordination in Binuclear Rhodium Complexes

(2011) María E. Moragues et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A New Method for High-Yield Cyclopalladation of Primary and Secondary Amines. Atom-Efficient Open-to-Air Inexpensive Synthesis of Buchwald-Type Precatalysts

(2011) José Vicente et al.   ORGANOMETALLICS

Participation of Carbonyl Oxygen in Carbon–Carboxylate Bond-Forming Reductive Elimination from Palladium

(2011) J. Brannon Gary et al.   ORGANOMETALLICS

Preparation of benzolactams by Pd(ii)-catalyzed carbonylation of N-unprotected arylethylamines

(2010) Blanca López et al.   CHEMICAL COMMUNICATIONS

Emergence of Palladium(IV) Chemistry in Synthesis and Catalysis

(2010) Petr Sehnal et al.   CHEMICAL REVIEWS

C—H Bond Activation in Transition Metal Species from a Computational Perspective

(2010) David Balcells et al.   CHEMICAL REVIEWS

Kinetico-Mechanistic Study of the Thermal Cis-to-Trans Isomerization of 4,4′-Dialkoxyazoderivatives in Nematic Liquid Crystals

(2010) Jaume Garcia-Amorós et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Mechanism of C−F Reductive Elimination from Palladium(IV) Fluorides

(2010) Takeru Furuya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Eight-Membered Palladacycles Derived from the Insertion of Olefins into the Pd−C Bond of Ortho-Palladated Pharmaceuticals Phenethylamine and Phentermine. Synthesis of Stable Heck-Type Intermediates Containing Accessible β-Hydrogens and Its Use in the Synthesis of 2-Styrylphenethylamines, Tetrahydroisoquinolines, and Eight-Membered Cyclic Amidines†

(2010) José Vicente et al.   ORGANOMETALLICS

Cyclometallation of amino-imines on palladium complexes. The effect of the solvent on the experimental and calculated mechanism

(2009) Gabriel Aullón et al.   DALTON TRANSACTIONS

Organopalladium and platinum chemistry in oxidising milieu as models for organic synthesis involving the higher oxidation states of palladium

(2009) Allan J. Canty   DALTON TRANSACTIONS

Effect of Ligand Steric Properties and Halide Identity on the Mechanism for Oxidative Addition of Haloarenes to Trialkylphosphine Pd(0) Complexes

(2009) Fabiola Barrios-Landeros et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Insertion of One, Two, and Three Molecules of Alkyne into the Pd−C Bond of Ortho-palladated Primary and Secondary Arylalkylamines

(2009) José Vicente et al.   ORGANOMETALLICS

Kinetico-Mechanistic Insight into the Platinum-Mediated C−C Coupling of Fluorinated Arenes

(2009) Teresa Calvet et al.   ORGANOMETALLICS

Carbon−Fluorine Reductive Elimination from a High-Valent Palladium Fluoride

(2008) Takeru Furuya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbon–heteroatom bond formation catalysed by organometallic complexes

(2008) John F. Hartwig   NATURE

Rates of the Oxidative Addition of Benzyl Halides to a Metallacyclic Palladium(II) Complex and of the Reductive Elimination from a Benzyl-Palladium(IV) Complex

(2008) Christian Amatore et al.   ORGANOMETALLICS

Unexpected Structure of Palladacycles Containing Carboxylated Schiff Bases. Synthesis of Some Water-Soluble Metallacycles

(2008) Joan Albert et al.   ORGANOMETALLICS