Article
Psychiatry
Juan L. Gomez, Jordi Bonaventura, Jacqueline Keighron, Kelsey M. Wright, Dondre L. Marable, Lionel A. Rodriguez, Sherry Lam, Meghan L. Carlton, Randall J. Ellis, Chloe J. Jordan, Guo-hua Bi, Oscar Solis, Marco Pignatelli, Michael J. Bannon, Zheng-Xiong Xi, Gianluigi Tanda, Michael Michaelides
Summary: Cocaine binds to dopamine transporter to regulate reward behavior, and research suggests that cocaine-induced increases in synaptic Zn2+ may potentiate effects on dopamine neurotransmission and behavior in the brain.
TRANSLATIONAL PSYCHIATRY
(2021)
Article
Microbiology
Zhenyao Luo, Jacqueline R. Morey, Evelyne Deplazes, Alina Motygullina, Aimee Tan, Katherine Ganio, Stephanie L. Neville, Nikolaos Eleftheriadis, Michael Isselstein, Victoria G. Pederick, James C. Paton, Thorben Cordes, Jeffrey R. Harmer, Bostjan Kobe, Christopher A. McDevitt
Summary: This study elucidates a novel mechanism for zinc binding in Streptococcus pneumoniae's AdcA protein and highlights the importance of the N-terminal domain for zinc import, as well as a conserved loop region crucial for zinc acquisition. These findings provide insights into the structural and functional basis of selective zinc uptake in prokaryotes.
Article
Geriatrics & Gerontology
Zhifeng Qi, Xixi Zhou, Wen Dong, Graham S. Timmins, Rong Pan, Wenjuan Shi, Shuhua Yuan, Yongmei Zhao, Xunming Ji, Ke Jian Liu
Summary: Zinc plays important roles in physiological and pathological processes in the brain. The accumulation of free zinc in ischemic tissue leads to blood-brain barrier (BBB) disruption following cerebral ischemia. However, little is known about the source of free zinc in microvessels and the mechanism of free zinc-mediated BBB damage. In this study, we found that cerebral ischemia increased the extracellular fluid (ECF-Zn) levels in ischemic brain, resulting in exacerbated BBB damage in a rat stroke model. Suppressing zinc release from neurons, using neuronal-specific zinc transporter 3 (ZnT3) knockout mice, significantly reduced ECF-Zn and BBB permeability after ischemia. Interestingly, we discovered that the activity of zinc-dependent metalloproteinase-2 (MMP-2) was modulated by ECF-Zn levels.
Article
Biochemistry & Molecular Biology
Romain La Rocca, Philipp O. Tsvetkov, V. Andrey Golovin, Diane Allegro, Pascale Barbier, Soazig Malesinski, Francoise Guerlesquin, Francois Devred
Summary: This study identified three zinc binding sites on Tau protein using Nuclear Magnetic Resonance (NMR) and revealed that the N-terminal and C-terminal sites are independent of each other. Molecular simulations were conducted to propose models of zinc binding to each site. These findings are crucial for the design of potential therapies for Tau pathologies.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2022)
Article
Immunology
Marina L. Zupan, Zhenyao Luo, Katherine Ganio, Victoria G. Pederick, Stephanie L. Neville, Evelyne Deplazes, Bostjan Kobe, Christopher A. McDevitt
Summary: The pathogen Streptococcus pneumoniae acquires essential zinc ions from the host through the proteins AdcA and AdcAII, which is crucial for infection. AdcAII plays a larger role during initial infection, and the Zn(II)-coordinating residues are found to be important for metal binding. Through structural and biochemical analyses, it was shown that specific conformational changes in AdcAII are necessary for effective metal uptake.
FRONTIERS IN CELLULAR AND INFECTION MICROBIOLOGY
(2021)
Article
Biochemistry & Molecular Biology
Saleh Alquethamy, Katherine Ganio, Zhenyao Luo, Sheikh I. Hossain, Andrew J. Hayes, Thomas Ve, Mark R. Davies, Evelyne Deplazes, Bostjan Kobe, Christopher A. McDevitt
Summary: In this study, A. baumannii ZnuA, a zinc-recruiting protein, was characterized using genomic, biochemical, and structural approaches. The findings revealed the high conservation of ZnuA and provided insight into the mechanism of zinc recruitment by ZnuA, expanding our understanding of the functional diversity of zinc-recruiting proteins.
JOURNAL OF INORGANIC BIOCHEMISTRY
(2022)
Article
Biochemistry & Molecular Biology
Yuting Liu, Elizabeth M. Bafaro, Robert E. Dempski
Summary: This study reports the heterologous expression of hZIP4 in Saccharomyces cerevisiae. By observing the presence of hZIP4-GFP and mhZIP4-GFP fusion proteins on the plasma membrane of yeast cells, the expression and localization characteristics of hZIP4 in yeast have been revealed.
Article
Psychiatry
Luke A. Jelen, Mark S. Green, Sinead King, Alex G. Morris, Xinyuan Zhang, David J. Lythgoe, Allan H. Young, Jacqueline De Belleroche, James M. Stone
Summary: This pilot study investigated the impact of two variants in the gene encoding ZnT3 on brain glutamate levels and cognitive activity in patients with schizophrenia and bipolar affective disorder. The study found that the presence of a minor allele of the gene affected glutamate levels in specific brain regions during cognitive tasks. This suggests a potential role of SLC30A3 in glutamatergic neurotransmission and mental illness neuropathology.
FRONTIERS IN PSYCHIATRY
(2022)
Article
Biochemistry & Molecular Biology
Denise Bellotti, Adriana Miller, Magdalena Rowinska-Zyrek, Maurizio Remelli
Summary: Zrt2 is a zinc transporter essential for Candida albicans zinc uptake and growth. By studying its protein structure and coordination properties, a specific protein fragment of Zrt2 was found to have the highest metal binding affinity under acidic conditions. Compared to another zinc transporter Zrt1, Zrt2 has lower affinity towards zinc.
Article
Biochemistry & Molecular Biology
Vilde Leipart, Oyvind Enger, Diana Cornelia Turcu, Olena Dobrovolska, Finn Drablos, Oyvind Halskau, Gro Amdam
Summary: The protein vitellogenin in honey bees can bind multiple zinc ions, which are crucial for various activities of the protein including DNA binding. These findings have implications not only for other egg-laying species but also provide a platform for studying metal ions in bee health.
INSECT MOLECULAR BIOLOGY
(2022)
Article
Microbiology
N. Zohreh Pourhassan, Eymen Hachani, Olivia Spitz, Sander H. J. Smits, Lutz Schmitt
Summary: This study investigates the role of the ABC transporter hemolysin B (HlyB) in the HlyA secretion system. The results reveal that the HlyA T1SS is composed of multiple proteins, and the GG repeats and amphipathic helix are crucial for efficient secretion.
FRONTIERS IN MICROBIOLOGY
(2022)
Article
Chemistry, Medicinal
Davide Sala, Andrea Giachetti, Antonio Rosato
Summary: ZnT8, a human zinc transporter, shows significant differences in zinc ion transport kinetics and conformational dynamics between different variants, which may lead to different disease risks.
JOURNAL OF CHEMICAL INFORMATION AND MODELING
(2021)
Review
Biochemistry & Molecular Biology
Martina Maywald, Lothar Rink
Summary: Zinc plays a vital role in the functioning of the immune system and immune defense. Zinc deficiency, mainly caused by malnutrition, can lead to immune disorders and is associated with metabolic diseases, chronic illnesses, and infectious diseases. The anti-inflammatory and antioxidant properties of zinc are not yet comprehensively understood. Zinc supplementation has the potential to improve infectious diseases.
Article
Chemistry, Multidisciplinary
Manuel David Peris-Diaz, Roman Guran, Carmen Domene, Vivian de los Rios, Ondrej Zitka, Vojtech Adam, Artur Krezel
Summary: Mammalian metallothioneins (MTs) are important cellular buffering systems, but their mode of action remains unclear. This study utilized various methods to unravel the binding mechanism of Zn(II) with MTs and highlighted the differences in binding affinities of different Zn(II) ions to MTs.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2021)
Article
Biochemistry & Molecular Biology
Maria Carmen Catapano, Douglas S. Parsons, Radoslaw Kotuniak, Premysl Mladenka, Wojciech Bal, Wolfgang Maret
Summary: Human zinc transporter ZnT8 differs from bacterial zinc exporters in metal binding and export mechanisms, with the R variant associated with a higher risk of type 2 diabetes. Structural studies have revealed differences in metal binding and coordination between the human and bacterial proteins, particularly in the cytosolic domain. This investigation provides insights into the metal-chelation mechanism of ZnT8 and highlights the impact of structural differences on diabetes risk.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2021)
Article
Chemistry, Inorganic & Nuclear
Janos P. Meszaros, Gabor Nemeti, Jelena M. Poljarevic, Tamas Holczbauer, Nora V. May, Eva A. Enyedy
Summary: The solution speciation and reactivity of Rh(η5-C5Me5), Ru(η6-p-cymene), and Ru(η6-toluene) complexes with 2,4-pyridinedicarboxylic acid and 2-picolinic acid were studied and compared. X-ray diffraction analysis revealed structures of the complexes, showing different geometries and stability preferences. Complexes with 2,4-pyridinedicarboxylic acid were found to form more stable complexes compared to those with 2-picolinic acid, especially with Ru(η6-arene) complexes.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
(2021)
Article
Biochemistry & Molecular Biology
Nora V. May, Attila Jancso, Eva A. Enyedy
Summary: Copper(II) complexes of thiosemicarbazones have been found to exhibit anticancer properties and their interaction with human serum albumin (HSA) can be influenced by blood transport proteins. The study revealed weak-to-moderate binding strength of the TSC complexes with HSA and observed molecular changes through spectral analysis during the binding process.
Article
Chemistry, Inorganic & Nuclear
Szilvia Bunda, Nora May, Dora Bonczidai-Kelemen, Antal Udvardy, H. Y. Vincent Ching, Kevin Nys, Mohammad Samanipour, Sabine Van Doorslaer, Ferenc Joo, Norbert Lihi
Summary: Copper(II) complexes formed with sulfonated salan ligands exhibit excellent binding ability and stability, especially when introducing a cyclohexyl moiety. The complexes also show moderate catalytic activity in the Henry reaction, with the best yield achieved by complexes of PrHSS and BuHSS. Despite lower metal binding ability compared to cyclohexyl counterparts, these complexes possess larger spin density on the nitrogen nuclei, affecting their catalytic activity.
INORGANIC CHEMISTRY
(2021)
Article
Biochemistry & Molecular Biology
Tatsiana V. Petrasheuskaya, Debora Wernitznig, Marton A. Kiss, Nora V. May, Dominik Wenisch, Bernhard K. Keppler, Eva Frank, Eva A. Enyedy
Summary: The study synthesized and characterized terminal N-mono- and dimethylated derivatives of an estrone-salicylaldehyde thiosemicarbazone hybrid and their highly cytotoxic Cu(II) complexes, as well as simpler structurally related analogues. The dimethylation of the derivatives led to more stable complexes in a series of ligands, exhibiting significant inhibitory effects on 3D spheroids of various human cancer cells.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY
(2021)
Article
Biochemistry & Molecular Biology
Eva A. Enyedy, Tatsiana Petrasheuskaya, Marton A. Kiss, Debora Wernitznig, Dominik Wenisch, Bernhard K. Keppler, Gabriella Spengler, Nora May, Eva Frank, Orsolya Domotor
Summary: The study investigated the solution chemical properties and biological activities of a novel tridentate salicyaldehyde semicarbazoneestrone hybrid and a related bicyclic compound. The compounds showed relatively high stability, efficient gallium binding, significant cytotoxicity against cancer cells, and dissociation at physiological pH.
JOURNAL OF INORGANIC BIOCHEMISTRY
(2021)
Article
Biochemistry & Molecular Biology
Marton A. Kiss, Miroslav Perina, Vaclav Bazgier, Nora V. May, Adam Baji, Radek Jorda, Eva Frank
Summary: Steroid research is focusing on preparing modified derivatives with altered receptor binding and bioactivity. Results show that new compounds can inhibit androgen receptor activity and regulate gene expression in prostate cancer cells.
JOURNAL OF STEROID BIOCHEMISTRY AND MOLECULAR BIOLOGY
(2021)
Article
Chemistry, Inorganic & Nuclear
Tibor Csupasz, Norbert Lihi, Zsuzsa Fekete, Antonia Nagy, Richard Botar, Viktoria Forgacs, Dezso Szikra, Nora Veronika May, Gyula Tircso, Ferenc Krisztian Kalman
Summary: In this study, two Cu(ii) complexes formed from the CB-15aneN(5) ligand and its bifunctional derivative were thoroughly characterized. The results showed that these Cu(ii) chelates have high thermodynamic stability, fast complexation, and moderate inertness under harsh conditions. The radiolabeling experiments demonstrated the fast complexation even at low concentrations. Based on these findings, the CB-15aneN(5) ligand family is an excellent platform for Cu(ii) complexation in radiotheranostics.
INORGANIC CHEMISTRY FRONTIERS
(2022)
Article
Chemistry, Physical
Tatsiana V. Petrasheuskaya, Ferenc Kovacs, Gabriella Spengler, Nora V. May, Eva Frank, Eva A. Enyedy
Summary: The effects of complexation of 2-aminophenol and 2-aminoestradiol with divalent metal ions on their physico-chemical and biological properties were investigated. It was found that complexation with Cu(II) ions resulted in higher stability and increased cytotoxicity against cancer cells. Moreover, complexation with Cu(II) ions also enhanced antioxidant activity and percentage of apoptotic cells.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Oncology
Vivien Posa, Alessia Stefanelli, Julia H. Bormio Nunes, Sonja Hager, Marlene Mathuber, Nora May, Walter Berger, Bernhard K. Keppler, Christian R. Kowol, Eva A. Enyedy, Petra Heffeter
Summary: In addition to zinc, iron and copper also play a role in the mode of action and resistance development of COTI-2 and its derivatives. COTI-NMe2 is discovered to be a new drug candidate with improved anticancer activity and resistance profile. The study reveals that COTI-2 forms stable complexes with copper and glutathione, making it a substrate for the resistance efflux transporter ABCC1. Furthermore, the interaction of COTI-2 and its derivatives with iron, copper, and zinc ions is characterized, and their activities against drug-resistant cancer cells are investigated.
Article
Biochemistry & Molecular Biology
Tamas Pivarcsik, Vivien Posa, Hilda Kovacs, Nora May, Gabriella Spengler, Szonja P. Posa, Szilard Toth, Zeinab Nezafat Yazdi, Csilla Ozvegy-Laczka, Imre Ugrai, Istvan Szatmari, Gergely Szakacs, Eva A. Enyedy
Summary: This article investigates a novel 5-nitro-8-hydroxyquinoline-proline hybrid and its Rh(eta(5)-C5Me5) and Ru(eta(6)-p-cymene) complexes, which have excellent solubility in water and show inhibitory effects on sensitive and multidrug-resistant cells.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2023)
Article
Biochemistry & Molecular Biology
Tatsiana Petrasheuskaya, Ferenc Kovacs, Nora Igaz, Andrea Ronavari, Balint Hajdu, Laura Bereczki, Nora May, Gabriella Spengler, Bela Gyurcsik, Monika Kiricsi, Eva Frank, Eva A. Enyedy
Summary: A series of novel estradiol-based salicylaldehyde (thio)semicarbazones and their Cu(II) complexes were synthesized and characterized. The Cu(II)-estradiol-semicarbazone complex structure was determined by X-ray crystallography. The Cu(II) complexes of estradiol-TSC and its N,N-dimethyl derivative showed high cytotoxicity against cancer cells and significant activity against Staphylococcus aureus bacteria strain. Estradiol-TSCs exhibited efficient antioxidant activity, which was decreased by complexation with Cu(II) ions. The exchange of estrone moiety to estradiol did not significantly affect the physicochemical and biological properties.
Article
Chemistry, Inorganic & Nuclear
Azza A. Hassoon, Attila Szorcsik, Livia Fulop, Zita Papp, Nora May, Tamas Gajda
Summary: Copper(II) complexes of HPH-NH2 (L-1) and HPHPY-NH2 (L-2) peptides were studied as small molecular models of lytic polysaccharide monooxygenases, and their coordination properties were investigated by pH-potentiometry and various spectroscopic techniques. It was found that the coordination properties of these ligands were fundamentally different from those of other non-protected N-terminal HXH-sequences concerning the metal binding ability of amide nitrogens.
DALTON TRANSACTIONS
(2022)
Article
Chemistry, Inorganic & Nuclear
Nora May, Niloofar Bayat, Kende Attila Beres, Petra Bombicz, Vladimir M. Petrusevski, Gyorgy Lendvay, Attila Farkas, Laszlo Kotai
Summary: A hemipyridine solvate of bis(pyridine)silver(I) perchlorate was prepared and characterized by single crystal X-ray analysis and vibrational spectroscopy. The solvate structure is isomorphic with the analogous permanganate complex. The stoichiometric ratio of the monomer [Agpy(2)ClO(4)] and the solvent pyridine is 1:0.5, and the solvate pyridine occupies 18.0% of the volume of the unit cell.
Article
Chemistry, Multidisciplinary
G. Tamas Gal, Nora May, Laszlo Trif, Judith Mihaly, Petra Bombicz
Summary: This study reported the crystal structure of clopamide drug and its copper (II) complexes. By growing single crystals and analyzing molecular arrangements, the authors revealed the structural landscape of different polymorphs and solvatomorphs. The systematic comparison of crystal arrangements contributes to a better understanding of structure-directing effects and provides strategies to control molecular self-assembly.
Article
Chemistry, Inorganic & Nuclear
Janos P. Meszaros, Veronika F. S. Pape, Gergely Szakacs, Gabor Nemeti, Mark Denes, Tamas Holczbauer, Nora V. May, Eva A. Enyedy
Summary: A series of half-sandwich polypyridyl complexes were synthesized and compared for their structural, cytotoxic, and aqueous solution behavior. Introduction of methyl groups near coordinating nitrogen atoms affected steric congestion and changed ligand plane angles. The complexes showed high stability in solution, with Ru complexes susceptible to slow, irreversible decomposition in light exposure.
DALTON TRANSACTIONS
(2021)
Article
Chemistry, Inorganic & Nuclear
Vaibhav Bedi, Dipendu Mandal, Zahid Hussain, Shi-Ming Chen, Yile Wu, Zheng-Wang Qu, Stefan Grimme, Douglas W. Stephan
Summary: The reaction of (tBuO(2)CN)(2) with 9-BBN leads to the formation of a bicyclic heterocyclic compound, while its reactions with BF3 or [Et3Si][B(C6F5)(4)] result in the isolation of different compounds. Computational studies reveal that the steric and electronic properties of the Lewis acid are important in the formation of one of the compounds.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Chisa Itoh, Haruka Yoshino, Taku Kitayama, Wataru Kosaka, Hitoshi Miyasaka
Summary: A new synthetic route for constructing functional paddlewheel diruthenium(II,II) complexes was developed, utilizing Schiff base condensation reactions. The attached Schiff base groups significantly affected the electronic states of the resulting complexes, as revealed by cyclic voltammetry and DFT calculations.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Danrui Ni, Haozhe Wang, Xianghan Xu, Weiwei Xie, Robert J. Cava
Summary: A layered rhombohedral polymorph of indium(iii) triiodide is synthesized at high pressure and temperature. It has an orange color, which is different from ambient pressure InI3, which has a monoclinic molecular structure and a light-yellow color.
DALTON TRANSACTIONS
(2024)
Review
Chemistry, Inorganic & Nuclear
Juan Carlos Perez-Sanchez, Raquel P. Herrera, M. Concepcion Gimeno
Summary: Gold(II) complexes have been less utilized in catalysis compared to their gold(I) and gold(III) counterparts. However, gold(II) complexes offer potential in homo-coupling and cross-coupling reactions, as they are more easily accessible through simplified oxidation and reduction processes. Gold(II) exhibits characteristics of both soft acid gold(I) and hard acid gold(III). This review explores the unique reactivity and potential applications of gold(II) species, highlighting their significance in catalytic transformations.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Nighat Yousuf, Yanping Ma, Qaiser Mahmood, Wenjuan Zhang, Yizhou Wang, Hassan Saeed, Wen-Hua Sun
Summary: In this study, a series of structurally rigid cyclooctyl-fused iminopyridine iron complexes were synthesized and used with methylaluminoxane for isoprene polymerization. The extent of steric hindrance of the ligand framework was found to significantly affect catalytic performance, with less hindrance leading to better activity and stability.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Chenghao Song, Huiwei Du, Menglei Xu, Jie Yang, Xinyu Zhang, Jungan Wang, Yuanfang Zhang, Chengjun Gu, Rui Li, Tao Hong, Jingji Zhang, Jiangying Wang, Yongchun Ye
Summary: This study improves the performance of perovskite solar cells by using a dual-hole transport layer strategy. This strategy enhances the charge transfer efficiency of the transport layer, reduces charge recombination, and improves the quality of the perovskite film layer. Ultimately, the stability of the device is enhanced.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Mahender Singh, Aakash Yadav, Ranjit Singh, Chullikkattil P. Pradeep
Summary: A new aryl selenonium polyoxometalate hybrid was developed and compared with an aryl sulfonium polyoxometalate hybrid in terms of their photocatalytic properties. It was found that the aryl selenonium hybrid exhibited better catalytic performance, which could be attributed to the larger atomic radii of selenium stabilizing the photogenerated electron-hole pair more efficiently. Additionally, the generation of elemental selenium through cleavage of C-Se bonds during catalysis was observed.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Yuhan Xie, Boyu Dong, Xuemin Wang, Siyuan Wang, Jinxi Chen, Yongbing Lou
Summary: This study successfully fabricated visible-light-responsive three-dimensional core-shell CoSe2/ZnIn2S4 heterostructures and achieved attractive activity in photocatalytic hydrogen evolution. The presence of CoSe2 improved light absorption and accelerated charge transfer kinetics. The strong interaction between CoSe2 and ZnIn2S4 reduced charge recombination, further enhancing photocatalytic activity for hydrogen evolution.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Andre L. de O. Batista, Joao Marcos T. Palheta, Mauricio J. Piotrowski, Celso R. C. Rego, Diego Guedes-Sobrinho, Alexandre C. Dias
Summary: This study presents a simulation protocol that provides a solid foundation for exploring two-dimensional materials. Using the TiBr2 2H monolayer as an example, the study reveals its promising properties for optoelectronic and valleytronic applications, including its stability, spin-orbit coupling effects, and optical helicity selection rule.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Jiang Jiang, Zi-Wei Li, Zhi-Zhuan Zhang, Bin Tan, Zhao-Feng Wu, Xiao-Ying Huang
Summary: In this work, two metal organic frameworks (MOFs) containing {Cu2I2} clusters, Eu-CuI-INA and Sr-K-CuI-INA, were synthesized and characterized. Both materials have a three-dimensional structure with {Cu2I2} clusters coordinated by INA(-) ligands and Eu3+ or Sr2+ ions. The Sr-K-CuI-INA material exhibited sensitive fluorescence sensing behaviors towards cysteine and nitro-bearing molecules, showing potential applications in bio and explosive molecule sensing. This work provides a good reference for designing fluorescent MOF probes containing CuI molecules.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Zhiya Lin, Jiasheng Wu, Qianwen Ye, Yulong Chen, Hai Jia, Xiaohui Huang, Shaoming Ying
Summary: Na-ion batteries (NIBs) have attracted great interest as a potential technology for grid-scale energy storage due to the wide distribution, low cost, and environmental friendliness of sodium resources. However, their implementation is hindered by low rate capability and cycling stability caused by the large ionic size of Na+. In this study, a three-dimensional nanoarchitectured coral-like CoSe2@N-doped carbon (CL-CoSe2@NC) was synthesized, and it exhibited improved sodium storage properties with better electrode kinetics and a stable SEI film.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Ya-Qiong Zhang, Yu Zhang, Guoping Zeng, Rong-Zhen Liao, Man Li
Summary: The mechanism and selectivity of CO2 reduction under visible light were investigated using density functional calculations. The results showed that a tetradentate PNNP-type Iridium(III) complex exhibited high activity and selectivity in the reaction.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Sanyukta Ghosh, Shubhanth Jain, Soumya Ranjan Mishra, Gerda Rogl, Peter Rogl, Ernst Bauer, B. S. Murty, A. Govindaraj, Ramesh Chandra Mallik
Summary: In this study, reduced graphene oxide (rGO) was uniformly dispersed in the In0.5Co4Sb12 bulk material by ultrasonication, which effectively reduced the lattice thermal conductivity and improved the thermoelectric efficiency.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Mika Takeuchi, Yutaka Amao
Summary: This study developed an effective visible-light driven system for fumaric acid production using renewable resources such as biomass derivatives, providing an alternative to the current petroleum-based synthesis methods.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Juan Jian, Meiting Wang, Zhuo Wang, Jingwen Meng, Yuqin Yang, Limin Chang
Summary: Developing low-cost and self-supported bifunctional catalysts is crucial for highly efficient water splitting devices. In this study, nano-NiFe2O4 was directly grown onto iron foil surface and Sn4+ was introduced into the NiFe2O4. The resulting Sn-NiFe2O4/IF showed low overpotentials and high current densities during oxygen evolution reaction (OER) and hydrogen evolution reaction (HER), making it a promising catalyst for large-scale hydrogen production.
DALTON TRANSACTIONS
(2024)