4.7 Article

Effect of NH2-MWCNTs on crosslink density of epoxy matrix and ILSS properties of e-glass/epoxy composites

期刊

COMPOSITE STRUCTURES
卷 95, 期 -, 页码 213-221

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.compstruct.2012.07.019

关键词

Functionalized MWCNTs; Crosslink density; Interlaminar shear strength; Calendaring; Sonication

资金

  1. ERDC-CERL
  2. NSF-EPSCoR

向作者/读者索取更多资源

Crosslink density is one of the important parameters that govern the physical properties of fiber reinforced polymer (FRP) composites. Enhancement of crosslink density by effective matrix modification through nanoparticle incorporation is the most prominent way to improve mechanical and thermo-mechanical properties of FRP composites. In this study, at first, 0.1-0.4 wt.% amino-functionalized multi-walled carbon nanotubes (NH2-MWCNTs) were incorporated in SC-15 epoxy system and the variation in crosslink density was investigated using rubber elasticity theory. Subsequently, the effect of these MWCNTs on interlaminar shear strength (ILSS) of e-glass/epoxy composites was studied. Result obtained from the tests showed a linearly increasing trend in crosslink density and ILSS properties from 0 to 0.3 wt.% MWCNTs loading. Better dispersion of MWCNTs facilitated more crosslinking sites, whereas, the three-way reaction between amine functional groups of MWCNTs with epoxide groups of resin and epoxy silanes of fiber surfaces improved the crosslinking and thereby ILSS properties of e-glass/epoxy composites. (c) 2012 Elsevier Ltd. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Chemistry, Multidisciplinary

Structural Defects Modulate Electronic and Nanomechanical Properties of 2D Materials

Manoj Tripathi, Frank Lee, Antonios Michail, Dimitris Anestopoulos, James G. McHugh, Sean P. Ogilvie, Matthew J. Large, Aline Amorim Graf, Peter J. Lynch, John Parthenios, Konstantinos Papagelis, Soumyabrata Roy, M. A. S. R. Saadi, Muhammad M. Rahman, Nicola Maria Pugno, Alice A. K. King, Pulickel M. Ajayan, Alan B. Dalton

Summary: This study investigates the influence of different geometries of line defects in graphene and molybdenum disulfide using atomic force microscopy and Raman spectroscopic mapping. The stiffness of graphene was found to be higher than molybdenum disulfide, with deflated graphene nanobubbles exhibiting the lowest stiffness. Density functional theory reveals alteration of bandstructures in graphene and MoS2 due to wrinkled structures, showing a higher modulation effect in MoS2.

ACS NANO (2021)

Article Chemistry, Physical

Patterning, Transfer, and Tensile Testing of Covalent Organic Framework Films with Nanoscale Thickness

Dongyang Zhu, Zhiqi Hu, Tanya K. Rogers, Morgan Barnes, Chia-Ping Tseng, Hao Mei, Lucas M. Sassi, Zhuqing Zhang, Muhammad M. Rahman, Pulickel M. Ajayan, Rafael Verduzco

Summary: This study introduces a novel method for patterning, transferring, and measuring the tensile properties of free-floating nanoscale COF films. The tensile tests of TAPB-PDA COF resulted in a modulus of approximately 1.4 GPa and a fracture strain of 2.5%, demonstrating the potential of COFs for thin-film applications.

CHEMISTRY OF MATERIALS (2021)

Article Multidisciplinary Sciences

Damage-tolerant 3D-printed ceramics via conformal coating

Seyed Mohammad Sajadi, Livia Vasarhelyi, Reza Mousavi, Amir Hossein Rahmati, Zoltan Konya, Akos Kukovecz, Taib Arif, Tobin Filleter, Robert Vajtai, Peter Boul, Zhenqian Pang, Teng Li, Chandra Sekhar Tiwary, Muhammad M. Rahman, Pulickel M. Ajayan

Summary: The proposed approach externalizes the soft phase by conformal polymer coating over architected ceramic structures, leading to improved compressive strength and toughness. This surface modification strategy provides a simple way to build complex ceramic parts that are far more damage-tolerant than traditional counterparts.

SCIENCE ADVANCES (2021)

Article Chemistry, Multidisciplinary

Corrosion Resistance of Sulfur-Selenium Alloy Coatings

Sandhya Susarla, Govinda Chilkoor, Jawahar R. Kalimuthu, M. A. S. R. Saadi, Yufei Cui, Taib Arif, Thierry Tsafack, Anand B. Puthirath, Pawan Sigdel, Bharat Jasthi, Parambath M. Sudeep, Leiqing Hu, Aly Hassan, Samuel Castro-Pardo, Morgan Barnes, Soumyabrata Roy, Rafael Verduzco, Md Golam Kibria, Tobin Filleter, Haiqing Lin, Santiago D. Solares, Nikhil Koratkar, Venkataramana Gadhamshetty, Muhammad M. Rahman, Pulickel M. Ajayan

Summary: Research shows that a lightweight sulfur-selenium (S-Se) alloy coating can effectively resist steel corrosion in diverse environments, with superior mechanical performance and longevity.

ADVANCED MATERIALS (2021)

Review Green & Sustainable Science & Technology

3D Printed Materials in Water Treatment Applications

Pranjal Ghosal, Bramha Gupta, Rushikesh S. Ambekar, Muhammad M. Rahman, Pulickel M. Ajayan, Nirupam Aich, Ashok Kumar Gupta, Chandra Sekhar Tiwary

Summary: As the global population grows and water quality becomes a critical issue, water treatment technologies are evolving to address the challenges. 3D printing technology shows great potential for enhancing water treatment efficiency by creating materials with tailored properties.

ADVANCED SUSTAINABLE SYSTEMS (2022)

Review Chemistry, Multidisciplinary

Direct Ink Writing: A 3D Printing Technology for Diverse Materials

M. A. S. R. Saadi, Alianna Maguire, Neethu T. Pottackal, Md Shajedul Hoque Thakur, Maruf Md Ikram, A. John Hart, Pulickel M. Ajayan, Muhammad M. Rahman

Summary: Direct ink writing (DIW) is a versatile 3D printing technique that allows printing of a wide range of materials. This comprehensive review explores the process of DIW printing of complex 3D structures and discusses its diverse applications in various industries.

ADVANCED MATERIALS (2022)

Article Chemistry, Multidisciplinary

Oxygen Reduction Reaction with Manganese Oxide Nanospheres in Microbial Fuel Cells

Bhuvan Vemuri, Govinda Chilkoor, Pramod Dhungana, Jamil Islam, Aravind Baride, Nikhil Koratkar, Pulickel M. Ajayan, Muhammad M. Rahman, James D. Hoefelmeyer, Venkataramana Gadhamshetty

Summary: Operating MFCs under extreme pH conditions is challenging, but a pH-universal ORR ink based on hollow nanospheres of manganese oxide (h-Mn3O4) anchored with multiwalled carbon nanotubes (MWCNTs) shows remarkable activity and stability in both acidic and alkaline conditions.

ACS OMEGA (2022)

Article Chemistry, Multidisciplinary

Graphene as Thinnest Coating on Copper Electrodes in Microbial Methanol Fuel Cells

Jamil Islam, Parthiba Karthikeyan Obulisamy, Venkata K. K. Upadhyayula, Alan B. Dalton, Pulickel M. Ajayan, Muhammad M. Rahman, Manoj Tripathi, Rajesh Kumar Sani, Venkataramana Gadhamshetty

Summary: In this study, the use of graphene layers on copper surfaces for microbially driven methanol dehydrogenation to generate DC electricity was investigated. The results showed that the graphene layers significantly improved the power density and current density. This catalyst-free approach has important implications for enhancing the sustainability of fuel cell technologies.

ACS NANO (2023)

Article Engineering, Mechanical

3D printed metamaterials for damping enhancement and vibration isolation: Schwarzites

Sudheendra Herkal, Muhammad M. Rahman, Satish Nagarajaiah, Vijay Vedhan Jayanthi Harikrishnan, Pulickel Ajayan

Summary: Schwarzites are 3D solids with negative Gaussian curvatures that possess unique mechanical properties such as high ductility and strength. The energy dissipation mechanism of Schwarzites allows for the removal of energy from dynamic systems and reduction of system response. Experimental results show that Schwarzite geometry can increase the damping ratio by almost 80% with the same material volume as a solid support. Additionally, Schwarzites exhibit vibration isolation properties.

MECHANICAL SYSTEMS AND SIGNAL PROCESSING (2023)

Article Chemistry, Multidisciplinary

Economic and environmental assessment of asphaltene-derived carbon fiber production

Md Abdullah Al Bari, Shariful Kibria Nabil, Shabab Saad, Rahul Sarkar, Sabrina Sabiha, Muhammad M. M. Rahman, Md Golam Kibria

Summary: There is growing interest in using carbon fibers in various applications due to their excellent mechanical, electrical, and thermal properties. Recent studies have identified asphaltene as a promising low-cost precursor for carbon fiber production, potentially accelerating its adoption. Techno-economic and life cycle assessments show that asphaltene-derived carbon fiber production can be cost-effective and offer climate benefits compared to current precursors.

GREEN CHEMISTRY (2023)

Article Materials Science, Multidisciplinary

Solvent-Induced Incremental Pore Collapse in Two-Dimensional Covalent Organic Frameworks

Dongyang Zhu, Qianqian Yan, Yifan Zhu, Xinbo Tong, Alec Ajnsztajn, Muhammad M. Rahman, Pulickel M. Ajayan, Rafael Verduzco

Summary: This study demonstrates that the degree of pore collapse in nanoporous materials COFs can be precisely controlled by using a mixture of high and low surface tension solvents. The study also reveals that pore collapse is an irreversible process, and solvent surface tension is the most important characteristic that governs pore collapse.

ACS MATERIALS LETTERS (2022)

Article Chemistry, Multidisciplinary

Understanding fragility and engineering activation stability in two-dimensional covalent organic frameworks

Dongyang Zhu, Jun-Jie Zhang, Xiaowei Wu, Qianqian Yan, Fangxin Liu, Yifan Zhu, Xiaodong Gao, Muhammad M. Rahman, Boris Yakobson, Pulickel M. Ajayan, Rafael Verduzco

Summary: The activation stability of covalent organic frameworks (COFs) is crucial for their crystallinity and porosity, but current understanding is limited. This study presents a versatile experimental approach to quantify the activation stability of COFs and demonstrates how it can be systematically tuned using a multivariate synthesis approach. The findings provide novel insights into COF stability and offer guidance for designing more robust COFs.

CHEMICAL SCIENCE (2022)

Article Chemistry, Multidisciplinary

Transition pathways towards net-zero emissions methanol production

Muflih A. Adnan, M. A. Khan, Pulickel M. Ajayan, Muhammad M. Rahman, Jinguang Hu, Md Golam Kibria

Summary: The race to decarbonize energy systems has led to technological advancements, with a focus on capturing CO2 from air and converting it into valuable fuels and chemicals. Two transition pathways for sustainable production of methanol were assessed, showing economic viability in jurisdictions with low-cost grid electricity. Technical improvements and cost reductions are necessary for these envisioned air-to-fuel routes to be competitive.

GREEN CHEMISTRY (2021)

Review Chemistry, Multidisciplinary

Seawater electrolysis for hydrogen production: a solution looking for a problem?

M. A. Khan, Tareq Al-Attas, Soumyabrata Roy, Muhammad M. Rahman, Noreddine Ghaffour, Venkataraman Thangadurai, Stephen Larter, Jinguang Hu, Pulickel M. Ajayan, Md Golam Kibria

Summary: As the price of renewable electricity drops, water electrolysis for hydrogen production is being considered for decarbonization. However, there is currently limited economic and environmental incentive for further research and development in direct seawater electrolysis technology.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

Article Chemistry, Physical

Fiber-reinforced monolithic supercapacitors with interdigitated interfaces

Fanshu Yuan, Devashish Salpekar, Abhijit Baburaj, Anand B. Puthirath, Sakib Hassan, Francisco C. Robles Hernandez, Hossein Robatjazi, M. A. S. R. Saadi, Soumyabrata Roy, Dongping Sun, Nicholas A. Kotov, Muhammad M. Rahman, Pulickel M. Ajayan

Summary: This study presents a novel approach to develop structural monolithic supercapacitors using strong nanofibers for enhanced mechanical and thermal integrity. The new supercapacitors demonstrate a combination of mechanical flexibility, robustness, and thermal stability, addressing long-standing challenges in traditional supercapacitor design. These advancements pave the way for potential applications of structural energy and power systems.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Article Mechanics

A dovetail core design for joints in composite sandwich structures

Rawan Aqel, Patrick Severson, Rani Elhajjar

Summary: A novel core splice joint configuration for composite sandwich structures is studied and proposed to improve the strength and toughness. Experimental and numerical efforts show that this configuration can significantly increase the ultimate strength by 13% to 51% and the toughness by 2% to 35%.

COMPOSITE STRUCTURES (2024)

Article Mechanics

Form-finding of elastic gridshell based on spatial elastica model

Xianheng Wang, Cong Chen, Jinsong Zhang, Xinming Qiu

Summary: In this paper, a new form-finding method based on spatial elastica model (FMSE) is proposed for elastic gridshells. The method integrates the deformations of elastic rods into the overall deformation of the gridshell, and solves a set of transcendental equations using the quasi-Newton method to ensure the deformation satisfies the given boundary conditions. The method is validated through experiments and expected to have potential applications in the investigations of elastic gridshells.

COMPOSITE STRUCTURES (2024)

Article Mechanics

Prediction of elastic properties of 3D4D rotary braided composites with voids using multi-scale finite element and surrogate models

Hao Huang, Zitong Guo, Zhongde Shan, Zheng Sun, Jianhua Liu, Dong Wang, Wang Wang, Jiale Liu, Chenchen Tan

Summary: The conventional evaluation of 3D braided composites' mechanical properties through numerical and experimental methodologies hinders material application due to the expenses, time constraints, and laborious efforts involved. This study establishes a multi-scale finite element model and a surrogate model for predicting the elastic properties of 3D4D rotary braided composites with voids. By optimizing a neural network model, the results are validated and provide valuable insights into the microstructure and properties of these composites.

COMPOSITE STRUCTURES (2024)

Article Mechanics

Free vibration characteristics of integrated fluted-core composite sandwich cylinders

Xinyu Li, Hao Zhang, Haiyang Yang, Junrong Luo, Zhongmin Xiao, Hongshuai Lei

Summary: Due to their excellent mechanical properties and design flexibility, fluted-core composite sandwich structures have gained significant attention in aerospace and rail transit applications. This study investigated the free-vibration characteristics and optimized design of composite fluted-core sandwich cylinders through theoretical models and experimental tests.

COMPOSITE STRUCTURES (2024)

Article Mechanics

Mechanistic modeling considering bottom edge cutting effect and material anisotropy during end milling of aluminum honeycomb core

Chao Li, Chunzheng Duan, Xiaodong Tian, Chao Wang

Summary: A mechanistic model considering the bottom edge cutting effect and the anisotropic characteristics of the material is proposed in this paper to accurately predict cutting forces. The model was validated through a series of milling experiments and can be used to predict the cutting force of various parts of the cutter and any feed direction.

COMPOSITE STRUCTURES (2024)

Article Mechanics

Vibro-acoustic performance of graded piezoelectric metamaterial plates

Camila Sanches Schimidt, Leopoldo Pisanelli Rodrigues de Oliveira, Carlos De Marqui Jr

Summary: This work investigates the vibro-acoustic performance of graded piezoelectric metamaterial plates. The study shows that piezoelectric metamaterial plates with reconfigurable properties can provide enhanced vibration and sound power attenuation.

COMPOSITE STRUCTURES (2024)

Article Mechanics

Torsional mechanical properties and damage mechanism of glass fiber-ramie hybrid circular tube

Jun Ke, Li-jie Liu, Zhen-yu Wu, Zhong-ping Le, Luo Bao, Dong-wei Luo

Summary: Compared with other green natural fibers, ramie has higher mechanical properties and lower cost. In this study, ramie and glass fiber are made into composite circular tubes. The results show that the hybrid circular tube with ramie and glass fiber has improved torsional mechanical properties and reduced weight and cost. The failure mechanisms are affected by the loading direction and the content of each fiber.

COMPOSITE STRUCTURES (2024)

Article Mechanics

A novel analytical model for fiber reinforced cementitious matrix FRCM coupons subjected to tensile tests

Natalia Pingaro, Gabriele Milani

Summary: This paper proposes an enhanced analytical model for predicting the behavior of FRCM samples tested under standard tensile tests. The model takes into account the interaction between fibers and matrix through the interface, and assumes different material properties at different phases. By solving a second order linear differential equation, an analytical solution can be obtained. The model is validated with experimental data and shows good predictability.

COMPOSITE STRUCTURES (2024)

Article Mechanics

Mode I fracture of thick adhesively bonded GFRP composite joints for wind turbine rotor blades

Jialiang Fan, Anastasios P. Vassilopoulos, Veronique Michaud

Summary: This article investigates the effects of voids, joint geometry, and test conditions on the fracture performance of thick adhesive Double Cantilever Beam (DCB) joints. It concludes that grooved DCB joints with low void content tested at low displacement rates showed stable crack propagation without significant crack path deviation.

COMPOSITE STRUCTURES (2024)

Article Mechanics

Quasi-static compression tests of overwrapped composite pressure vessels under low velocity impact

Auwalu I. Mohammed, Kaarthikeyan Raghupathy, Osvaldo De Victoria Garcia Baltazar, Lawson Onokpasah, Roger Carvalho, Anders Mogensen, Farzaneh Hassani, James Njuguna

Summary: This study investigates the performance of composite pressure vessels under damaged and undamaged conditions, providing insights into their reliability and residual strength capabilities. The results demonstrate that the damage profile and its effect on compressive strength are similar between damaged and non-damaged cylinders. When subjected to quasi-static compression, the polyethylene liner absorbs enough elastic strain energy to recover without plastic deformation. Additionally, quasi-static compression has little to no influence on the axial strength of the cylinders. The damage characterization reveals fiber breakage, delamination, local buckling, and brooming failure. This study has direct implications for the safety design tolerances, manufacturing strategies, and operational failure conditions of composite overwrapped pressure vessels (COPVs).

COMPOSITE STRUCTURES (2024)

Article Mechanics

Feature extraction and classification of multiple cracks from raw vibrational responses of composite beams using 1D-CNN network

Muhammad Irfan Shirazi, Samir Khatir, Djilali Boutchicha, Magd Abdel Wahab

Summary: Structural health monitoring is important to ensure the safety of components and structures. This study proposes a method using finite element models and 1D-CNN network to extract and classify vibration responses for crack detection. The results show that the proposed approach is effective in real-time damage detection.

COMPOSITE STRUCTURES (2024)

Article Mechanics

The effect of load concentration on one-way response of 3D-woven sandwich panels

Maryam Mirsalehi, Kiarash Kianpour, Sharif Shahbeyk, Mohammad Bakhshi

Summary: This study comprehensively investigates the one-way response of 3D-woven sandwich panels (3DWSPs) and their interfering parameters, providing interpretation of elastic and failure results, failure maps, and reliable theoretical models for linear elastic response and observed failure mechanisms.

COMPOSITE STRUCTURES (2024)

Article Mechanics

A unified hybrid Ritz-SEA acoustic vibration coupling method of a rectangular plate coupled with fast multipole boundary integration

Yiming Zhao, Zhonggang Wang, Zhigang Yang, Bin Qin

Summary: The paper proposes a Ritz and statistical energy analysis (Ritz SEA) hybrid method for calculating rectangular plate acoustic vibration coupling in the mid-frequency range. This method combines the fast convergence and ability to handle arbitrary boundary conditions of the Ritz method with the power flow equation of the statistical energy analysis method. The results show that this approach effectively filters out random fluctuations in mid-frequency domains while demonstrating exceptional stability and precision.

COMPOSITE STRUCTURES (2024)

Article Mechanics

Strength and manufacturability enhancement of a composite automotive component via an integrated finite element/artificial neural network multi-objective optimization approach

Joao Henrique Fonseca, Woojung Jang, Dosuck Han, Naksoo Kim, Hyungyil Lee

Summary: This study addresses the enhancement of an injection-molded fiber-reinforced plastic / metal hybrid automotive structure and its plastic injection molding process through the integration of the finite element method, artificial intelligence, and evolutionary search methods. Experimental validation of finite element models, the generation of a database through orthogonal array and Latin hypercube methods, and the training of artificial neural networks are conducted. The genetic optimization algorithm is then applied to identify optimal process parameters. The results show significant reduction in product warpage and manufacturing time while maintaining structural strength, contributing to the advancement of composite automotive structures with superior quality.

COMPOSITE STRUCTURES (2024)

Article Mechanics

Post-buckling behavior and collapse of Double-Double composite single stringer specimens

Alessandro Vescovini, Carina Xiaochen Li, Javier Paz Mendez, Bo Cheng Jin, Andrea Manes, Chiara Bisagni

Summary: This paper presents a study on six single-stringer specimens manufactured using the card-sliding technique with non-crimp fabrics and adopting a Double-Double (DD) stacking sequence. The specimens were tested under compression loading conditions to investigate post-buckling and failure in aerospace structures. Experimental results and numerical simulations were compared to analyze the behavior and failure modes of the specimens. The study found promising evidence of a viable solution to optimize aeronautical structures and enhance resistance to skin-stringer separation, particularly with the use of tapered flanges.

COMPOSITE STRUCTURES (2024)