Cyclic (Amino)(aryl)carbenes (CAArCs) as Strong σ-Donating and π-Accepting Ligands for Transition Metals

Correlations and Contrasts in Homo- and Heteroleptic Cyclic (Alkyl)(amino)carbene-Containing Pt0Complexes

(2015) Nicole Arnold et al.   CHEMISTRY-A EUROPEAN JOURNAL

Determining the Ligand Properties of N-Heterocyclic Carbenes from77Se NMR Parameters

(2015) Kathrin Verlinden et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Highly Selective Hydrogenation of Aromatic Ketones and Phenols Enabled by Cyclic (Amino)(alkyl)carbene Rhodium Complexes

(2015) Yu Wei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

What can NMR spectroscopy of selenoureas and phosphinidenes teach us about the π-accepting abilities of N-heterocyclic carbenes?

(2015) Sai V. C. Vummaleti et al.   Chemical Science

Cyclic (Alkyl)(Amino)Carbenes (CAACs): Stable Carbenes on the Rise

(2014) Michèle Soleilhavoup et al.   ACCOUNTS OF CHEMICAL RESEARCH

One-, Two-, and Three-Electron Reduction of a Cyclic Alkyl(amino)carbene-SbCl3Adduct

(2014) Robert Kretschmer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C4Cumulene and the Corresponding Air-Stable Radical Cation and Dication

(2014) Yan Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Isolation of a Neutral Boron-Containing Radical Stabilized by a Cyclic (Alkyl)(Amino)Carbene

(2014) Philipp Bissinger et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Two-Coordinate Fe0and Co0Complexes Supported by Cyclic (alkyl)(amino)carbenes

(2014) Gaël Ung et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reductive generation of stable, five-membered N,N′-diamidocarbenes

(2014) Jonathan P. Moerdyk et al.   CHEMICAL COMMUNICATIONS

Gold-Catalyzed Hydroarylation of Alkenes with Dialkylanilines

(2014) Xingbang Hu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An overview of N-heterocyclic carbenes

(2014) Matthew N. Hopkinson et al.   NATURE

Isolation of Neutral Mono- and Dinuclear Gold Complexes of Cyclic (Alkyl)(amino)carbenes

(2013) David S. Weinberger et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

31P NMR Chemical Shifts of Carbene-Phosphinidene Adducts as an Indicator of the π-Accepting Properties of Carbenes

(2013) Olivier Back et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Functionalization of C(sp2)H and C(sp3)H Bonds by Using Bidentate Directing Groups

(2013) Guy Rouquet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Anti-Bredt N-heterocyclic carbene: an efficient ligand for the gold(i)-catalyzed hydroamination of terminal alkynes with parent hydrazine

(2013) María J. López-Gómez et al.   CHEMICAL COMMUNICATIONS

Phosphaalkene vs. phosphinidene: the nature of the P–C bond in carbonyl-decorated carbene → PPh adducts

(2013) Roberta R. Rodrigues et al.   CHEMICAL COMMUNICATIONS

Quantifying and understanding the electronic properties of N-heterocyclic carbenes

(2013) David J. Nelson et al.   CHEMICAL SOCIETY REVIEWS

Bottleable (Amino)(Carboxy) Radicals Derived from Cyclic (Alkyl)(Amino) Carbenes

(2013) Janell K. Mahoney et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Acyclic Germylones: Congeners of Allenes with a Central Germanium Atom

(2013) Yan Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Formation of a 1,4-Diamino-2,3-disila-1,3-butadiene Derivative

(2013) Kartik Chandra Mondal et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Determining the π-Acceptor Properties of N-Heterocyclic Carbenes by Measuring the 77Se NMR Chemical Shifts of Their Selenium Adducts

(2013) Annika Liske et al.   ORGANOMETALLICS

Stable Carbenes: From ‘Laboratory Curiosities' to Catalysis Mainstays

(2013) Tomislav Rovis et al.   SYNLETT

Carbene-stabilized main group radicals and radical ions

(2013) Caleb D. Martin et al.   Chemical Science

A Cyclic Diaminocarbene with a Pyramidalized Nitrogen Atom: A Stable N-Heterocyclic Carbene with Enhanced Electrophilicity

(2012) David Martin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From C(sp2)–H to C(sp3)–H: systematic studies on transition metal-catalyzed oxidative C–C formation

(2012) Bi-Jie Li et al.   CHEMICAL SOCIETY REVIEWS

Diamidocarbenes as versatile and reversible [2 + 1] cycloaddition reagents

(2012) Jonathan P. Moerdyk et al.   Nature Chemistry

Tuning the Electronic Properties of Carbenes: A Systematic Comparison of Neighboring Amino versus Amido Groups

(2012) Garrett A. Blake et al.   ORGANOMETALLICS

Retracted Article: Homonuclear bond activation using a stable N,N′-diamidocarbene

(2012) Kelly M. Wiggins et al.   Chemical Science

Gold-Catalyzed Hydroamination of Alkynes and Allenes with Parent Hydrazine

(2011) Rei Kinjo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene Catalyzed Domino Reactions

(2011) André Grossmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Towards mild metal-catalyzed C–H bond activation

(2011) Joanna Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

A Brief Survey of Our Contribution to Stable Carbene Chemistry

(2011) David Martin et al.   ORGANOMETALLICS

Synthesis and Characterization of a Neutral Tricoordinate Organoboron Isoelectronic with Amines

(2011) R. Kinjo et al.   SCIENCE

Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes

(2010) Mohand Melaimi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of SiH, BH, and PH Bonds at a Single Nonmetal Center

(2010) Guido D. Frey et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

A Crystalline Phosphinyl Radical Cation

(2010) Olivier Back et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phthalazin-2-ylidenes As Cyclic Amino Aryl Carbene Ligands in Rhodium(I) and Iridium(I) Complexes

(2010) Antonio Magriz et al.   ORGANOMETALLICS

Stable singlet carbenes as mimics for transition metal centers

(2010) David Martin et al.   Chemical Science

Palladium- and Copper-Catalyzed Arylation of Carbon−Hydrogen Bonds

(2009) Olafs Daugulis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality

(2009) Xiao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stable Noncyclic Singlet Carbenes

(2009) Joan Vignolle et al.   CHEMICAL REVIEWS

13C NMR Spectroscopy of “Arduengo-type” Carbenes and Their Derivatives

(2009) Daniela Tapu et al.   CHEMICAL REVIEWS

Carbenes Introduction

(2009) Anthony J. Arduengo et al.   CHEMICAL REVIEWS

Synthesis of a Simplified Version of Stable Bulky and Rigid Cyclic (Alkyl)(amino)carbenes, and Catalytic Activity of the Ensuing Gold(I) Complex in the Three-Component Preparation of 1,2-Dihydroquinoline Derivatives

(2009) Xiaoming Zeng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

AnN,N′-Diamidocarbene: Studies in C−H Insertion, Reversible Carbonylation, and Transition-Metal Coordination Chemistry

(2009) Todd W. Hudnall et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Homogeneous Catalytic Hydroamination of Alkynes and Allenes with Ammonia

(2008) Vincent Lavallo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heterocyclic Carbenes: Synthesis and Coordination Chemistry

(2008) F. Ekkehardt Hahn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of (NHC)Rh(cod)Cl and (NHC)RhCl(CO)2 complexes – Translation of the Rh- into the Ir-scale for the electronic properties of NHC ligands

(2008) Stefanie Wolf et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Quinoline-Tethered N-Heterocyclic Carbene Complexes of Rhodium and Iridium: Synthesis, Catalysis, and Electrochemical Properties

(2008) Hong Mei Peng et al.   ORGANOMETALLICS