期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 40, 页码 4483-4485出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc41279b
关键词
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资金
- DOE [DE-FG02-09ER16069]
- university of Oviedo
- FICYT
- Principado de Asturias
An anti-Bredt N-heterocyclic carbene gold(I) chloride complex was synthesized by taking advantage of the reversible insertion of the free carbene into the NH bond of hexamethyldisilazane. This precatalyst promotes the parent hydrazine hydroamination of terminal alkynes at room temperature.
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