Chemoselective Silylative Reduction of Conjugated Nitriles under Metal-Free Catalytic Conditions: β-Silyl Amines and Enamines

Markovnikov-Selective Hydrosilylation of Electron-Deficient Alkenes with Arylsilanes Catalyzed by Mono(phosphine)palladium(0)

(2015) Nobuyuki Komine et al.   ORGANOMETALLICS

Direct Catalytic Access to N-Silylated Enamines from Enolizable Imines and Hydrosilanes by Base-Free Dehydrogenative SiN Coupling

(2014) Julia Hermeke et al.   CHEMISTRY-A EUROPEAN JOURNAL

Metal-Free Reduction of Secondary and Tertiary N-Phenyl Amides by Tris(pentafluorophenyl)boron-Catalyzed Hydrosilylation

(2014) Ryan C. Chadwick et al.   JOURNAL OF ORGANIC CHEMISTRY

Boron-Catalyzed Silylative Reduction of Quinolines: Selective sp3 C–Si Bond Formation

(2014) Narasimhulu Gandhamsetty et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct observation of a borane–silane complex involved in frustrated Lewis-pair-mediated hydrosilylations

(2014) Adrian Y. Houghton et al.   Nature Chemistry

Hydrogenation by Frustrated Lewis Pairs: Main Group Alternatives to Transition Metal Catalysts?

(2014) Lindsay J. Hounjet et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Mild and selective hydrogenation of aromatic and aliphatic (di)nitriles with a well-defined iron pincer complex

(2014) Christoph Bornschein et al.   Nature Communications

3-Silylated Cyclohexa-1,4-dienes as Precursors for Gaseous Hydrosilanes: The B(C6F5)3-Catalyzed Transfer Hydrosilylation of Alkenes

(2013) Antoine Simonneau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

SiH Bond Activation: Bridging Lewis Acid Catalysis with Brookhart’s Iridium(III) Pincer Complex and B(C6F5)3

(2013) Tobias Robert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Quantum Chemical Study of B(C6F5)3-Catalyzed Hydrosilylation of Carbonyl Group

(2013) Ken Sakata et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhenium-mediated dehydrogenative silylation and highly regioselective hydrosilylation of nitrile substituted olefins

(2013) Hailin Dong et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Metal-Free Borane-Catalyzed Highly Stereoselective Hydrogenation of Pyridines

(2013) Yongbing Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental Analysis of the Catalytic Cycle of the Borane-Promoted Imine Reduction with Hydrosilanes: Spectroscopic Detection of Unexpected Intermediates and a Refined Mechanism

(2013) Julia Hermeke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free Hydrogenation of N-Based Heterocycles

(2013) Tayseer Mahdi et al.   ORGANOMETALLICS

Silyl Ketene Imines: Highly Versatile Nucleophiles for Catalytic, Asymmetric Synthesis

(2012) Scott E. Denmark et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Illuminating the Mechanism of the Borane-Catalyzed Hydrosilylation of Imines with Both an Axially Chiral Borane and Silane

(2012) Marius Mewald et al.   CHEMISTRY-A EUROPEAN JOURNAL

Organosilicon Molecules with Medicinal Applications

(2012) Annaliese K. Franz et al.   JOURNAL OF MEDICINAL CHEMISTRY

Facile Activation of H–H and Si–H Bonds by Boranes

(2012) Georgii I. Nikonov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic functionalization of unactivated primary C–H bonds directed by an alcohol

(2012) Eric M. Simmons et al.   NATURE

Diastereoselective synthesis of vicinal amino alcohols

(2012) Oskari K. Karjalainen et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Iron Catalysts for Selective Anti-Markovnikov Alkene Hydrosilylation Using Tertiary Silanes

(2012) A. M. Tondreau et al.   SCIENCE

Facile Catalytic Hydrosilylation of Pyridines

(2011) Dmitry V. Gutsulyak et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Exploring Organosilane Amines as Potent Inhibitors and Structural Probes of Influenza A Virus M2 Proton Channel

(2011) Jun Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemoselective Catalytic Hydrosilylation of Nitriles

(2010) Dmitry V. Gutsulyak et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-free reductions of N-heterocycles via Lewis acid catalyzed hydrogenation

(2010) Stephen J. Geier et al.   CHEMICAL COMMUNICATIONS

B(C6F5)3-Promoted Tandem Silylation and Intramolecular Hydrosilylation: Diastereoselective Synthesis of Oxasilinanes and Oxasilepanes

(2010) Roman Shchepin et al.   ORGANIC LETTERS

On the Mechanism of B(C6F5)3-Catalyzed Direct Hydrogenation of Imines: Inherent and Thermally Induced Frustration

(2009) Tibor András Rokob et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An efficient metal-free reduction using diphenylsilane with (tris–perfluorophenyl)borane as catalyst

(2009) MeiXuan Tan et al.   TETRAHEDRON LETTERS

Conclusive Evidence for an SN2-Si Mechanism in the B(C6F5)3-Catalyzed Hydrosilylation of Carbonyl Compounds: Implications for the Related Hydrogenation

(2008) Sebastian Rendler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Free Catalytic Hydrogenation of Enamines, Imines, and Conjugated Phosphinoalkenylboranes

(2008) Patrick Spies et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lewis acid-catalyzed hydrogenation: B(C6F5)3-mediated reduction of imines and nitriles with H2

(2008) Preston A. Chase et al.   CHEMICAL COMMUNICATIONS

Heterolytic dihydrogen activation with the 1,8-bis(diphenylphosphino)naphthalene/B(C6F5)3 pair and its application for metal-free catalytic hydrogenation of silyl enol ethers

(2008) Huadong Wang et al.   CHEMICAL COMMUNICATIONS