Silyl Ketene Imines: Highly Versatile Nucleophiles for Catalytic, Asymmetric Synthesis

Lewis Base Catalyzed Enantioselective Additions of an N-Silyl Vinylketene Imine

(2012) Scott E. Denmark et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The thriving chemistry of ketenimines

(2012) Ping Lu et al.   CHEMICAL SOCIETY REVIEWS

Enantioselective synthesis of all-carbon quaternary stereogenic centers in acyclic systems

(2011) Jaya Prakash Das et al.   CHEMICAL COMMUNICATIONS

The Vinylogous Aldol and Related Addition Reactions: Ten Years of Progress†

(2011) Giovanni Casiraghi et al.   CHEMICAL REVIEWS

Employing homoenolates generated by NHC catalysis in carbon–carbon bond-forming reactions: state of the art

(2011) Vijay Nair et al.   CHEMICAL SOCIETY REVIEWS

Revisiting Keteniminium Salts: More than the Nitrogen Analogs of Ketenes

(2011) Claire Madelaine et al.   Chemistry-An Asian Journal

Enantioselective α-Arylation ofN-Acyloxazolidinones with Copper(II)-bisoxazoline Catalysts and Diaryliodonium Salts

(2011) Aurélien Bigot et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Quantification of the Electrophilic Reactivities of Aldehydes, Imines, and Enones

(2011) Roland Appel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective α-Arylation of Aldehydes via the Productive Merger of Iodonium Salts and Organocatalysis

(2011) Anna E. Allen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Mannich Reactions with α-Aryl Silyl Ketene Acetals and Imines

(2011) Gregory T. Notte et al.   ORGANIC LETTERS

A New Synthesis of Pyrrolidines by Way of an Enantioselective Mannich/Diastereoselective Hydroamination Reaction Sequence

(2011) Jenny M. Baxter Vu et al.   ORGANIC LETTERS

Mechanistically Driven Development of Iridium Catalysts for Asymmetric Allylic Substitution

(2010) John F. Hartwig et al.   ACCOUNTS OF CHEMICAL RESEARCH

Metal-Catalyzed α-Arylation of Carbonyl and Related Molecules: Novel Trends in CC Bond Formation by CH Bond Functionalization

(2010) Carin C. C. Johansson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Catalytic Asymmetric Addition of Allyl Cyanide to Ketones via Soft Lewis Acid/Hard Brønsted Base/Hard Lewis Base Catalysis

(2010) Ryo Yazaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-silyl oxyketene imines are underused yet highly versatile reagents for catalytic asymmetric synthesis

(2010) Scott E. Denmark et al.   Nature Chemistry

Construction of Quaternary Stereogenic Carbon Centers by the Lewis Base Catalyzed Conjugate Addition of Silyl Ketene Imines to α,β-Unsaturated Aldehydes and Ketones

(2010) Scott Denmark et al.   SYNLETT

Nucleophile Generation via Decarboxylation: Asymmetric Construction of Contiguous Trisubstituted and Quaternary Stereocenters through a Cu(I)-Catalyzed Decarboxylative Mannich-Type Reaction

(2009) Liang Yin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrazides as Tunable Reagents for Alkene Hydroamination and Aminocarbonylation

(2009) Jean-Grégoire Roveda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Catalytic Asymmetric Addition of Allyl Cyanide to Ketones

(2009) Ryo Yazaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A unique approach to aldol products for the creation of all-carbon quaternary stereocentres

(2009) Jaya Prakash Das et al.   Nature Chemistry

Stereoselective Formation of α-Quaternary Stereocenters in the Mannich Reaction

(2009) Erica A. Tiong et al.   ORGANIC LETTERS

Lewis Base Catalysis in Organic Synthesis

(2008) Scott E. Denmark et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances in carbon–carbon bond-forming reactions involving homoenolates generated by NHC catalysis

(2008) Vijay Nair et al.   CHEMICAL SOCIETY REVIEWS

Direct Catalytic Asymmetric Addition of Allylic Cyanides to Ketoimines

(2008) Ryo Yazaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalysed asymmetric Mannich reactions

(2007) Jorge M. M. Verkade et al.   CHEMICAL SOCIETY REVIEWS