期刊
CHEMISTRY-AN ASIAN JOURNAL
卷 7, 期 9, 页码 2090-2095出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201200192
关键词
diazapyrenes; deep-blue emission; fluorescence; nonlinear optics; two-photon absorption
资金
- Singapore Ministry of Education through the Academic Research Fund (Tier 1) [RG63/10]
- Singapore National Research Foundation through the Competitive Research Programme (CRP) [NRF-CRP5-2009-04]
- Science & Engineering Research Council for A*STAR [082 101 0019]
Efficient violetblue-emitting molecules are especially useful for applications in full-color displays, solid-state lighting, as well as in two-photon absorption (TPA) excited frequency-upconverted violetblue lasing. However, the reported violetblue-emitting molecules generally possess small TPA cross sections. In this work, new 1,8-diazapyrenes derivatives 3 with blue two-photon-excited fluorescence emission were concisely synthesized by the coupling reaction of readily available 1,4-naphthoquinone O,O-diacetyl dioxime (1) with internal alkynes 2 under the [{RhCl2Cp*}2]Cu(OAc)2 (Cp*=pentamethylcyclopentadienyl ligand) bimetallic catalytic system. Elongation of the p-conjugated length of 1,8-diazapyrenes 3 led to the increase of TPA cross sections without the expense of a redshift of the emission wavelength, probably due to the rigid planar structure of chromophores. It is especially noteworthy that 2,3,6,7-tetra(4-bromophenyl)-1,8-diazapyrene (3?c) has a larger TPA cross section than those of other molecules reported so far. These experimental results are explained in terms of the effects of extension of the p-conjugated system, intramolecular charge transfer, and reduced detuning energy.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据