4.6 Article

Nanoelectrocatalyst based on high-density Au/Pt hybrid nanoparticles supported on a silica nanosphere

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CHEMISTRY-AN ASIAN JOURNAL
卷 3, 期 7, 页码 1156-1162

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WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.200700422

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electrochemistry; fuel cell; gold; nanostructures; X-ray absorption spectroscopy

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A high-efficiency nanoelectrocatalyst based on high-density Au/Pt hybrid nanoparticles supported on a silica nanosphere (Au-Pt/SiO2) has been prepared by a facile wet chemical method. Scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy are employed to characterize the obtained Au-Pt/SiO2. It was found that each hybrid nanosphere is composed of high-density small Au/Pt hybrid nanoparticles with rough surfaces. These small Au/Pt hybrid nanoparticles interconnect and form a porous nanostructure, which provides highly accessible activity sites, as required for high electrocatalytic activity. We suggest that the particular morphology of the AuPt/SiO2 may be the reason for the high catalytic activity. Thus, this hybrid nanomaterial may find a potential application in fuel cells.

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