Iridium Complexes Containing Mesoionic C Donors: Selective C(sp3)H versus C(sp2)H Bond Activation, Reactivity Towards Acids and Bases, and Catalytic Oxidation of Silanes and Water

Carbene iridium complexes for efficient water oxidation: scope and mechanistic insights

(2014) James A. Woods et al.   Energy & Environmental Science

Mechanistic Aspects of Water Oxidation Catalyzed by Organometallic Iridium Complexes

(2013) Arianna Savini et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Carbene Transfer from Triazolylidene Gold Complexes as a Potent Strategy for Inducing High Catalytic Activity

(2013) Daniel Canseco-Gonzalez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cation–cation bonding in nitrenium metal complexes

(2013) Yuri Tulchinsky et al.   Chemical Science

Unconventional Reactivity of Imidazolylidene Pyridylidene Ligands in Iridium(III) and Rhodium(III) Complexes

(2012) Candela Segarra et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Application of 1,2,3-triazolylidenes as versatile NHC-type ligands: synthesis, properties, and application in catalysis and beyond

(2012) Kate F. Donnelly et al.   CHEMICAL COMMUNICATIONS

Comparison of primary oxidants for water-oxidation catalysis

(2012) Alexander R. Parent et al.   CHEMICAL SOCIETY REVIEWS

PEPPSI-Type Palladium Complexes Containing Basic 1,2,3-Triazolylidene Ligands and Their Role in Suzuki-Miyaura Catalysis

(2012) Daniel Canseco-Gonzalez et al.   CHEMISTRY-A EUROPEAN JOURNAL

Water Oxidation with Molecularly Defined Iridium Complexes: Insights into Homogeneous versus Heterogeneous Catalysis

(2012) Henrik Junge et al.   CHEMISTRY-A EUROPEAN JOURNAL

Abnormal, mesoionic and remote N-heterocyclic carbene complexes

(2012) Robert H. Crabtree   COORDINATION CHEMISTRY REVIEWS

Photolytic water oxidation catalyzed by a molecular carbene iridium complex

(2012) Ana Petronilho et al.   DALTON TRANSACTIONS

Rhodium and Iridium Complexes with Chelating C–C′-Imidazolylidene–Pyridylidene Ligands: Systematic Approach to Normal, Abnormal, and Remote Coordination Modes

(2012) Candela Segarra et al.   ORGANOMETALLICS

Organometallic Iridium Catalysts Based on Pyridinecarboxylate Ligands for the Oxidative Splitting of Water

(2012) Alberto Bucci et al.   ORGANOMETALLICS

Rhodium-Catalyzed Hydrosilylation of Ketones: Catalyst Development and Mechanistic Insights

(2012) Korbinian Riener et al.   ACS Catalysis

Catalytic Oxidation of Silanes by Carbon Nanotube-Gold Nanohybrids

(2011) Jubi John et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Abnormal N-heterocyclic Carbenes: More than Just Exceptionally Strong Donor Ligands

(2011) Anneke Krüger et al.   AUSTRALIAN JOURNAL OF CHEMISTRY

Rhodium Carbene Complexes as Versatile Catalyst Precursors for SiH Bond Activation

(2011) Anneke Krüger et al.   CHEMISTRY-A EUROPEAN JOURNAL

Protonolysis of a Ruthenium–Carbene Bond and Applications in Olefin Metathesis

(2011) Benjamin K. Keitz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Evolution of Iridium-Based Molecular Catalysts during Water Oxidation with Ceric Ammonium Nitrate

(2011) Douglas B. Grotjahn et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nitrenium ions as ligands for transition metals

(2011) Yuri Tulchinsky et al.   Nature Chemistry

Neutral species from “non-protic” N-heterocyclic ionic liquids

(2011) Oldamur Hollóczki et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

An Iridium(IV) Species, [Cp*Ir(NHC)Cl]+, Related to a Water-Oxidation Catalyst

(2011) Timothy P. Brewster et al.   ORGANOMETALLICS

Bis(1,2,3-triazol-5-ylidenes) (i-bitz) as Stable 1,4-Bidentate Ligands Based on Mesoionic Carbenes (MICs)

(2011) Gregorio Guisado-Barrios et al.   ORGANOMETALLICS

Synthesis of Highly Stable 1,3-Diaryl-1H-1,2,3-triazol-5-ylidenes and Their Applications in Ruthenium-Catalyzed Olefin Metathesis

(2011) Jean Bouffard et al.   ORGANOMETALLICS

“Rollover” cyclometalation – early history, recent developments, mechanistic insights and application aspects

(2011) Burkhard Butschke et al.   Chemical Science

Water Oxidation Catalyzed by Strong Carbene-Type Donor-Ligand Complexes of Iridium

(2010) Ralte Lalrempuia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes

(2010) Mohand Melaimi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Crystalline 1H-1,2,3-Triazol-5-ylidenes: New Stable Mesoionic Carbenes (MICs)

(2010) Gregorio Guisado-Barrios et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium(iii) molecular catalysts for water oxidation: the simpler the faster

(2010) Arianna Savini et al.   CHEMICAL COMMUNICATIONS

C—H Bond Activation in Transition Metal Species from a Computational Perspective

(2010) David Balcells et al.   CHEMICAL REVIEWS

One-Step Conversion of AzineN-Oxides to α-1,2,4-Triazolo-, 1,2,3-Triazolo, Imidazolo-, and Pyrazoloheteroarenes

(2010) John M. Keith   JOURNAL OF ORGANIC CHEMISTRY

Half-Sandwich Iridium Complexes for Homogeneous Water-Oxidation Catalysis

(2010) James D. Blakemore et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrosilylation of Carbonyl-Containing Substrates Catalyzed by an Electrophilic η1-Silane Iridium(III) Complex

(2010) Sehoon Park et al.   ORGANOMETALLICS

Oxygen−Oxygen Bond Formation Pathways Promoted by Ruthenium Complexes

(2009) Sophie Romain et al.   ACCOUNTS OF CHEMICAL RESEARCH

Water as green oxidant: a highly selective conversion of organosilanes to silanols with water

(2009) Bhanu P. S. Chauhan et al.   APPLIED ORGANOMETALLIC CHEMISTRY

Rhodium-mediated activation of an alkane-type C–H bond

(2009) Anneke Krüger et al.   CHEMICAL COMMUNICATIONS

Beyond ConventionalN-Heterocyclic Carbenes: Abnormal, Remote, and Other Classes of NHC Ligands with Reduced Heteroatom Stabilization

(2009) Oliver Schuster et al.   CHEMICAL REVIEWS

Carbenes Introduction

(2009) Anthony J. Arduengo et al.   CHEMICAL REVIEWS

Cyclometalation Using d-Block Transition Metals: Fundamental Aspects and Recent Trends

(2009) Martin Albrecht   CHEMICAL REVIEWS

Methyleneimidazoline Complexes of Iridium, Rhodium, and Palladium from Selective C(sp3)H Bond Activation

(2009) Guoyong Song et al.   CHEMISTRY-A EUROPEAN JOURNAL

On the Electronic Impact of Abnormal C4-Bonding in N-Heterocyclic Carbene Complexes

(2009) Marion Heckenroth et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Active and Robust Cp* Iridium Complexes for Catalytic Water Oxidation

(2009) Jonathan F. Hull et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

On the Chemical Stabilities of Ionic Liquids

(2009) Subbiah Sowmiah et al.   MOLECULES

Isolation of a C5-Deprotonated Imidazolium, a Crystalline "Abnormal" N-Heterocyclic Carbene

(2009) E. Aldeco-Perez et al.   SCIENCE

Synthesis and Ligand Properties of Stable Five‐Membered‐Ring Allenes Containing Only Second‐Row Elements

(2008) Vincent Lavallo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Coordination Chemistry of Ene-1,1-diamines and a Prototype “Carbodicarbene”

(2008) Alois Fürstner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heterocyclic Carbenes: Synthesis and Coordination Chemistry

(2008) F. Ekkehardt Hahn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C4-bound imidazolylidenes: from curiosities to high-impact carbene ligands

(2008) Martin Albrecht   CHEMICAL COMMUNICATIONS

Reactivity of Phosphane–Imidazolium Salts Towards [Ir(COD)Cl]2: Preparation of New Hydridoiridium(III) Complexes Bearing Abnormal Carbenes

(2008) Joffrey Wolf et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Analysis of the Concerted Metalation-Deprotonation Mechanism in Palladium-Catalyzed Direct Arylation Across a Broad Range of Aromatic Substrates

(2008) Serge I. Gorelsky et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

1,2,3-Triazolylidenes as Versatile Abnormal Carbene Ligands for Late Transition Metals

(2008) Paulson Mathew et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium Abnormal N-Heterocyclic Carbene Hydrides via Highly Selective C−H Activation

(2008) Guoyong Song et al.   ORGANOMETALLICS

Flexible, Bowl-Shaped N-Heterocyclic Carbene Ligands: Substrate Specificity in Iridium-Catalyzed Ketone Hydrosilylation

(2008) Anthony R. Chianese et al.   ORGANOMETALLICS

Cyclometalated Iridium(III) Aquo Complexes:  Efficient and Tunable Catalysts for the Homogeneous Oxidation of Water

(2007) Neal D. McDaniel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY