☆ 4.6 Article

Highly Efficient and Chemoselective Zinc-Catalyzed Hydrosilylation of Esters under Mild Conditions

CHEMISTRY-A EUROPEAN JOURNAL (2015)

期刊

CHEMISTRY-A EUROPEAN JOURNAL

卷 21, 期 7, 页码 2785-2788

出版社

WILEY-V C H VERLAG GMBH

DOI: 10.1002/chem.201406176

关键词

alcohols; esters; hydrosilylation; reduction; zinc

类别

Chemistry, Multidisciplinary

资金

Knut and Alice Wallenberg Foundation
Swedish Research Council

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Protocol

Reagent

摘要

A mild and highly efficient catalytic hydrosilylation protocol for room-temperature ester reductions has been developed using diethylzinc as the catalyst. The methodology is operationally simple, displays high functional group tolerance and provides for a facile access to a broad range of different alcohols in excellent yields.

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