The Nature of the UC Double Bond: Pushing the Stability of High-Oxidation-State Uranium Carbenes to the Limit

Giant Spin-Orbit Effects on NMR Shifts in Diamagnetic Actinide Complexes: Guiding the Search of Uranium(VI) Hydride Complexes in the Correct Spectral Range

(2012) Peter Hrobárik et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

New Reactivity of the Uranyl(VI) Ion

(2012) Robert J. Baker   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis, Molecular and Electronic Structure of UV(O)[N(SiMe3)2]3

(2012) Skye Fortier et al.   INORGANIC CHEMISTRY

Synthesis of a Uranium(VI)-Carbene: Reductive Formation of Uranyl(V)-Methanides, Oxidative Preparation of a [R2C═U═O]2+ Analogue of the [O═U═O]2+ Uranyl Ion (R = Ph2PNSiMe3), and Comparison of the Nature of UIV═C, UV═C, and UVI═C Double Bonds

(2012) David P. Mills et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Probing the 5f Orbital Contribution to the Bonding in a U(V) Ketimide Complex

(2012) Lani A. Seaman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Uranium(VI) Terminal Oxo Complexes: Molecular Geometry Driven by the Inverse Trans-Influence

(2012) Boris Kosog et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Direct Route to Bis(imido)uranium(V) Halides via Metathesis of Uranium Tetrachloride

(2012) Robert E. Jilek et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Determining Relative f and d Orbital Contributions to M–Cl Covalency in MCl62– (M = Ti, Zr, Hf, U) and UOCl5– Using Cl K-Edge X-ray Absorption Spectroscopy and Time-Dependent Density Functional Theory

(2012) Stefan G. Minasian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Structure of a Terminal Uranium Nitride Complex

(2012) D. M. King et al.   SCIENCE

Uranium-Carbon Multiple Bonding: Facile Access to the Pentavalent Uranium Carbene [U{C(PPh2NSiMe3)2}(Cl)2(I)] and Comparison of UVC and UIVC Bonds

(2011) Oliver J. Cooper et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Early metal bis(phosphorus-stabilised)carbene chemistry

(2011) Stephen T. Liddle et al.   CHEMICAL SOCIETY REVIEWS

Evaluating f-Element Bonding from Structure and Thermodynamics

(2011) Stefan G. Minasian et al.   CHEMISTRY-A EUROPEAN JOURNAL

Syntheses, Structures, and Reactivities of Homometallic Rare-Earth-Metal Multimethyl Methylidene and Oxo Complexes

(2011) Jianquan Hong et al.   CHEMISTRY-A EUROPEAN JOURNAL

The ThC double bond: an experimental and computational study of thorium poly-carbene complexes

(2011) Wenshan Ren et al.   DALTON TRANSACTIONS

Actinide Metals with Multiple Bonds to Carbon: Synthesis, Characterization, and Reactivity of U(IV) and Th(IV) Bis(iminophosphorano)methandiide Pincer Carbene Complexes

(2011) Guibin Ma et al.   INORGANIC CHEMISTRY

Synthesis of a Phosphorano-Stabilized U(IV)-Carbene via One-Electron Oxidation of a U(III)-Ylide Adduct

(2011) Skye Fortier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

High-Valent Uranium Alkyls: Evidence for the Formation of UVI(CH2SiMe3)6

(2011) Skye Fortier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Exploring the Uranyl Organometallic Chemistry: From Single to Double Uranium−Carbon Bonds

(2011) Jean-Christophe Tourneux et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ln4(CH2)4Cubane-Type Rare-Earth Methylidene Complexes Consisting of “(C5Me4SiMe3)LnCH2” Units (Ln = Tm, Lu)

(2011) Wen-Xiong Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Group 1 Bis(iminophosphorano)methanides, Part 2:N-Aryl Derivatives of the Sterically Demanding Methanes H2C(PPh2NR)2(R = 2,4,6-trimethylphenyl or 2,6-diisopropylphenyl)

(2011) Ashley J. Wooles et al.   ORGANOMETALLICS

Uranium(IV) Nucleophilic Carbene Complexes

(2011) Jean-Christophe Tourneux et al.   ORGANOMETALLICS

A Monomeric Dilithio Methandiide with a Distorted trans-Planar Four-Coordinate Carbon

(2010) Oliver J. Cooper et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Amido-stabilized rare-earth metal mixed methyl methylidene complexes

(2010) Melanie Zimmermann et al.   CHEMICAL COMMUNICATIONS

The Effect of the Equatorial Environment on Oxo-Group Silylation of the Uranyl Dication: A Computational Study

(2010) Ahmed Yahia et al.   CHEMISTRY-A EUROPEAN JOURNAL

Covalency in AnCp4 (An = Th–Cm): a comparison of molecular orbital, natural population and atoms-in-molecules analyses

(2010) Matthew J. Tassell et al.   DALTON TRANSACTIONS

Synthesis and structure of [U{C(PPh2NMes)2}2] (Mes = 2,4,6-Me3C6H2): A homoleptic uranium bis(carbene) complex with two formal UC double bonds

(2010) Oliver J. Cooper et al.   DALTON TRANSACTIONS

Easy access to uranium nucleophilic carbene complexes

(2010) Jean-Christophe Tourneux et al.   DALTON TRANSACTIONS

Transmetalation Reactions of a Scandium Complex Supported by a Ferrocene Diamide Ligand

(2010) Wenliang Huang et al.   INORGANIC CHEMISTRY

Regioselective C−H Activation and Sequential C−C and C−O Bond Formation Reactions of Aryl Ketones Promoted by an Yttrium Carbene

(2010) David P. Mills et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cation-Cation Interactions, Magnetic Communication, and Reactivity of the Pentavalent Uranium Ion [U(NtBu)2]+

(2009) Liam P. Spencer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium-Based Heterocyclic Carbene-Coordinated Olefin Metathesis Catalysts†

(2009) Georgios C. Vougioukalakis et al.   CHEMICAL REVIEWS

First neodymium(iii) alkyl-carbene complex based on bis(iminophosphoranyl) ligands

(2009) Antoine Buchard et al.   DALTON TRANSACTIONS

Synthesis and reactivity of the yttrium-alkyl-carbene complex [Y(BIPM)(CH2C6H5)(THF)] (BIPM = {C(PPh2NSiMe3)2})

(2009) David P. Mills et al.   DALTON TRANSACTIONS

A tribute to Frederick Nye Tebbe. Lewis acid stabilized alkylidyne, alkylidene, and imides of 3d early transition metals

(2009) Jennifer Scott et al.   DALTON TRANSACTIONS

Lanthanide tri-benzyl complexes: structural variations and useful precursors to phosphorus-stabilised lanthanide carbenes

(2009) Ashley J. Wooles et al.   DALTON TRANSACTIONS

Metal–ligand multiple bonding in uranium: structure and reactivity

(2009) Trevor W. Hayton   DALTON TRANSACTIONS

A Heterobimetallic Gallyl Complex Containing an Unsupported Ga−Y Bond

(2009) Stephen T. Liddle et al.   INORGANIC CHEMISTRY

The UC Double Bond: Synthesis and Study of Uranium Nucleophilic Carbene Complexes

(2009) Thibault Cantat et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis, Structure, and Bonding of Stable Complexes of Pentavalent Uranyl

(2009) Grégory Nocton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Heteroleptic [M(CH2C6H5)2(I)(THF)3] Complexes (M = Y or Er): Remarkably Stable Precursors to Yttrium and Erbium T-Shaped Carbenes

(2009) David P. Mills et al.   ORGANOMETALLICS

A Rare-Earth Metal Variant of the Tebbe Reagent

(2008) Rannveig Litlabø et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and structural characterisation of an yttrium–alkyl–alkylidene

(2008) Stephen T. Liddle et al.   CHEMICAL COMMUNICATIONS

Bis-phosphorus stabilised carbene complexes

(2008) Thibault Cantat et al.   DALTON TRANSACTIONS

Infrared Spectra and Electronic Structures of Agostic Uranium Methylidene Molecules

(2008) Jonathan T. Lyon et al.   INORGANIC CHEMISTRY

Synthesis and Characterization of Three Homoleptic Alkoxides of Uranium: [Li(THF)]2[UIV(OtBu)6], [Li(Et2O)][UV(OtBu)6], and UVI(OtBu)6

(2008) Skye Fortier et al.   INORGANIC CHEMISTRY

Lewis Acid Stabilized Methylidene and Oxoscandium Complexes

(2008) Jennifer Scott et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Imido Exchange in Bis(imido) Uranium(VI) Complexes with Aryl Isocyanates

(2008) Liam P. Spencer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organometallic Uranium(V)−Imido Halide Complexes: From Synthesis to Electronic Structure and Bonding

(2008) Christopher R. Graves et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbon Dioxide Activation with Sterically Pressured Mid- and High-Valent Uranium Complexes

(2008) Suzanne C. Bart et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ln(iii) methyl and methylidene complexes stabilized by a bulky hydrotris(pyrazolyl)borate ligand

(2007) Melanie Zimmermann et al.   CHEMICAL COMMUNICATIONS