期刊
DALTON TRANSACTIONS
卷 40, 期 38, 页码 9662-9664出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1dt11149c
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资金
- National Natural Science Foundation of China [20972018, 21074013, 21073016]
- Program for New Century Excellent Talents in University [NCET-10-0253]
- Fundamental Research Funds for the Central Universities
- Beijing Municipal Commission of Education
The first thorium poly-carbene complexes [(Ph2P=S)(2)C](2)-Th(DME) (2) and [{[(Ph2P=S)(2)C](3)Th}Li-2(DME)](n) ( 3) have been prepared and structurally characterized. DFT calculations reveal that the Th=C bond is polarized toward the nucleophilic carbene carbon atom, which is further verified by the experimental observation that the Th=C bond shows a nucleophilic behavior with Ph2CO.
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