期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 16, 页码 6928-6931出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja301243t
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资金
- National Institutes of Health [GM-64444]
A double migratory cascade reaction of alpha-halogen-substituted propargylic phosphates to produce highly functionalized 1,3-dienes has been developed. This transformation features 1,3-phosphatyloxy group migration followed by 1,3-shifts of bromine and chlorine as well as the unprecedented 1,3-migration of iodine. The reaction is stereodivergent: (Z)-1,3-dienes are formed in the presence of a copper catalyst, whereas gold-catalyzed reactions exhibit inverted stereoselectivity, producing the corresponding E products.
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