Catalytic metal-free Si–N cross-dehydrocoupling

Palladium-Catalyzed Oxidative Cross-Coupling between Heterocycles and Terminal Alkynes with Low Catalyst Loading

(2013) Xiaoming Jie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic dehydrogenative Si–N coupling of pyrroles, indoles, carbazoles as well as anilines with hydrosilanes without added base

(2013) C. David F. Königs et al.   CHEMICAL COMMUNICATIONS

E–H (E = R3Si or H) bond activation by B(C6F5)3 and heteroarenes; competitive dehydrosilylation, hydrosilylation and hydrogenation

(2013) Liam D. Curless et al.   CHEMICAL COMMUNICATIONS

Mechanisms of metal-catalyzed dehydrocoupling reactions

(2013) Rory Waterman   CHEMICAL SOCIETY REVIEWS

N-Heterocyclic Carbene Organocatalysts for Dehydrogenative Coupling of Silanes and Hydroxyl Compounds

(2013) Dongjing Gao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Generation of Borenium Ions by Cooperative B–H Bond Activation: The Elusive Direct Electrophilic Borylation of Nitrogen Heterocycles with Pinacolborane

(2013) Timo Stahl et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C(sp3)–F Bond Activation of CF3-Substituted Anilines with Catalytically Generated Silicon Cations: Spectroscopic Evidence for a Hydride-Bridged Ru–S Dimer in the Catalytic Cycle

(2013) Timo Stahl et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental Analysis of the Catalytic Cycle of the Borane-Promoted Imine Reduction with Hydrosilanes: Spectroscopic Detection of Unexpected Intermediates and a Refined Mechanism

(2013) Julia Hermeke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalysis in service of main group chemistry offers a versatile approach to p-block molecules and materials

(2013) Erin M. Leitao et al.   Nature Chemistry

Hetero-dehydrocoupling of silanes and amines by heavier alkaline earth catalysis

(2013) Michael S. Hill et al.   Chemical Science

Electronic effects of triarylphosphines in metal-free hydrogen activation: a kinetic and computational study

(2013) Lutz Greb et al.   Chemical Science

Metal-free Catalytic Olefin Hydrogenation: Low-Temperature H2 Activation by Frustrated Lewis Pairs

(2012) Lutz Greb et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective Rhodium(III)-Catalyzed Cross-Dehydrogenative Coupling of Furan and Thiophene Derivatives

(2012) Nadine Kuhl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Zinc-Catalyzed Dehydrogenative N-Silylation of Indoles with Hydrosilanes

(2012) Teruhisa Tsuchimoto et al.   CHEMISTRY-A EUROPEAN JOURNAL

[2.2]Paracyclophane derived bisphosphines for the activation of hydrogen by FLPs: application in domino hydrosilylation/hydrogenation of enones

(2012) Lutz Greb et al.   DALTON TRANSACTIONS

Ruthenium carbonyl-catalysed Si–heteroatom X coupling (X = S, O, N)

(2012) Chun Keong Toh et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Base-Free Dehydrogenative Coupling of Enolizable Carbonyl Compounds with Silanes

(2012) C. David F. Königs et al.   ORGANIC LETTERS

Reactions of Hydrosilanes with Transition Metal Complexes and Characterization of the Products

(2011) Joyce Y. Corey   CHEMICAL REVIEWS

Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

(2011) Charles S. Yeung et al.   CHEMICAL REVIEWS

Mechanistic Aspects of Bond Activation with Perfluoroarylboranes

(2011) Warren E. Piers et al.   INORGANIC CHEMISTRY

Metal-Free Catalytic Hydrogenation of Polar Substrates by Frustrated Lewis Pairs

(2011) Douglas W. Stephan et al.   INORGANIC CHEMISTRY

Cooperative Catalytic Activation of Si−H Bonds by a Polar Ru−S Bond: Regioselective Low-Temperature C−H Silylation of Indoles under Neutral Conditions by a Friedel−Crafts Mechanism

(2011) Hendrik F. T. Klare et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tris(oxazolinyl)boratomagnesium-Catalyzed Cross-Dehydrocoupling of Organosilanes with Amines, Hydrazine, and Ammonia

(2011) James F. Dunne et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-free reductions of N-heterocycles via Lewis acid catalyzed hydrogenation

(2010) Stephen J. Geier et al.   CHEMICAL COMMUNICATIONS

Lewis acid mediated P–P bond hydrogenation and hydrosilylation

(2010) Stephen J. Geier et al.   CHEMICAL COMMUNICATIONS

Beyond Traditional Cross Couplings: The Scope of the Cross Dehydrogenative Coupling Reaction

(2010) Caroline J. Scheuermann   Chemistry-An Asian Journal

Tandem Frustrated Lewis Pair/Tris(pentafluorophenyl)borane-Catalyzed Deoxygenative Hydrosilylation of Carbon Dioxide

(2010) Andreas Berkefeld et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dehydrogenation as a Substrate-Activating Strategy in Homogeneous Transition-Metal Catalysis

(2009) Graham E. Dobereiner et al.   CHEMICAL REVIEWS

Cross-Dehydrogenative Coupling (CDC): Exploring C−C Bond Formations beyond Functional Group Transformations

(2008) Chao-Jun Li   ACCOUNTS OF CHEMICAL RESEARCH

Reactions at the Ru-S Bonds of Coordinatively Unsaturated Ruthenium Complexes with Tethered 2,6-Dimesitylphenyl Thiolate

(2008) Yasuhiro Ohki et al.   Chemistry-An Asian Journal