Electronic effects of triarylphosphines in metal-free hydrogen activation: a kinetic and computational study

Reactivity Models of Hydrogen Activation by Frustrated Lewis Pairs: Synergistic Electron Transfers or Polarization by Electric Field?

(2013) Tibor András Rokob et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Anionic N-Heterocyclic Carbenes That Contain a Weakly Coordinating Borate Moiety

(2012) Sabrina Kronig et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-free Catalytic Olefin Hydrogenation: Low-Temperature H2 Activation by Frustrated Lewis Pairs

(2012) Lutz Greb et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective organocatalytic reductive amination of aliphatic ketones by benzothiazoline as hydrogen donor

(2012) Kodai Saito et al.   CHEMICAL COMMUNICATIONS

Metal-free hydrogenation catalysis of polycyclic aromatic hydrocarbons

(2012) Yasutomo Segawa et al.   CHEMICAL COMMUNICATIONS

Transfer hydrogenation with Hantzsch esters and related organic hydride donors

(2012) Chao Zheng et al.   CHEMICAL SOCIETY REVIEWS

Enantioselective Hydrosilylation with Chiral Frustrated Lewis Pairs

(2012) Dianjun Chen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Supramolecular Binding Thermodynamics by Dispersion-Corrected Density Functional Theory

(2012) Stefan Grimme   CHEMISTRY-A EUROPEAN JOURNAL

Theoretical analysis of cooperative effects of small molecule activation by frustrated Lewis pairs

(2012) Christian Mück-Lichtenfeld et al.   DALTON TRANSACTIONS

[2.2]Paracyclophane derived bisphosphines for the activation of hydrogen by FLPs: application in domino hydrosilylation/hydrogenation of enones

(2012) Lutz Greb et al.   DALTON TRANSACTIONS

Asymmetric hydrogenation of imines with a recyclable chiral frustrated Lewis pair catalyst

(2012) Ghazi Ghattas et al.   DALTON TRANSACTIONS

Basicity of Phosphanes and Diphosphanes in Acetonitrile

(2012) Kristjan Haav et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Reactions of Modified Intermolecular Frustrated P/B Lewis Pairs with Dihydrogen, Ethene, and Carbon Dioxide

(2012) Marcel Harhausen et al.   ORGANOMETALLICS

Frustrated Lewis Pair Behavior of Intermolecular Amine/B(C6F5)3 Pairs

(2012) Tanja Voss et al.   ORGANOMETALLICS

Chiral Phosphoric Acid Catalyzed Transfer Hydrogenation: Facile Synthetic Access to Highly Optically Active Trifluoromethylated Amines

(2011) Alexander Henseler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heterolytic Cleavage of Dihydrogen by “Frustrated Lewis Pairs” Comprising Bis(2,4,6-tris(trifluoromethyl)phenyl)borane and Amines: Stepwise versus Concerted Mechanism

(2011) Zhenpin Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemistry of a geminal frustrated Lewis pair featuring electron withdrawing C6F5 substituents at both phosphorus and boron

(2011) Annika Stute et al.   CHEMICAL COMMUNICATIONS

Catalytic Hydrogenation with Frustrated Lewis Pairs: Selectivity Achieved by Size-Exclusion Design of Lewis Acids

(2011) Gábor Erős et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanistic Aspects of Bond Activation with Perfluoroarylboranes

(2011) Warren E. Piers et al.   INORGANIC CHEMISTRY

Metal-Free Catalytic Hydrogenation of Polar Substrates by Frustrated Lewis Pairs

(2011) Douglas W. Stephan et al.   INORGANIC CHEMISTRY

Effect of the damping function in dispersion corrected density functional theory

(2011) Stefan Grimme et al.   JOURNAL OF COMPUTATIONAL CHEMISTRY

Molecular Hydrogen Tweezers: Structure and Mechanisms by Neutron Diffraction, NMR, and Deuterium Labeling Studies in Solid and Solution

(2011) Felix Schulz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dihydrogen Activation withtBu3P/B(C6F5)3: A Chemically Competent Indirect Mechanism via in Situ-Generatedp-tBu2P–C6F4–B(C6F5)2

(2011) Adam J. V. Marwitz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Readily available hydrogen bond catalysts for the asymmetric transfer hydrogenation of nitroolefins

(2011) Jakob F. Schneider et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Heterolytic Cleavage of H2by Frustrated B/N Lewis Pairs

(2011) Chunfang Jiang et al.   ORGANOMETALLICS

Design of frustrated Lewis pair catalysts for metal-free and selective hydrogenation

(2011) Tibor Soós   PURE AND APPLIED CHEMISTRY

The COSMO and COSMO-RS solvation models

(2011) Andreas Klamt   Wiley Interdisciplinary Reviews-Computational Molecular Science

Enantioselective Organocatalytic Transfer Hydrogenation of α-Imino Esters by Utilization of Benzothiazoline as Highly Efficient Reducing Agent

(2010) Chen Zhu et al.   ADVANCED SYNTHESIS & CATALYSIS

Exploring the Reactivity of Carbon(0)/Borane-Based Frustrated Lewis Pairs

(2010) Manuel Alcarazo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Expanding the Scope of Metal-Free Catalytic Hydrogenation through Frustrated Lewis Pair Design

(2010) Gábor Erős et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Hydrogenation with Chiral Frustrated Lewis Pairs

(2010) Dianjun Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Probing substituent effects on the activation of H2 by phosphorus and boron frustrated Lewis pairs

(2010) Rebecca C. Neu et al.   DALTON TRANSACTIONS

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu

(2010) Stefan Grimme et al.   JOURNAL OF CHEMICAL PHYSICS

Equilibrium Acidities of Superacids

(2010) Agnes Kütt et al.   JOURNAL OF ORGANIC CHEMISTRY

Methyl cation affinity (MCA) values for phosphanes

(2010) Christoph Lindner et al.   JOURNAL OF PHYSICAL ORGANIC CHEMISTRY

Electrophilic Reactivity of the α,α-Dimethylbenzyl (Cumyl) Cation

(2010) Johannes Ammer et al.   MACROMOLECULES

Effect of the “Supersilyl” Group on the Reactivities of Allylsilanes and Silyl Enol Ethers

(2010) Hans A. Laub et al.   ORGANIC LETTERS

Mechanism of hydrogen activation by frustrated Lewis pairs: A molecular orbital approach

(2009) Andrea Hamza et al.   INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY

The B−H···H−P Dihydrogen Bonding in Ion Pair Complexes [(CF3)3BH−][HPH3−n(Me)n+] (n= 0−3) and Its Implication in H2Elimination and Activation Reactions

(2009) Shulin Gao et al.   JOURNAL OF PHYSICAL CHEMISTRY A

On the Mechanism of B(C6F5)3-Catalyzed Direct Hydrogenation of Imines: Inherent and Thermally Induced Frustration

(2009) Tibor András Rokob et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lutidine/B(C6F5)3: At the Boundary of Classical and Frustrated Lewis Pair Reactivity

(2009) Stephen J. Geier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rationalizing the Reactivity of Frustrated Lewis Pairs: Thermodynamics of H2Activation and the Role of Acid−Base Properties

(2009) Tibor András Rokob et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Benzothiazoline: Highly Efficient Reducing Agent for the Enantioselective Organocatalytic Transfer Hydrogenation of Ketimines

(2009) Chen Zhu et al.   ORGANIC LETTERS

Metal-Free Hydrogen Activation by the Frustrated Lewis Pairs of ClB(C6F5)2and HB(C6F5)2and Bulky Lewis Bases

(2009) Chunfang Jiang et al.   ORGANOMETALLICS

Cover Picture: Facile Heterolytic H2Activation by Amines and B(C6F5)3(Angew. Chem. Int. Ed. 32/2008)

(2008) Victor Sumerin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogen and Amine Activation by a Frustrated Lewis Pair of a Bulky N-Heterocyclic Carbene and B(C6F5)3

(2008) Preston A. Chase et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heterolytic Dihydrogen Activation by a Frustrated Carbene-Borane Lewis Pair

(2008) Dirk Holschumacher et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lewis acid-catalyzed hydrogenation: B(C6F5)3-mediated reduction of imines and nitriles with H2

(2008) Preston A. Chase et al.   CHEMICAL COMMUNICATIONS

Heterolytic dihydrogen activation with the 1,8-bis(diphenylphosphino)naphthalene/B(C6F5)3 pair and its application for metal-free catalytic hydrogenation of silyl enol ethers

(2008) Huadong Wang et al.   CHEMICAL COMMUNICATIONS

Metal-free catalytic hydrogenation of imines with tris(perfluorophenyl)borane

(2008) Dianjun Chen et al.   CHEMICAL COMMUNICATIONS

Do general nucleophilicity scales exist?

(2008) Herbert Mayr et al.   JOURNAL OF PHYSICAL ORGANIC CHEMISTRY

Organocatalytic Asymmetric Transferhydrogenation of β-Nitroacrylates: Accessing β2-Amino Acids

(2008) Nolwenn J. A. Martin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible, Metal-Free, Heterolytic Activation of H2at Room Temperature

(2008) Matthias Ullrich et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

“Frustrated Lewis pairs”: a concept for new reactivity and catalysis

(2008) Douglas W. Stephan   ORGANIC & BIOMOLECULAR CHEMISTRY