Direct asymmetric syntheses of chiral aldehydes and ketones via N-acyl chiral auxiliary derivatives including chiral Weinreb amide equivalents

Crystallization-Induced Dynamic Resolution of Fox Chiral Auxiliary and Application to the Diastereoselective Electrophilic Fluorination of Amide Enolates

(2013) Hodney Lubin et al.   JOURNAL OF ORGANIC CHEMISTRY

Pseudoephenamine: A Practical Chiral Auxiliary for Asymmetric Synthesis

(2012) Marvin R. Morales et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis ofanti-α-Substituted β-Amino Ketones from Sulfinimines

(2011) Franklin A. Davis et al.   JOURNAL OF ORGANIC CHEMISTRY

Use of a Tandem Prins/Friedel–Crafts Reaction in the Construction of the Indeno-Tetrahydropyridine Core of the Haouamine Alkaloids: Formal Synthesis of (−)-Haouamine A

(2011) Erik Fenster et al.   ORGANIC LETTERS

A Formal Synthesis of SCH 351448

(2011) Heekwang Park et al.   ORGANIC LETTERS

Asymmetric Total Synthesis of the Antimalarial Drug (+)-Mefloquine Hydrochloride via ChiralN-Amino Cyclic Carbamate Hydrazones

(2011) John D. Knight et al.   ORGANIC LETTERS

Synthesis of α-S-Glycosphingolipids Based on Uronic Acids

(2011) Ciaran O’Reilly et al.   ORGANIC LETTERS

(+)-Sorangicin A: evolution of a viable synthetic strategy

(2011) Amos B. Smith et al.   TETRAHEDRON

Total synthesis of (5S)-dihydroyashabushiketol

(2011) Jan Romanski et al.   TETRAHEDRON-ASYMMETRY

Gephyronic Acid, a Missing Link between Polyketide Inhibitors of Eukaryotic Protein Synthesis (Part I): Structural Revision and Stereochemical Assignment of Gephyronic Acid

(2010) Lionel Nicolas et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper(II)-Catalyzed meta-Selective Direct Arylation of α-Aryl Carbonyl Compounds

(2010) Hung A. Duong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of Cycliccis-β-Amino Acid Derivatives Using Sulfinimines and Prochiral Weinreb Amide Enolates

(2010) Franklin A. Davis et al.   JOURNAL OF ORGANIC CHEMISTRY

On the Origins of Diastereoselectivity in the Alkylation of Enolates Derived fromN-1-(1′-Naphthyl)ethyl-O-tert-butylhydroxamates: Chiral Weinreb Amide Equivalents

(2010) Stephen G. Davies et al.   JOURNAL OF ORGANIC CHEMISTRY

Origins of Stereoselectivity in the α-Alkylation of Chiral Hydrazones

(2010) Elizabeth H. Krenske et al.   JOURNAL OF ORGANIC CHEMISTRY

Role of Pseudoephedrine as Chiral Auxiliary in the “Acetate-Type” Aldol Reaction with Chiral Aldehydes; Asymmetric Synthesis of Highly Functionalized Chiral Building Blocks

(2010) Marta Ocejo et al.   JOURNAL OF ORGANIC CHEMISTRY

Highly Diastereoselective α-Hydroxylation of Fox Chiral Auxiliary-Based Amide Enolates with Molecular Oxygen

(2010) Hodney Lubin et al.   ORGANIC LETTERS

Asymmetric Synthesis of Substituted Homotropinones fromN-Sulfinyl β-Amino Ketone Ketals. (−)-Euphococcinine and (−)-Adaline

(2010) Franklin A. Davis et al.   ORGANIC LETTERS

Asymmetric Total Synthesis and Structural Elucidation of NFAT-68

(2010) Lin Wang et al.   ORGANIC LETTERS

Alkylation and aldol reactions of acyl derivatives of N-1-(1′-naphthyl)ethyl-O-tert-butylhydroxylamine: asymmetric synthesis of α-alkoxy-, α-substituted-β-alkoxy- and α,β-dialkoxyaldehydes

(2010) Alexander N. Chernega et al.   TETRAHEDRON

Synthesis of a designed sesquiterpenoid that forms useful composites with peptides and related oligomers

(2010) Kenneth V. Lawson et al.   TETRAHEDRON LETTERS

Biocatalytic Strategies for the Asymmetric Synthesis of α-Hydroxy Ketones

(2009) Pilar Hoyos et al.   ACCOUNTS OF CHEMICAL RESEARCH

Decarboxylative Grob-Type Fragmentations in the Synthesis of TrisubstitutedZ Olefins: Application to Peloruside A, Discodermolide, and Epothilone D

(2009) Kathrin Prantz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Holy Grail of Organocatalysis: Intermolecular α-Alkylation of Aldehydes

(2009) Andrea-Nekane Alba et al.   ChemCatChem

Chiral iron complex catalyzed enantioselective oxidation of racemic benzoins

(2009) Pandi Muthupandi et al.   CHEMICAL COMMUNICATIONS

Epothilone Analogues with Benzimidazole and Quinoline Side Chains: Chemical Synthesis, Antiproliferative Activity, and Interactions with Tubulin

(2009) Silvia Anthoine Dietrich et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of (Z)-Trisubstituted Olefins by Decarboxylative Grob-Type Fragmentations: Epothilone D, Discodermolide, and Peloruside A

(2009) Kathrin Prantz et al.   CHEMISTRY-A EUROPEAN JOURNAL

Total Synthesis of (−)-Spirangien A, an Antimitotic Polyketide Isolated from the MyxobacteriumSorangium Cellulosum

(2009) Ian Paterson et al.   Chemistry-An Asian Journal

Convenient Access toβ-Substituted Chiral Phenones

(2009) Xiu-Fang Cao et al.   HELVETICA CHIMICA ACTA

Asymmetric aldol reactions using chiral CF3-Oxazolidines (Fox) as chiral auxiliary

(2009) Arnaud Tessier et al.   JOURNAL OF FLUORINE CHEMISTRY

Synthesis and Biochemical Analysis of Complex Chain-Elongation Intermediates for Interrogation of Molecular Specificity in the Erythromycin and Pikromycin Polyketide Synthases

(2009) Jonathan D. Mortison et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total Synthesis of Piericidin A1. Application of a Modified Negishi Carboalumination-Nickel-Catalyzed Cross-Coupling

(2009) Bruce H. Lipshutz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total Synthesis of Platensimycin and Related Natural Products

(2009) K. C. Nicolaou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Evolution of the Total Synthesis of (−)-Okilactomycin Exploiting a Tandem Oxy-Cope Rearrangement/Oxidation, a Petasis−Ferrier Union/Rearrangement, and Ring-Closing Metathesis

(2009) Amos B. Smith et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total synthesis of (5R,6R,8R,9S)-(−)-5,9Z-indolizidine 221T using sulfinimine-derived N-sulfinyl β-amino ketones

(2009) Franklin A. Davis et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Organocatalyzed direct asymmetric α-halogenation of carbonyl compounds

(2009) Mitsuhiro Ueda et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Total Synthesis and Neuritotrophic Activity of Farinosone C and Derivatives

(2009) Henning J. Jessen et al.   ORGANIC LETTERS

The Chiral AuxiliaryN-1-(1′-Naphthyl)ethyl-O-tert-butylhydroxylamine: A Chiral Weinreb Amide Equivalent

(2009) Alexander N. Chernega et al.   ORGANIC LETTERS

Asymmetric Synthesis of Substituted Tropinones Using the Intramolecular Mannich Cyclization Reaction and AcyclicN-Sulfinyl β-Amino Ketone Ketals

(2009) Franklin A. Davis et al.   ORGANIC LETTERS

Simple and Efficient Asymmetric α‐Alkylation and α,α‐Bisalkylation of Acyclic Ketones by Using Chiral N‐Amino Cyclic Carbamate Hydrazones

(2008) Daniel Lim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Preparation of 2,4-Disubstituted Cyclopentenones by Enantioselective Iridium-Catalyzed Allylic Alkylation: Synthesis of 2′-Methylcarbovir andTEI-9826

(2008) Pierre Dübon et al.   CHEMISTRY-A EUROPEAN JOURNAL

Fluorine⋅⋅⋅ and π⋅⋅⋅Alkali Metal Interactions Control in the Stereoselective Amide Enolate Alkylation with Fluorinated Oxazolidines (Fox) as a Chiral Auxiliary: An Experimental and Theoretical Study

(2008) Gjergji Sini et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Synthesis of 6′-Hydroxyarenarol: The Proposed Biosynthetic Precursor to Popolohuanone E

(2008) Rachel H. Munday et al.   JOURNAL OF ORGANIC CHEMISTRY

Highly Diastereoselective Synthetic Route to Enantiopure β2-Amino Acids and γ-Amino Alcohols Using a Fluorinated Oxazolidine (Fox) as Chiral Auxiliary

(2008) Arnaud Tessier et al.   JOURNAL OF ORGANIC CHEMISTRY

Stereocontrolled Alkylative Construction of Quaternary Carbon Centers

(2008) David A. Kummer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diastereoselective Synthesis of Cyclopentapyridazinones via Radical Cyclization: Synthetic Studies Toward Halichlorine

(2008) Gary E. Keck et al.   ORGANIC LETTERS

(S,S)-(+)-Pseudoephedrine α-Iminoglyoxylamide as a Chiral Glycine Cation Equivalent: A Modular and Flexible Approach to Enantioenriched α-Amino Ketones

(2008) Nerea Ruiz et al.   ORGANIC LETTERS

Total Synthesis of Amphidinolide J

(2008) Marion Barbazanges et al.   ORGANIC LETTERS

Stereoselective functionalisation of SuperQuat enamides: asymmetric synthesis of homochiral 1,2-diols and α-benzyloxy carbonyl compounds

(2008) Caroline Aciro et al.   TETRAHEDRON

Anodic cyclization reactions and the synthesis of (−)-crobarbatic acid

(2008) Hai-Chao Xu et al.   TETRAHEDRON LETTERS

Asymmetric aza-Michael addition: synthesis of (−)-allosedridine and (−)-2-epi-ethylnorlobelol

(2008) Li-Ju Chen et al.   TETRAHEDRON-ASYMMETRY