4.5 Article

Microwave-assisted methylation of cassava starch with dimethyl carbonate

期刊

CARBOHYDRATE RESEARCH
卷 346, 期 9, 页码 1178-1181

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.carres.2011.04.001

关键词

Cassava starch; Methylation; Dimethyl carbonate; Na2HPO4; Microwave irradiation

资金

  1. Natural Science Foundation of Guangdong Province, China [E06200692]
  2. Comprehensive Strategic Cooperation Project of Guangdong Province and Chinese Academy of Sciences, China [2009B091300052]
  3. Guangzhou Municipal Science and Technology Support Project, China [2008z1-D191]

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A novel and environmentally friendly process for the methylation of cassava starch with dimethyl carbonate (DMC) could be accelerated by employing a combined strategy: using disodium hydrogen phosphate (Na2HPO4) as the catalyst (chemical means) and microwave irradiation as the energy source (physical means). By varying the volume of 5% sodium chloride aqueous solution between 50 and 150 mL, the amount of Na2HPO4 between 0 and 1.25 g. the volume of DMC between 75 and 200 mL, and the microwave time from 5 to 20 min, methyl cassava starch with degree of substitution (DS) values in the range of 0.033 and 1.087 was prepared. The chemical structure of methyl cassava starch was analyzed by H-1 NMR spectroscopy. (C) 2011 Elsevier Ltd. All rights reserved.

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