Development of Cobalt-Catalyzed C–H Bond Functionalization Reactions

Low-Valent Cobalt Catalysis: New Opportunities for C–H Functionalization

(2014) Ke Gao et al.   ACCOUNTS OF CHEMICAL RESEARCH

Air-Stable Carbonyl(pentamethylcyclopentadienyl)cobalt Diiodide Complex as a Precursor for Cationic (Pentamethylcyclopentadienyl)cobalt(III) Catalysis: Application for Directed C-2 Selective CH Amidation of Indoles

(2014) Bo Sun et al.   ADVANCED SYNTHESIS & CATALYSIS

Cobalt-Catalyzedortho-CH Alkylation of 2-ArylpyridinesviaRing-Opening of Aziridines

(2014) Ke Gao et al.   ADVANCED SYNTHESIS & CATALYSIS

Cobalt-Catalyzed C-4 Selective Alkylation of Quinolines

(2014) Shohei Yamamoto et al.   ADVANCED SYNTHESIS & CATALYSIS

A Highly Modular One-Pot Multicomponent Approach to Functionalized Benzo[b]phosphole Derivatives

(2014) Bin Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structure and Reactivity of Late Transition Metal η3-Benzyl Complexes

(2014) Barry M. Trost et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pyrroloindolone Synthesis via a Cp*CoIII-Catalyzed Redox-Neutral Directed C–H Alkenylation/Annulation Sequence

(2014) Hideya Ikemoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Intramolecular Olefin Hydroarylation Leading to Dihydropyrroloindoles and Tetrahydropyridoindoles

(2013) Zhenhua Ding et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Cationic High-Valent Cp*CoIIIComplex for the Catalytic Generation of Nucleophilic Organometallic Species: Directed CH Bond Activation

(2013) Tatsuhiko Yoshino et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-Catalyzed C4-Selective Direct Alkylation of Pyridines

(2013) Takashi Andou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Approach to Benzophosphole Oxides through Silver- or Manganese-Mediated Dehydrogenative Annulation Involving CC and CP Bond Formation

(2013) Yuto Unoh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Versatile Synthesis of Benzothiophenes and Benzoselenophenes by Rapid Assembly of Arylzinc Reagents, Alkynes, and Elemental Chalcogens

(2013) Bin Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-catalyzed Branched-selective Addition of Aromatic Ketimines to Styrenes under Room-temperature Conditions

(2013) Jinghua Dong et al.   CHEMISTRY LETTERS

Silver-Mediated Oxidative C–H/P–H Functionalization: An Efficient Route for the Synthesis of Benzo[b]phosphole Oxides

(2013) Yun-Rong Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Ortho Alkylation of Aromatic Imines with Primary and Secondary Alkyl Halides

(2013) Ke Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

(2013) Joanna Wencel-Delord et al.   Nature Chemistry

Cobalt-catalyzed ortho-alkenylation of aromatic aldimines via chelation-assisted C–H bond activation

(2013) Takeshi Yamakawa et al.   TETRAHEDRON

Synthesis of Functionalized Benzo[b]thiophenes by the Intramolecular Copper-Catalyzed Carbomagnesiation of Alkynyl(aryl)thioethers

(2012) Thomas Kunz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-Catalyzed Direct Arylation and Benzylation by CH/CO Cleavage with Sulfamates, Carbamates, and Phosphates

(2012) Weifeng Song et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aldimine-Directed Branched-Selective Hydroarylation of Styrenes

(2012) Pin-Sheng Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Selective Synthesis

(2012) Jessada Mahatthananchai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-Catalyzed Addition of Arylzinc Reagents to Alkynes to Form ortho-Alkenylarylzinc Species through 1,4-Cobalt Migration

(2012) Boon-Hong Tan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild and Efficient C2-Alkenylation of Indoles with Alkynes Catalyzed by a Cobalt Complex

(2012) Zhenhua Ding et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

(2012) Junichiro Yamaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-catalyzed arylation of aldimines via directed C–H bond functionalization: addition of 2-arylpyridines and self-coupling of aromatic aldimines

(2012) Ke Gao et al.   CHEMICAL COMMUNICATIONS

Ir(I)-Catalyzed C–H Bond Alkylation of C2-Position of Indole with Alkenes: Selective Synthesis of Linear or Branched 2-Alkylindoles

(2012) Shiguang Pan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Ortho-Arylation of Aromatic Imines with Aryl Chlorides

(2012) Ke Gao et al.   ORGANIC LETTERS

Annulation of α,β-Unsaturated Imines and Alkynes via Cobalt-Catalyzed Olefinic C–H Activation

(2012) Takeshi Yamakawa et al.   ORGANIC LETTERS

Cobalt-Phenanthroline Catalysts for the ortho Alkylation of Aromatic Imines under Mild Reaction Conditions

(2011) Ke Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C–H functionalization logic in total synthesis

(2011) Will R. Gutekunst et al.   CHEMICAL SOCIETY REVIEWS

Towards mild metal-catalyzed C–H bond activation

(2011) Joanna Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Indium-Catalyzed Construction of Polycyclic Aromatic Hydrocarbon Skeletons via Dehydration

(2011) Yoichiro Kuninobu et al.   JOURNAL OF ORGANIC CHEMISTRY

Cobalt−Xantphos-Catalyzed, LiCl-Mediated Preparation of Arylzinc Reagents from Aryl Iodides, Bromides, and Chlorides

(2011) Meng-Yi Jin et al.   JOURNAL OF ORGANIC CHEMISTRY

Cobalt-Catalyzed Chemoselective Insertion of Alkene into the Ortho C−H Bond of Benzamide

(2011) Laurean Ilies et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed, Room-Temperature Addition of Aromatic Imines to Alkynes via Directed C–H Bond Activation

(2011) Pin-Sheng Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Coupling of Alkyl Grignard Reagent with Benzamide and 2-Phenylpyridine Derivatives through Directed C–H Bond Activation under Air

(2011) Quan Chen et al.   ORGANIC LETTERS

Palladium-Catalyzed Alkylation ofortho-C(sp2)–H Bonds of Benzylamide Substrates with Alkyl Halides

(2011) Yingsheng Zhao et al.   ORGANIC LETTERS

Cobalt-Catalyzed, Chelation-Assisted C-H Bond Functionalization

(2011) Naohiko Yoshikai   SYNLETT

Nickel-Catalyzed Hydroheteroarylation of Vinylarenes

(2010) Yoshiaki Nakao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Cross-Coupling of CH Bonds with Grignard Reagents through Cobalt Catalysis

(2010) Bin Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A review of new developments in the Friedel–Crafts alkylation – From green chemistry to asymmetric catalysis

(2010) Magnus Rueping et al.   Beilstein Journal of Organic Chemistry

Metal-catalyzed direct alkylations of (hetero)arenes via C–H bond cleavages with unactivated alkyl halides

(2010) Lutz Ackermann   CHEMICAL COMMUNICATIONS

Cobalt-Catalyzed Hydroarylation of Alkynes through Chelation-Assisted C−H Bond Activation

(2010) Ke Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Intermolecular Hydroarylation of Alkynes

(2010) Derek J. Schipper et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselectivity-Switchable Hydroarylation of Styrenes

(2010) Ke Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzedortho-Alkylation of Secondary Benzamide with Alkyl Chloride through Directed C−H Bond Activation

(2010) Quan Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Addition of Azoles to Alkynes

(2010) Zhenhua Ding et al.   ORGANIC LETTERS

Mechanistic Insight into Direct Arylations with Ruthenium(II) Carboxylate Catalysts

(2010) Lutz Ackermann et al.   ORGANIC LETTERS

Iron-Catalyzed Chemoselective ortho Arylation of Aryl Imines by Directed CH Bond Activation

(2009) Naohiko Yoshikai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium-Catalyzed Regioselective Direct Alkylation of Arenes with Unactivated Alkyl Halides through CH Bond Cleavage

(2009) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient Synthesis of Benzothiophenes by an Unusual Palladium-Catalyzed Vinylic CS Coupling

(2009) Christopher S. Bryan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

(2009) Denise A. Colby et al.   CHEMICAL REVIEWS

Cyclometalation Using d-Block Transition Metals: Fundamental Aspects and Recent Trends

(2009) Martin Albrecht   CHEMICAL REVIEWS

Platinum-Catalyzed Multisubstituted Benzo[b]selenophene Synthesis

(2009) Takuma Sato et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Cobalt-Catalyzed Arylzincation of Alkynes

(2009) Kei Murakami et al.   ORGANIC LETTERS

Synthesis of Dihydropyridines and Pyridines from Imines and Alkynes via C−H Activation

(2008) Denise A. Colby et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Direct Arylation through Directed C−H Bond Activation

(2008) Jakob Norinder et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Base-Mediated Cyclization Reaction of 2-Alkynylphenylphosphine Oxides: Synthesis and Photophysical Properties of Benzo[b]phosphole Oxides

(2008) Takanobu Sanji et al.   ORGANIC LETTERS

Modular Synthesis of Benzo[b]phosphole Derivatives via BuLi-Mediated Cyclization of (o-Alkynylphenyl)phosphine

(2008) Hayato Tsuji et al.   ORGANIC LETTERS

Transition-Metal-Catalyzed Carbon-Carbon Bond Formation via Carbon-Hydrogen Bond Cleavage

(2008) Fumitoshi Kakiuchi et al.   SYNTHESIS-STUTTGART

Rhodium-Catalyzed One-Pot Synthesis of Substituted Pyridine Derivatives from α,β-Unsaturated Ketoximes and Alkynes

(2007) Kanniyappan Parthasarathy et al.   ORGANIC LETTERS