期刊
BIOINORGANIC CHEMISTRY AND APPLICATIONS
卷 2010, 期 -, 页码 -出版社
HINDAWI LTD
DOI: 10.1155/2010/149149
关键词
-
资金
- NSERC (Canada)
- Minsitry of Higher Education, Egypt
Copyright c 2010 Shadia A. Elsayed et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. New complexes of dioxovanadium(V), zinc(II), ruthenium(II), palladium(II), and platinum(II) with 6-methylpyridine-2-carbaldehyde-N(4)-ethylthiosemicarbazone (HmpETSC) have been synthesized. The composition of these complexes is discussed on the basis of elemental analyses, IR, Raman, NMR (H-1, C-13, and P-31), and electronic spectral data. The X-ray crystal structures of [VO2(mpETSC)] and [Pt(mpETSC)Cl] are also reported. The HmpETSC and its [Zn(HmpETSC)Cl-2] and [Pd(mpETSC)Cl] complexes exhibit antineoplastic activity against colon cancer human cell lines (HCT 116).
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