Article
Materials Science, Multidisciplinary
E. Hug, C. Keller
Summary: The influence of grain size on the corrosion and passivation mechanisms of stainless steel 316L was investigated in this study. It was found that reducing grain size increases the passivation current density, but passivation treatment with HNO3 can enhance the stability of the passivation layer.
MATERIALS CHEMISTRY AND PHYSICS
(2023)
Article
Materials Science, Multidisciplinary
Khashayar Morshed-Behbahani, Nika Zakerin, Pooria Najafisayar, Mahmoud Pakshir
Summary: The research found that samples with less internal stress formed denser and less defective passive films on their surfaces, attributed to higher concentration of metal ions at the metal/solution interface during anodization process. Prolonged passivation times resulted in more impurities being incorporated into the growing passive film, deteriorating its electrochemical properties.
Article
Materials Science, Multidisciplinary
Rafael dos Santos Pereira, Roosevelt Droppa, Mara Cristina Lopes de Oliveira, Renato Altobelli Antunes
Summary: The study examined the effect of milling with different feed rates and depths of cut on the surface residual stresses and chemical composition of AISI 304 stainless steel samples. It was found that milling imparted higher surface stresses, compressive stresses, and chromium enrichment, leading to increased stability of the passive film for the milled samples.
JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE
(2021)
Article
Materials Science, Multidisciplinary
Ahmad Keyvani, Majid Naseri, Omid Imantalab, Davood Gholami, Kazem Babaei, Arash Fattah-alhosseini
Summary: This study investigates the effects of constrained groove pressing (CGP) on pure copper in a quiescent phosphate buffer solution, demonstrating improvements in passive behavior and reduced corrosion current density with increased CGP cycles. Microstructural, electrochemical, and mechanical characterizations were conducted to analyze the impact of CGP on copper material properties.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2021)
Article
Materials Science, Multidisciplinary
Yu Gao, Kai Chong, Linjing Qiao, Yuanxiao Li, Chang Liu, Fuqiang Guo, Dongting Wu, Yong Zou
Summary: The Mo15Nb20Ta10Ti35V20 refractory high entropy alloy with BCC structure was prepared by vacuum arc melting. The synthesized alloy demonstrated better corrosion resistance compared to 316 stainless steel in chloride corrosion environment, which is attributed to the complex passive film structure and shows the characteristics of passivation-transpassivation-secondary passivation on the polarization curve. Mott-Schottky curves analysis and XPS results reveal that the primary and secondary passive films have different P-N junctions composed of different oxides showing bilayer structure characteristics. The dynamic changes of TiO2 and Ti2O3 contents are responsible for the secondary passivation phenomenon.
MATERIALS & DESIGN
(2023)
Review
Chemistry, Physical
Ling Liu, Cuilin Fan, Hongying Sun, Fuxiao Chen, Junqing Guo, Tao Huang
Summary: This paper reviews the development of Alumina-Forming Austenitic (AFA) stainless steel and introduces its characteristics and composition design methods. It analyzes the influence of alloy elements and heat treatment process on the performance of this steel. Additionally, the corrosion resistance, mechanical properties, and creep properties of AFA steel are analyzed, and future research directions are explored.
Article
Nanoscience & Nanotechnology
Guosheng Sun, Jizi Liu, Yuntian Zhu
Summary: By introducing a bi-modal heterostructure, Luders deformation in UFG 304 stainless steel can be effectively suppressed, leading to improved ductility and toughness without sacrificing strength.
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
(2022)
Review
Engineering, Manufacturing
Di Zhang, Aobo Liu, Bangzhao Yin, Peng Wen
Summary: Duplex stainless steels (DSSs) are promising materials in many fields due to their excellent corrosion resistance and mechanical properties resulted from their microstructure, which consists of roughly equal amounts of austenite and ferrite phases. Additive manufacturing (AM) has shown great advantages in fabricating metal parts with complex geometries, however, achieving expected formation quality and microstructure simultaneously remains a challenge. Delicate control of processing conditions is highly required based on understanding of DSS materials and AM processes in order to optimize the fabrication process.
JOURNAL OF MANUFACTURING PROCESSES
(2022)
Review
Materials Science, Multidisciplinary
Pavel Dolzhenko, Marina Tikhonova, Marina Odnobokova, Rustam Kaibyshev, Andrey Belyakov
Summary: The aim of this review is to summarize recent achievements in the development of ultrafine-grained austenitic/ferritic stainless steels through large strain deformation. The paper discusses various methods of large strain deformation for producing ultrafine-grained metallic materials. It also explores the structural mechanisms responsible for grain refinement during plastic deformation and examines the physical and mechanical properties of ultrafine-grained stainless steels. The review concludes that the development of ultrafine-grained microstructures during severe plastic deformation is a result of continuous dynamic recrystallization, with the misorientations among strain-induced cells/subgrains progressively increasing.
Article
Materials Science, Multidisciplinary
Staffan Hertzman, Reza Naraghi, Sten Wessman, Rachel Pettersson, Ulrika Borggren, Jan Y. Jonsson, Niklas Hollander Pettersson, Mina Khoda Karami, Ali Kohan-Zade
Summary: Adding nitrogen to high-performance stainless steels improves strength, corrosion resistance, and weldability. Reliable databases are crucial for developing new stainless steels. A series of experiments were conducted to calibrate existing thermodynamic data, with results compared to equilibrium calculations.
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE
(2021)
Article
Chemistry, Physical
Nuria Rojas, Margarita Sanchez-Molina, Gema Sevilla, Ernesto Amores, Eluxka Almandoz, Joseba Esparza, Marlon R. Cruz Vivas, Carles Colominas
Summary: Different surface engineered coating systems were tested on various substrates to find cost-effective solutions for bipolar plates in proton exchange membrane water electrolysis. The Ti/TiN multi-layered coating on SS 321 showed the best performance, leading to reduced cost and improved corrosion resistance.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Materials Science, Multidisciplinary
Youssof Dandal, Cyrille Bazin, Francoise Pillier, Hubert Cachet, Alain Pailleret
Summary: The carrier density of electrodeposited methylammonium lead iodide perovskite (CH3NH3PbI3) can be adjusted within the range of 1017 to 1020 cm-3 by carefully selecting experimental parameters during the final two chemical conversion steps in the synthesis process. This method, which allows the production of perovskite thin films on large surfaces, was characterized using Mott-Schottky plots and scanning electron microscopy (SEM) and X-Ray Diffraction (XRD) analysis.
MATERIALS CHEMISTRY AND PHYSICS
(2023)
Article
Chemistry, Physical
Chang Liu, Yu Gao, Kai Chong, Fuqiang Guo, Dongting Wu, Yong Zou
Summary: This paper investigates the microstructure and corrosion resistance of FeCoCrNiNbx high-entropy alloys in a chloride ion environment. The results show that FeCoCrNiNb0.15 alloy exhibits the best corrosion resistance, with significantly lower corrosion current density and corrosion rate compared to 316LSS. The P-N junction improves the corrosion resistance of the passive film of FeCoCrNiNb0.15, while the passive film of FeCoCrNi mainly exhibits n-type semiconductor characteristics.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Materials Science, Multidisciplinary
Harishchandra Singh, Yi Xiong, Ekta Rani, Shubo Wang, Mourad Kharbach, Tian Zhou, Huai Yao, Yuran Niu, Alexei Zakharov, Graham King, Frank M. F. de Groot, Jukka Komi, Marko Huttula, Wei Cao
Summary: This study reveals that the nanometer-scaled chemical heterogeneity dominates the breakdown and corrosion behavior of cold-rolled SDSS, providing a deeper understanding of the corrosion of stainless steel and potential benefits for corrosion controls.
NPJ MATERIALS DEGRADATION
(2022)
Article
Materials Science, Multidisciplinary
Heon-Young Ha, Kyeong-Won Kim, Seong-Jun Park, Chang-Hoon Lee, Tae-Ho Lee, Hyun-Uk Hong, Joonoh Moon
Summary: Fe-20Mn-11.5Al-1.4C-5Cr lightweight stainless steel (LWSS) has equivalent or better resistance to pitting corrosion compared to Fe-11Cr stainless steel (SS), which can be attributed to its protective passive film with higher Cr and Al content, thicker thickness, and lower concentration of point defects.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2023)
Article
Chemistry, Physical
Qi-Wen Chen, Ze-Qing Guo, Jian-Ping Zhou
Summary: Multifunctional continuous solid solutions NFMTO-x were successfully synthesized via a one-step hydrothermal method by controlling the ratio of Mg and Fe. The NFMTO-x materials exhibited enhanced visible light response, effective adsorption and photocatalytic degradation of organic pollutants, CO2 methanation capability, and easy recyclability due to their magnetic properties. This research provides a significant multifunctional material for water purification.
APPLIED SURFACE SCIENCE
(2024)
Review
Chemistry, Physical
George E. Stan, Maziar Montazerian, Adam Shearer, Bryan W. Stuart, Francesco Baino, John C. Mauro, Jose M. F. Ferreira
Summary: Bioactive glasses have the ability to form strong bonds with tissues and release therapeutic ions. However, their biomechanical compatibility limits their use in load-bearing applications. The use of magnetron sputtering technology to fabricate BG coatings shows promise in improving their efficacy and potential for application.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Zhaoxuan Wang, Zhicheng Yan, Zhigang Qi, Yu Feng, Qi Chen, Ziqi Song, Meng Huang, Peng Jia, Ki Buem Kim, Weimin Wang
Summary: The corrosion behavior of Fe-60 and Fe-83 ribbons in 0.6 M NaCl was studied. Fe-60 exhibited a local corrosion mode and formed a stable passivation film with higher corrosion resistance, while Fe-83 showed a combination of local and global corrosion modes and had lower corrosion resistance. Controlling the precipitation of nanocrystalline phases and increasing the POx content in the passivation film significantly improved the corrosion resistance of Fe-based glassy alloys.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Hao-Kai Peng, Sheng-Yen Zheng, Wei-Ning Kao, Ting-Chieh Lai, Kai-Sheun Lee, Yung- Hsien Wu
Summary: This study investigates the effects of high energy/fluence proton radiation on the performance of HfZrOx-based FeFETs memory with different Zr content. The results show that the characteristics of FeFETs are influenced by proton radiation, and the extent of the influence depends on the Zr content. FeFETs with 50% Zr content exhibit minimal changes in memory window and demonstrate good endurance and retention performance.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Zongyi Yue, Guangyi Wang, Zengguang Huang, Sihua Zhong
Summary: In this study, AZO and ITO films were successfully tuned as excellent passivation layers for c-Si surfaces, achieving effective minority carrier lifetime and outstanding optical properties through the optimization of annealing temperature and interfacial silicon oxide.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Martin Hruska, Jan Kejzlar, Jaroslav Otta, Premysl Fitl, Michal Novotny, Jakub Cizek, Oksana Melikhova, Matej Micusik, Peter Machata, Martin Vrnata
Summary: This paper presents a detailed study on the hydrogen sensing capabilities of highly nanoporous black gold films. The films exhibit fast response and recovery times at low temperatures. Different levels of nanoporosity were prepared and tested to investigate the sensing properties, and it was found that nanoporous black gold is suitable for hydrogen sensing. The sensitivity of the film depends on its nanoporosity.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yupu Wang, Gaofeng Teng, Chun To Yiu, Junyi Zhu
Summary: In the study of BM-SCO and HSCO thin films, it was found that H vacancies tend to prefer sites near the external surface or oxygen vacancy channels (OVCs), while H interstitials prefer sites of oxygen on a layer that contains six-fold coordinated Co. These findings not only enrich the understanding of complex surface phenomena of defect formation but also provide an explanation for the reversibility during phase transformation.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Jiafeng Lu, Linping Teng, Qinxiao Zhai, Chunhua Wang, Matthieu Lancry, Ye Dai, Xianglong Zeng
Summary: In this study, we achieved full control of fiber nanograting orientation by manipulating laser polarization, and tailored space variant fiber nanogratings, which expanded the diversity in fiber nanograting engineering.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yibo Liu, Yujie Tao, Yue Liu, Qi Sun, Qinrong Lin, Kexin Kang, Qinghua Zhang, Qingjie Sun
Summary: This study investigates the wettability of the Ti-Cu-Fe multi-metal system, specifically the wetting behaviors of CuSi3 droplets on TC4 and 304SS plates. The results show that the CO2 + Ar gas atmosphere significantly affects interfacial mass transfer, thus influencing the wettability of the systems.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Jimei Liu, Fei Wang, Rong Guo, Yuqi Liu, Mengyu Zhang, Jaka Sunarso, Dong Liu
Summary: This study developed Co/MXene composites with anti-corrosion properties by varying the cobalt content. These composites exhibited remarkable electromagnetic absorption performance and high resistance to corrosion under various corrosive conditions. The study also revealed the mechanism of electron transfer from cobalt to MXene and the electromagnetic dissipation behavior originated from polarization loss alone.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Moujie Huang, Yongsong Ma, Jingbo Yang, Lingyun Xu, Hangqi Yang, Miao Wang, Xin Ma, Xin Xia, Junhao Yang, Deli Wang, Chuang Peng
Summary: Strong metal-support interactions (SMSIs) are important for enhancing catalytic activities and stability in thermal catalysis. This study demonstrates a method to create SMSIs in electrocatalysis using carbon nanotubes and Ru nanoparticles, resulting in excellent catalytic activity and stability.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Ravi Trivedi, Brinti Mondal, Nandini Garg, Brahmananda Chakraborty
Summary: This study explores the potential of biphenylene as a nanocarrier for the delivery of the anticancer drug cisplatin. It is found that biphenylene offers physical stability, rapid release rate, solubility, and bio-compatibilities compared to other nanocarriers. The adsorption of cisplatin on the surface of biphenylene involves charge transfer from cisplatin to biphenylene. The drug is shown to be released at body temperature in an acidic environment. Biphenylene also exhibits excellent cytotoxicity activity and cellular uptake of the drug. Overall, biphenylene shows promise as a potential nanocarrier for cisplatin delivery.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Hyun Jeong, Hyeong Chan Suh, Ga Hyun Cho, Rafael Salas-Montiel, Hayoung Ko, Ki Kang Kim, Mun Seok Jeong
Summary: In this study, a potential platform to enhance Raman scattering and increase the number of observable Raman modes in monolayer transition metal dichalcogenides (TMDs) was proposed. The platform consisted of large-scale arrays of gold micropillars (MPs), which were able to enhance the Raman intensity of TMDs and make difficult-to-detect Raman modes observable. The platform showed great industrial advantages and wide applicability due to its low cost, simple process, large controllable area, and short process time.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yasir Abbas, Shafqat Ali, Sajjad Ali, Waqar Azeem, Zareen Zuhra, Haoliang Wang, Mohamed Bououdina, Zhenzhong Sun
Summary: In this study, FeOx@SPNO-C core-shell nanospheres as a catalyst for degradation of sulfamethoxazole (SMX) were successfully synthesized. The synergistic interaction between FeOx and SPNO-C, high carbon charge density, and the presence of C = O groups and N/Fe-Nx sites were found to be key factors for the enhanced degradation of SMX.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Qiaoting Yang, Yuxiao Gong, Yan Qian, Zhou-Qing Xiao, Serge Cosnier, Xue-Ji Zhang, Robert S. Marks, Dan Shan
Summary: This study proposes a hierarchical confinement strategy to design Prussian blue nanoparticles (PB NPs) with satisfactory electrocatalytic ability and stability. The catalytic synthesis of PB NPs is achieved through a hydrothermal process, and the as-prepared PB@NH2MIL exhibits efficient electronic transmission and enhanced electrocatalytic properties.
APPLIED SURFACE SCIENCE
(2024)