Can a Ketone Be More Reactive than an Aldehyde? Catalytic Asymmetric Synthesis of Substituted Tetrahydrofurans

The Catalytic Asymmetric Mukaiyama-Michael Reaction of Silyl Ketene Acetals with α,β-Unsaturated Methyl Esters

(2018) Tim Gatzenmeier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Approaching sub-ppm-level asymmetric organocatalysis of a highly challenging and scalable carbon–carbon bond forming reaction

(2018) Han Yong Bae et al.   Nature Chemistry

Activation of olefins via asymmetric Brønsted acid catalysis

(2018) Nobuya Tsuji et al.   SCIENCE

Desymmetrizing Enantio- and Diastereoselective Selenoetherification through Supramolecular Catalysis

(2018) Jie Yang See et al.   ACS Catalysis

Catalytic Asymmetric [4+2]-Cycloaddition of Dienes with Aldehydes

(2017) Luping Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Catalysis via Cyclic, Aliphatic Oxocarbenium Ions

(2017) Sunggi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Chiral 1,4-Benzodioxanes and Chromans by Enantioselective Palladium-Catalyzed Alkene Aryloxyarylation Reactions

(2016) Naifu Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Extremely Active Organocatalysts Enable a Highly Enantioselective Addition of Allyltrimethylsilane to Aldehydes

(2016) Philip S. J. Kaib et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Allenes via Alkynylogous Mukaiyama Aldol Reaction

(2016) Aurélien Tap et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Biomimetic Approach to the Catalytic Enantioselective Synthesis of Flavonoids

(2016) Zhenyu Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Vinylogous Prins Cyclization: A Highly Diastereo- and Enantioselective Entry to Tetrahydrofurans

(2016) Youwei Xie et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silanediol-Catalyzed Chromenone Functionalization

(2016) Andrea M. Hardman-Baldwin et al.   ORGANIC LETTERS

Asymmetric Lewis acid organocatalysis of the Diels-Alder reaction by a silylated C-H acid

(2016) T. Gatzenmeier et al.   SCIENCE

Catalytic and enantioselective bromoetherification of olefinic 1,3-diols: mechanistic insight

(2016) Zhihai Ke et al.   TETRAHEDRON

Recent advances in the synthesis of tetrahydrofurans and applications in total synthesis

(2016) Aurélien de la Torre et al.   TETRAHEDRON

Asymmetric counteranion-directed Lewis acid organocatalysis for the scalable cyanosilylation of aldehydes

(2016) Zhipeng Zhang et al.   Nature Communications

Enantioselective Copper(I)-Catalyzed Alkynylation of Oxocarbenium Ions to Set Diaryl Tetrasubstituted Stereocenters

(2015) Srimoyee Dasgupta et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Development of Enantioselective Palladium-Catalyzed Alkene Carboalkoxylation Reactions for the Synthesis of Tetrahydrofurans

(2015) Brett A. Hopkins et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Development and Applications of Disulfonimides in Enantioselective Organocatalysis

(2015) Thomas James et al.   CHEMICAL REVIEWS

Enantioselective Copper-Catalyzed Alkynylation of Benzopyranyl Oxocarbenium Ions

(2015) Harathi D. Srinivas et al.   JOURNAL OF ORGANIC CHEMISTRY

Towards High-Performance Lewis Acid Organocatalysis

(2014) Lars Ratjen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Catalytic Asymmetric Abramov Reaction

(2014) Joyram Guin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Disulfonimide-Catalyzed Synthesis of δ-Amino-β-Ketoester Derivatives by Vinylogous Mukaiyama-Mannich Reactions

(2014) Qinggang Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Trimethylsilyl Iodide Mediated One-Pot Synthesis of 2-Allyl-2H-chromenes

(2014) Birakishore Padhi et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Catalytic Asymmetric Bromoetherification and Desymmetrization of Olefinic 1,3-Diols with C2-Symmetric Sulfides

(2014) Zhihai Ke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Strategies for the construction of tetrahydropyran rings in the synthesis of natural products

(2014) Nadiah Mad Nasir et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Selective Aldehyde Reduction in Ketoaldehydes with NaBH4-Na2CO3-H2O at Room Temperatures

(2014) Sosale Chandrasekhar et al.   SYNTHETIC COMMUNICATIONS

Catalytic Enantioselective Oxidative Cross-Coupling of Benzylic Ethers with Aldehydes

(2013) Zhilin Meng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Silver Phosphate Catalyzed Transformation ofortho-Alkynylaryl Ketones into 1H-Isochromene Derivatives through an Intramolecular-Cyclization/Enantioselective-Reduction Sequence

(2013) Masahiro Terada et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Three-Component Synthesis of Homoallylic Amines

(2013) Shikha Gandhi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tetrahydrofuran-Containing Macrolides: A Fascinating Gift from the Deep Sea

(2013) Adriana Lorente et al.   CHEMICAL REVIEWS

Chiral Anion Catalysis in the Enantioselective 1,4-Reduction of the 1-Benzopyrylium Ion as a Reactive Intermediate

(2013) Masahiro Terada et al.   CHEMISTRY-A EUROPEAN JOURNAL

Shedding Light on Organocatalysis-Light-Assisted Asymmetric Ion-Pair Catalysis for the Enantioselective Hydrogenation of Pyrylium Ions

(2013) Chien-Chi Hsiao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Disulfonimide-Catalyzed Asymmetric Synthesis of β3-Amino Esters Directly from N-Boc-Amino Sulfones

(2013) Qinggang Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bimolecular coupling reactions through oxidatively generated aromatic cations: scope and stereocontrol

(2013) Yubo Cui et al.   TETRAHEDRON

Highly Enantioselective Hetero-Diels-Alder Reaction of 1,3-Bis(silyloxy)-1,3-dienes with Aldehydes Catalyzed by Chiral Disulfonimide

(2012) Joyram Guin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Counteranion-Directed Catalysis: Concept, Definition, and Applications

(2012) Manuel Mahlau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Counteranion-Directed Catalytic Hosomi-Sakurai Reaction

(2012) Manuel Mahlau et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Asymmetric Addition of Aldehydes to Oxocarbenium Ions: A Dual Catalytic System for the Synthesis of Chromenes

(2012) Magnus Rueping et al.   ORGANIC LETTERS

Controlling Enantioselectivity in Additions to Cyclic Oxocarbenium Ions via Transition-Metal Catalysis

(2012) Mary Watson et al.   SYNLETT

Recent developments in the field of oxa-Michael reactions

(2011) Carl F. Nising et al.   CHEMICAL SOCIETY REVIEWS

Copper-Catalyzed Enantioselective Additions to Oxocarbenium Ions: Alkynylation of Isochroman Acetals

(2011) Prantik Maity et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dual Catalysis in Enantioselective Oxidopyrylium-Based [5 + 2] Cycloadditions

(2011) Noah Z. Burns et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Addition of Boronates to Chromene Acetals Catalyzed by a Chiral Brønsted Acid/Lewis Acid System

(2010) Philip N. Moquist et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Disulfonimide-Catalyzed Asymmetric Vinylogous and Bisvinylogous Mukaiyama Aldol Reactions

(2010) Lars Ratjen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Stereoselective α-Alkylation of Aldehydes with Stable Carbocations

(2010) Fides Benfatti et al.   Chemistry-An Asian Journal

A Powerful Chiral Counteranion Motif for Asymmetric Catalysis

(2009) Pilar García-García et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of (+)-Polyanthellin A

(2009) Matthew J. Campbell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diastereoselective synthesis of 2,5-disubstituted tetrahydrofurans

(2009) Gaël Jalce et al.   TETRAHEDRON-ASYMMETRY

Synthesis of AntiproliferativeCephalotaxus Esters and Their Evaluation against Several Human Hematopoietic and Solid Tumor Cell Lines: Uncovering Differential Susceptibilities to Multidrug Resistance

(2008) Joseph D. Eckelbarger et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Optically Active Monoacid Side-Chains ofCephalotaxusAlkaloids

(2008) Farouk Berhal et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Thiourea-Catalyzed Additions to Oxocarbenium Ions

(2008) Sarah E. Reisman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of six-membered oxygenated heterocycles through carbon–oxygen bond-forming reactions

(2008) Igor Larrosa et al.   TETRAHEDRON