期刊
ORGANIC LETTERS
卷 18, 期 15, 页码 3766-3769出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b01783
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资金
- National Science Foundation [1362030]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1654396] Funding Source: National Science Foundation
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1362030] Funding Source: National Science Foundation
Promising levels of enantiocontrol are observed in the silanediol-catalyzed addition of silyl ketene acetals to benzopyrylium triflates. This rare example of enantioselective, intermolecular chromenone functionalization with carbonyl containing nucleophiles has potential applications in the synthesis of bioactive chromanones and tetrahydroxanthones.
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