Selective Carbon-Carbon Bond Cleavage for the Stereoselective Synthesis of Acyclic Systems

Highly Enantioselective Rhodium(I)-Catalyzed Activation of Enantiotopic Cyclobutanone CC Bonds

(2014) Laetitia Souillart et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A New Golden Age for Donor-Acceptor Cyclopropanes

(2014) Tobias F. Schneider et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic Study on Rh-Catalyzed Stereoselective CC/CH Activation oftert-Cyclobutanols

(2014) Haizhu Yu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Evolution of Catalytic Stereoselective Olefin Metathesis: From Ancillary Transformation to Purveyor of Stereochemical Identity

(2014) Amir H. Hoveyda   JOURNAL OF ORGANIC CHEMISTRY

All-Carbon Quaternary Stereogenic Centers in Acyclic Systems through the Creation of Several C–C Bonds per Chemical Step

(2014) Ilan Marek et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cleavage of C–C and C–Si σ-Bonds and Their Intramolecular Exchange

(2014) Naoki Ishida et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Insertion of a Carbenoid Carbon into a C–C Bond To Expand Cyclobutanols to Cyclopentanols

(2014) Akira Yada et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Rhodium(I)-Catalyzed C–C Activations with Zwitterionic Bis-phospholane Ligands

(2014) Evelyne Parker et al.   ORGANOMETALLICS

Stereospecific ring expansion from orthocyclophanes with central chirality to metacyclophanes with planar chirality

(2014) Naoki Ishida et al.   Nature Communications

Reactivity Change of Cyclobutanols towards Isocyanates: Rhodium FavorsC-Carbamoylation overO-Carbamoylation

(2013) Naoki Ishida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CC Fragmentation: Origins and Recent Applications

(2013) Michael A. Drahl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diastereodivergent Carbometalation/Oxidation/Selective Ring Opening: Formation of All-Carbon Quaternary Stereogenic Centers in Acyclic Systems

(2013) Pierre-Olivier Delaye et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-catalyzed cross-coupling of cyclopropanol-derived ketone homoenolates with aryl bromides

(2013) David Rosa et al.   CHEMICAL COMMUNICATIONS

The Construction of All-Carbon Quaternary Stereocenters by Use of Pd-Catalyzed Asymmetric Allylic Alkylation Reactions in Total Synthesis

(2013) Allen Y. Hong et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Oxidative Addition of a Strained C–C Bond onto Electron-Rich Rhodium(I) at Room Temperature

(2013) Yusuke Masuda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

1,5-Rhodium Shift in Rearrangement of N-Arenesulfonylazetidin-3-ols into Benzosultams

(2013) Naoki Ishida et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pt-Catalyzed C–C Activation Induced by C–H Activation

(2013) Miriam A. Bowring et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cleavage of Ether, Ester, and Tosylate C(sp3)–O Bonds by an Iridium Complex, Initiated by Oxidative Addition of C–H Bonds. Experimental and Computational Studies

(2013) Sabuj Kundu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

sp3–sp2 vs sp3–sp3 C–C Site Selectivity in Rh-Catalyzed Ring Opening of Benzocyclobutenol: A DFT Study

(2013) Lina Ding et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Merging allylic carbon–hydrogen and selective carbon–carbon bond activation

(2013) Ahmad Masarwa et al.   NATURE

Multiple Rhodium-Catalyzed Cleavages of Single C–C bonds

(2013) Christophe Aïssa et al.   ORGANIC LETTERS

Nickel-Catalyzed Ring-Opening Alkylative Coupling of Enone with Methylenecyclopropane in the Presence of Triethylborane

(2013) Kenichi Ogata et al.   ORGANIC LETTERS

Arylation of Aldehyde Homoenolates with Aryl Bromides

(2013) Kevin Cheng et al.   ORGANIC LETTERS

C-Acylation of Cyclopropanols: Preparation of Functionalized 1,4-Diketones

(2013) Bibhuti Bhusan Parida et al.   ORGANIC LETTERS

Asymmetric Synthesis of Indole Homo-Michael Adducts via Dynamic Kinetic Friedel–Crafts Alkylation with Cyclopropanes

(2013) Steven M. Wales et al.   ORGANIC LETTERS

The Renaissance of Zinc Carbenoid in Stereoselective Synthesis in Acyclic Systems

(2013) Morgane Pasco et al.   ORGANOMETALLICS

Exploitation of Rh(i)–Rh(iii) cycles in enantioselective C–C bond cleavages: access to β-tetralones and benzobicyclo[2.2.2]octanones

(2013) Laetitia Souillart et al.   Chemical Science

Efficient Approaches to the Stereoselective Synthesis of Cyclopropyl Alcohols

(2012) Hun Young Kim et al.   ACCOUNTS OF CHEMICAL RESEARCH

SN2′ Alkylation of Cyclopropanols via Homoenolates

(2012) Pragna Pratic Das et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of the Si–B Interelement Bond: Mechanism, Catalysis, and Synthesis

(2012) Martin Oestreich et al.   CHEMICAL REVIEWS

Transition-Metal-Mediated Cleavage and Activation of C-C Single Bonds

(2012) Klaus Ruhland   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Csp3–Csp3 and Csp3–H Bond Activation of 1,1-Disubstituted Cyclopentane

(2012) Chisato Mukai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enhanced Catalyst Activity and Enantioselectivity with Chirality-Switchable Polymer Ligand PQXphos in Pd-Catalyzed Asymmetric Silaborative Cleavage of meso-Methylenecyclopropanes

(2012) Yuto Akai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Side-Arm-Promoted Highly Enantioselective Ring-Opening Reactions and Kinetic Resolution of Donor–Acceptor Cyclopropanes with Amines

(2012) You-Yun Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tandem Decarboxylative Allylation and Fragmentation of Allyl Benzocyclobutenyl Carbonates: Access to ortho-Functionalized Aryls from Aryl Bromides

(2012) Arturo Orellana et al.   SYNTHESIS-STUTTGART

Recent Applications of Cyclopropane-Based Strategies to Natural Product Synthesis

(2012) Yong Qin et al.   SYNTHESIS-STUTTGART

Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

(2011) Keary M. Engle et al.   ACCOUNTS OF CHEMICAL RESEARCH

Allyl-, Allenyl-, and Propargyl-Transfer Reactions through Cleavage of CC Bonds Catalyzed by an N-Heterocyclic Carbene/Copper Complex: Synthesis of Multisubstituted Pyrroles

(2011) Masahiro Sai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Synthesis of Axially Chiral Biarylphosphonates: Asymmetric Suzuki-Miyaura Coupling Using High-Molecular-Weight, Helically Chiral Polyquinoxaline-Based Phosphines

(2011) Takeshi Yamamoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective 1,2-Diboration of 1,3-Dienes: Versatile Reagents for Stereoselective Allylation

(2011) Laura T. Kliman et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cyclobutanes in Catalysis

(2011) Tobias Seiser et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Facile and chemoselective rhodium-catalysed intramolecular hydroacylation of α,α-disubstituted 4-alkylidenecyclopropanals

(2011) Damien Crépin et al.   CHEMICAL COMMUNICATIONS

Synthesis of α-indanones via intramolecular direct arylation with cyclopropanol-derived homoenolates

(2011) David Rosa et al.   CHEMICAL COMMUNICATIONS

Polarity Inversion of Donor–Acceptor Cyclopropanes: Disubstituted δ-Lactones via Enantioselective Iridium Catalysis

(2011) Joseph Moran et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diasteroselective Preparation of Cyclopropanols Using Methylene Bis(iodozinc)

(2011) Kevin Cheng et al.   ORGANIC LETTERS

Regioselective Carbon–Carbon Bond Cleavage in the Oxidation of Cyclopropenylcarbinols

(2011) Ahmad Basheer et al.   ORGANIC LETTERS

Multikilogram-Scale Synthesis of a Chiral Cyclopropanol and an Investigation of the Safe Use of Lithium Acetylide–Ethylene Diamine Complex

(2011) Ephraim M. Bassan et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Net Oxidative Addition of C(sp3)-F Bonds to Iridium via Initial C-H Bond Activation

(2011) J. Choi et al.   SCIENCE

β-Carbon Elimination from Cyclobutanols: A Clean Access to Alkylrhodium Intermediates Bearing a Quaternary Stereogenic Center

(2011) Nicolai Cramer et al.   SYNLETT

Transition-Metal-Catalyzed Rearrangements of Small Cycloalkanes: Regioselectivity Trends in β-Carbon Elimination Reactions

(2011) Christophe Aïssa   SYNTHESIS-STUTTGART

Synthesis of Methylene- and Alkylidenecyclopropane Derivatives

(2010) Gérard Audran et al.   ADVANCED SYNTHESIS & CATALYSIS

Metal-catalyzed asymmetric conjugate addition reaction: formation of quaternary stereocenters

(2010) Christine Hawner et al.   CHEMICAL COMMUNICATIONS

Metal-catalysed cleavage of carbon–carbon bonds

(2010) Masahiro Murakami et al.   CHEMICAL COMMUNICATIONS

Ruthenium-Based Olefin Metathesis Catalysts Derived from Alkynes

(2010) Ana M. Lozano-Vila et al.   CHEMICAL REVIEWS

Recent Contributions from the Baylis−Hillman Reaction to Organic Chemistry

(2010) Deevi Basavaiah et al.   CHEMICAL REVIEWS

Rhodium(I)-Catalyzed Enantioselective Activation of Cyclobutanols: Formation of Cyclohexane Derivatives with Quaternary Stereogenic Centers

(2010) Tobias Seiser et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stereospecific Construction of Chiral Tertiary and Quaternary Carbon by Nucleophilic Cyclopropanation with Bis(iodozincio)methane

(2010) Kenichi Nomura et al.   Chemistry-An Asian Journal

Palladium-Catalyzed Allylation of Aryl Halides with Homoallyl Alcohols Bearing a Trisubstituted Double Bond: Application to Chirality Transfer from Hydroxylated Carbon to Benzylic One

(2010) Ryota Wakabayashi et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed C−C Bond Cleavage: Construction of Acyclic Methyl Substituted Quaternary Stereogenic Centers

(2010) Tobias Seiser et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

High-Molecular-Weight Polyquinoxaline-Based Helically Chiral Phosphine (PQXphos) as Chirality-Switchable, Reusable, and Highly Enantioselective Monodentate Ligand in Catalytic Asymmetric Hydrosilylation of Styrenes

(2010) Takeshi Yamamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydroformylation Reaction of Alkylidenecyclopropane Derivatives: A New Pathway for the Formation of Acyclic Aldehydes Containing Quaternary Stereogenic Carbons

(2010) Samah Simaan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Benzodiquinanes via Tandem Palladium-Catalyzed Semipinacol Rearrangement and Direct Arylation

(2010) Angelika Schweinitz et al.   ORGANIC LETTERS

Palladium-Catalyzed Cross-Coupling of Cyclopropanols with Aryl Halides Under Mild Conditions

(2010) David Rosa et al.   ORGANIC LETTERS

Synthesis of α-methyl ketones by a selective, iridium-catalyzed cyclopropanol ring-opening reaction

(2010) Daniel T. Ziegler et al.   TETRAHEDRON LETTERS

Stereoselective Synthesis of Metalated Cyclobutyl Derivatives

(2009) Einav Tsoglin et al.   ADVANCED SYNTHESIS & CATALYSIS

Combined Rhodium-Catalyzed Carbon-Hydrogen Activation and β-Carbon Elimination to access Eight-Membered Rings

(2009) Damien Crépin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Indanols from tert-Cyclobutanols Using a Rhodium-Catalyzed CC/CH Activation Sequence

(2009) Tobias Seiser et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox Economy in Organic Synthesis

(2009) Noah Z. Burns et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Mediated Retro-Allylation of Homoallyl Alcohols for Highly Selective Organic Synthesis

(2009) Hideki Yorimitsu et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Ruthenium-Based Heterocyclic Carbene-Coordinated Olefin Metathesis Catalysts†

(2009) Georgios C. Vougioukalakis et al.   CHEMICAL REVIEWS

Heterocycles from cyclopropanes: applications in natural product synthesis

(2009) Cheryl A. Carson et al.   CHEMICAL SOCIETY REVIEWS

Stereoselective Restructuring of 3-Arylcyclobutanols into 1-Indanols by Sequential Breaking and Formation of Carbon–Carbon Bonds

(2009) Masanori Shigeno et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cyclopropenylcarbinol Derivatives as New Versatile Intermediates in Organic Synthesis: Application to the Formation of Enantiomerically Pure Alkylidenecyclopropane Derivatives

(2009) Samah Simaan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Metal-Catalyzed Ring-Opening of Alkylidenecyclopropanes: New Access to Building Blocks with an Acyclic Quaternary Stereogenic Center

(2009) Samah Simaan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Nucleophilic Cyclopropanation Reaction with Bis(iodozincio)methane by 1,4-Addition to α,β-Unsaturated Carbonyl Compounds

(2009) Kenichi Nomura et al.   Chemistry-An Asian Journal

trans-Directing Ability of the Amide Group: Enabling the Enantiocontrol in the Synthesis of 1,1-Dicarboxy Cyclopropanes. Reaction Development, Scope, and Synthetic Applications

(2009) David Marcoux et al.   JOURNAL OF ORGANIC CHEMISTRY

H-Bonding as a Control Element in Stereoselective Ru-Catalyzed Olefin Metathesis

(2009) Amir H. Hoveyda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Ring-Opening Hydroacylation of Methylenecyclopropanes: Synthesis of γ,δ-Unsaturated Ketones from Aldehydes

(2009) Hiroki Taniguchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis at the molecular frontier

(2009) Paul A. Wender et al.   NATURE

Kinetic Resolution of Racemic 1-Alkyl-2-methylenecyclopropanes via Palladium-Catalyzed Silaborative C−C Cleavage

(2009) Toshimichi Ohmura et al.   ORGANIC LETTERS

Organocatalytic Formation of Quaternary Stereocenters

(2009) Marco Bella et al.   SYNTHESIS-STUTTGART

Metal−Organic Cooperative Catalysis in C−H and C−C Bond Activation and Its Concurrent Recovery

(2008) Young Jun Park et al.   ACCOUNTS OF CHEMICAL RESEARCH

Enantioselective CC Bond Activation of Allenyl Cyclobutanes: Access to Cyclohexenones with Quaternary Stereogenic Centers

(2008) Tobias Seiser et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Helical Poly(quinoxaline-2,3-diyl)s Bearing Metal-Binding Sites as Polymer-Based Chiral Ligands for Asymmetric Catalysis

(2008) Takeshi Yamamoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed hydride transfer from LiAlH4 for the formation of alkylidenecyclopropane derivatives

(2008) Samah Simaan et al.   CHEMICAL COMMUNICATIONS