期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 48, 页码 19580-19583出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja309830p
关键词
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资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan
- Grants-in-Aid for Scientific Research [24790009] Funding Source: KAKEN
The unprecedented C-sp(3)-C-sp(3) bond cleavage of unactivated cyclopentane has been achieved. Rh-1-catalyzed cycloaddition of allenylcyclopentane-alkynes produced in situ the 9-cyclopentyl-8-rhodabicyclo[4.3.0]-nona-1,6-diene intermediates, which subsequently underwent [7+2] cycloaddition via beta-C elimination, affording bicyclo[7.4.0]tridecatriene derivatives in good yields. Changing the Rh-1 catalyst effected the C gamma-H bond activation of the common 9-cyclopenty1-8-rhodabicyclo[4.3.0]nona-1,6-diene intermediate to produce the novel spiro[2.4]heptane skeleton in a site-selective manner.
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