NHC-Catalyzed Hydroacylation of Styrenes

3- and 4-Uloses Derived from N-Acetyl-D-glucosamine: A Unique Pair of Complementary Organocatalysts for Asymmetric Epoxidation of Alkenes

(2012) Christof Schöberl et al.   ADVANCED SYNTHESIS & CATALYSIS

Synthesis of Five- and Six-Membered Benzocyclic Ketones through Intramolecular Alkene Hydroacylation Catalyzed by Nickel(0)/N-Heterocyclic Carbenes

(2012) Yoichi Hoshimoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structures and Reactivities of O-Methylated Breslow Intermediates

(2012) Biplab Maji et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nucleophilic Reactivities of Deoxy Breslow Intermediates: How Does Aromaticity Affect the Catalytic Activities of N-Heterocyclic Carbenes?

(2012) Biplab Maji et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Umpolung by N-Heterocyclic Carbenes: Generation and Reactivity of the Elusive 2,2-Diamino Enols (Breslow Intermediates)

(2012) Albrecht Berkessel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Intermolecular Stetter Reactions of Enolizable Aldehydes with Nitrostyrenes: Computational Study Provides Insight into the Success of the Catalyst

(2012) Daniel A. DiRocco et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Continuum of Progress: Applications of N-Hetereocyclic Carbene Catalysis in Total Synthesis

(2012) Javier Izquierdo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-catalysed linear-selective alkyne hydroacylation

(2012) Sarah-Jane Poingdestre et al.   CHEMICAL COMMUNICATIONS

Enantiomerically enriched trans-diols from alkenes in one pot: a multicatalyst approach

(2012) Radim Hrdina et al.   CHEMICAL COMMUNICATIONS

Desymmetrization of cyclohexadienones viad-camphor-derived triazolium salt catalyzed intramolecular Stetter reaction

(2012) Min-Qiang Jia et al.   CHEMICAL COMMUNICATIONS

Organocatalytic umpolung: N-heterocyclic carbenes and beyond

(2012) Xavier Bugaut et al.   CHEMICAL SOCIETY REVIEWS

Highly Enantioselective Intermolecular Stetter Reaction of Simple Acrylates: Synthesis of α-Chiral γ-Ketoesters

(2012) Nathalie E. Wurz et al.   CHEMISTRY-A EUROPEAN JOURNAL

2,6-Dimethoxyphenyl-Substituted N-Heterocyclic Carbenes (NHCs): A Family of Highly Electron-Rich Organocatalysts

(2012) Michael Schedler et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Diastereoselective and Enantioselective Desymmetrization of α-Substituted Cyclohexadienones via Intramolecular Stetter Reaction

(2012) Min-Qiang Jia et al.   JOURNAL OF ORGANIC CHEMISTRY

Intermolecular Hydroacylation: High Activity Rhodium Catalysts Containing Small-Bite-Angle Diphosphine Ligands

(2012) Adrian B. Chaplin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isolable Analogues of the Breslow Intermediate Derived from Chiral Triazolylidene Carbenes

(2012) Daniel A. DiRocco et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aryl Methyl Sulfides as Substrates for Rhodium-Catalyzed Alkyne Carbothiolation: Arene Functionalization with Activating Group Recycling

(2012) Joel F. Hooper et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Phosphoramidite Catalyzed Alkene Hydroacylation: Mechanism and Octaketide Natural Product Synthesis

(2012) Max von Delius et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Synthesis of γ-Keto Sulfones by NHC-Catalyzed Intermolecular Stetter Reaction

(2012) Anup Bhunia et al.   ORGANIC LETTERS

Metal-Free, Organocatalytic Syn Diacetoxylation of Alkenes

(2012) Wenhe Zhong et al.   ORGANIC LETTERS

Catalytic intermolecular hydroacylation of C–C π-bonds in the absence of chelation assistance

(2012) Joyce C. Leung et al.   Chemical Science

Extending NHC-Catalysis: Coupling Aldehydes with Unconventional Reaction Partners

(2011) Akkattu T. Biju et al.   ACCOUNTS OF CHEMICAL RESEARCH

Designing N-Heterocyclic Carbenes: Simultaneous Enhancement of Reactivity and Enantioselectivity in the Asymmetric Hydroacylation of Cyclopropenes

(2011) Fan Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Alkyne Hydroacylation Route to Highly Substituted Furans

(2011) Philip Lenden et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbenes: Organocatalysts with Moderate Nucleophilicity but Extraordinarily High Lewis Basicity

(2011) Biplab Maji et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene Catalyzed Domino Reactions

(2011) André Grossmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Asymmetric NHC-Catalyzed Hydroacylation of Unactivated Alkenes

(2011) Isabel Piel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Inter- and intramolecular hydroacylation of alkenes employing a bifunctional catalyst system

(2011) Nicolas R. Vautravers et al.   CHEMICAL COMMUNICATIONS

Employing homoenolates generated by NHC catalysis in carbon–carbon bond-forming reactions: state of the art

(2011) Vijay Nair et al.   CHEMICAL SOCIETY REVIEWS

Dual Activation in N-Heterocyclic Carbene-organocatalysis

(2011) Keiichi Hirano et al.   CHEMISTRY LETTERS

Direct Arylation of Alkenes with Aryl Iodides/Bromides through an Organocatalytic Radical Process

(2011) Chang-Liang Sun et al.   CHEMISTRY-A EUROPEAN JOURNAL

N-Heterocyclic Carbene (NHC)-Catalyzed Intermolecular Hydroacylation of Cyclopropenes

(2011) Xavier Bugaut et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Hydroacylation as an Approach to Homoaldol Products

(2011) Stephen K. Murphy et al.   ORGANIC LETTERS

Efficient Synthesis of Benzofuranones: N-Heterocyclic Carbene (NHC)/Base-Catalyzed Hydroacylation–Stetter–Rearrangement Cascade

(2011) Mohan Padmanaban et al.   ORGANIC LETTERS

Synthesis and reaction of phthaloyl peroxide derivatives, potential organocatalysts for the stereospecific dihydroxylation of alkenes

(2011) Changxia Yuan et al.   TETRAHEDRON LETTERS

β-hydroxy ketones prepared by regioselective hydroacylation

(2011) Stephen K. Murphy et al.   Chemical Science

Cooperative Lewis acid/N-heterocyclic carbene catalysis

(2011) Daniel T. Cohen et al.   Chemical Science

The effect of the N-mesityl group in NHC-catalyzed reactions

(2011) Jessada Mahatthananchai et al.   Chemical Science

Aldehyde Umpolung by N-Heterocyclic Carbenes: NMR Characterization of the Breslow Intermediate in its Keto Form, and a Spiro-Dioxolane as the Resting State of the Catalytic System

(2010) Albrecht Berkessel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intermolecular N-Heterocyclic Carbene Catalyzed Hydroacylation of Arynes

(2010) Akkattu T. Biju et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The cascade carbo-carbonylation of unactivated alkenes catalyzed by an organocatalyst and a transition metal catalyst: a facile approach to γ-diketones and γ-carbonyl aldehydes from arylalkenes under air

(2010) Jin Xie et al.   CHEMICAL COMMUNICATIONS

N-Heterocyclic Carbene-Catalyzed Cascade Reaction Involving the Hydroacylation of Unactivated Alkynes

(2010) Akkattu T. Biju et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

On new N-heterocyclic carbene derived alkylidene imidazolines

(2010) Christiane E. I. Knappke et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Transition Metal Catalyzed Alkene and Alkyne Hydroacylation

(2009) Michael C. Willis   CHEMICAL REVIEWS

Rhodium-Catalyzed Highly Enantioselective Direct Intermolecular Hydroacylation of 1,1-Disubstituted Alkenes with Unfunctionalized Aldehydes

(2009) Yu Shibata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic Carbene-Catalyzed Hydroacylation of Unactivated Double Bonds

(2009) Keiichi Hirano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydroacylation of 2-butyne from the alcohol or aldehyde oxidation level via ruthenium catalyzed C–C bond forming transfer hydrogenation

(2009) Vanessa M. Williams et al.   TETRAHEDRON

Diene Hydroacylation from the Alcohol or Aldehyde Oxidation Level via Ruthenium-Catalyzed C−C Bond-Forming Transfer Hydrogenation: Synthesis of β,γ-Unsaturated Ketones

(2008) Fumitoshi Shibahara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium Hydride-Catalyzed Addition of Aldehydes to Dienes Leading to β,γ-Unsaturated Ketones

(2008) Sohei Omura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Organo-Singly Occupied Molecular Orbital Catalysis: The Carbo-oxidation of Styrenes

(2008) Thomas H. Graham et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic carbene catalyzed intramolecular nucleophilic addition of carbonyl anion equivalents to enol ethers

(2008) Jinmei He et al.   TETRAHEDRON

Development of Chiral Bicyclic Triazolium Salt Organic Catalysts: The Importance of theN-Aryl Substituent

(2007) Tomislav Rovis   CHEMISTRY LETTERS