Transfer of Chirality in the Rhodium-Catalyzed Intramolecular [5+2] Cycloaddition of 3-Acyloxy-1,4-enynes (ACEs) and Alkynes: Synthesis of Enantioenriched Bicyclo[5.3.0]decatrienes

Mechanism and Origins of Selectivity in Ru(II)-Catalyzed Intramolecular (5+2) Cycloadditions and Ene Reactions of Vinylcyclopropanes and Alkynes from Density Functional Theory

(2013) Xin Hong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh-Catalyzed (5+2) Cycloadditions of 3-Acyloxy-1,4-enynes and Alkynes: Computational Study of Mechanism, Reactivity, and Regioselectivity

(2013) Xiufang Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

[5 + 2] Cycloaddition Reactions in Organic and Natural Product Synthesis

(2012) Kai E. O. Ylijoki et al.   CHEMICAL REVIEWS

Rhodium-catalyzed acyloxy migration of propargylic esters in cycloadditions, inspiration from the recent “gold rush”

(2012) Xing-Zhong Shu et al.   CHEMICAL SOCIETY REVIEWS

Ligand Effects on Rates and Regioselectivities of Rh(I)-Catalyzed (5 + 2) Cycloadditions: A Computational Study of Cyclooctadiene and Dinaphthocyclooctatetraene as Ligands

(2012) Xiufang Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Intra- and Intermolecular [5 + 2] Cycloaddition of 3-Acyloxy-1,4-enyne and Alkyne with Concomitant 1,2-Acyloxy Migration

(2012) Xing-Zhong Shu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism and Origins of Ligand-Controlled Selectivities in [Ni(NHC)]-Catalyzed Intramolecular (5 + 2) Cycloadditions and Homo-Ene Reactions: A Theoretical Study

(2012) Xin Hong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent Developments in the [5+2] Cycloaddition

(2011) Hélène Pellissier   ADVANCED SYNTHESIS & CATALYSIS

Enantioselective Gold(I)-Catalyzed Intramolecular (4+3) Cycloadditions of Allenedienes

(2011) Isaac Alonso et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Interception of a Rautenstrauch Intermediate by Alkynes for [5+2] Cycloaddition: Rhodium-Catalyzed Cycloisomerization of 3-Acyloxy-4-ene-1,9-diynes to Bicyclo[5.3.0]decatrienes

(2011) Xing-zhong Shu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

(4+3) Cycloaddition Reactions of Nitrogen-Stabilized Oxyallyl Cations

(2011) Andrew G. Lohse et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Atom-Economic Synthesis of Bicyclo[3.1.0]hexanes by Rhodium N-Heterocyclic Carbene-Catalyzed Diastereoselective Tandem Hetero-[5 + 2] Cycloaddition/Claisen Rearrangement Reaction of Vinylic Oxiranes with Alkynes

(2011) Jian-Jun Feng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dual Catalysis in Enantioselective Oxidopyrylium-Based [5 + 2] Cycloadditions

(2011) Noah Z. Burns et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(I)-Catalyzed Intramolecular [5+2] Cycloaddition Reactions of Alkynes and Allenylcyclopropanes: Construction of Bicyclo[5.4.0]undecatrienes and Bicyclo[5.5.0]dodecatrienes

(2010) Fuyuhiko Inagaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The (4+3)-cycloaddition reaction: heteroatom-substituted allylic cations as dienophiles

(2010) Michael Harmata   CHEMICAL COMMUNICATIONS

The (4+3)-cycloaddition reaction: simple allylic cations as dienophiles

(2010) Michael Harmata   CHEMICAL COMMUNICATIONS

A Metal-Catalyzed Intermolecular [5+2] Cycloaddition/Nazarov Cyclization Sequence and Cascade

(2010) Paul A. Wender et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electronic and Steric Control of Regioselectivities in Rh(I)-Catalyzed (5 + 2) Cycloadditions: Experiment and Theory

(2010) Peng Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reaction of α-Ene-Vinylcyclopropanes: Type II Intramolecular [5+2] Cycloaddition or [3+2] Cycloaddition?

(2010) Qian Li et al.   ORGANIC LETTERS

Rhodium-Catalyzed Asymmetric [5+2] Cycloaddition of Alkyne-Vinylcyclopropanes

(2009) Ryo Shintani et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric [4 + 3] Cycloadditions between Vinylcarbenoids and Dienes: Application to the Total Synthesis of the Natural Product (−)-5-epi-Vibsanin E

(2009) Brett D. Schwartz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

1,5-α-d-Mannoseptanosides, Ring-Size Isomers That Are Impervious to α-Mannosidase-Catalyzed Hydrolysis

(2009) Matthew A. Boone et al.   ORGANIC LETTERS

Synthetic approaches to bicyclo[5.3.0]decane sesquiterpenes

(2009) David A. Foley et al.   TETRAHEDRON

Substituent Effects, Reactant Preorganization, and Ligand Exchange Control the Reactivity in RhI-Catalyzed (5+2) Cycloadditions between Vinylcyclopropanes and Alkynes

(2008) Peng Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Seven‐Membered Rings by Cyclization at Transition Metals: [4+3], [3+2+2], [5+2]

(2008) Holger Butenschön   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rh(I)-Catalyzed Intramolecular [3 + 2] Cycloaddition oftrans-Vinylcyclopropane-enes

(2008) Lei Jiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Origins of Differences in Reactivities of Alkenes, Alkynes, and Allenes in [Rh(CO)2Cl]2-Catalyzed (5 + 2) Cycloaddition Reactions with Vinylcyclopropanes

(2008) Zhi-Xiang Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Cheap Metal for a “Noble” Task:  Preparative and Mechanistic Aspects of Cycloisomerization and Cycloaddition Reactions Catalyzed by Low-Valent Iron Complexes

(2008) Alois Fürstner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A fresh look at natural tropolonoids

(2007) Ronald Bentley   NATURAL PRODUCT REPORTS