Beyond Samarium Diiodide: Vistas in Reductive Chemistry Mediated by Lanthanides(II)

Preparation of Samarium(II) Iodide: Quantitative Evaluation of the Effect of Water, Oxygen, and Peroxide Content, Preparative Methods, and the Activation of Samarium Metal

(2012) Michal Szostak et al.   JOURNAL OF ORGANIC CHEMISTRY

Selective synthesis of 3-hydroxy acids from Meldrum's acids using SmI2-H2O

(2012) Michal Szostak et al.   Nature Protocols

A general electron transfer reduction of lactones using SmI2–H2O

(2012) Michal Szostak et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

SmI2-Mediated Cross-Coupling of Nitrones with β-Silyl Acrylates: Synthesis of (+)-Australine

(2012) Pierre Gilles et al.   ORGANIC LETTERS

Electron Transfer Reduction of Carboxylic Acids Using SmI2–H2O–Et3N

(2012) Michal Szostak et al.   ORGANIC LETTERS

Concise Syntheses of Strychnine and Englerin A: the Power of Reductive Cyclizations Triggered by Samarium Iodide

(2011) Michal Szostak et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electron transfer reduction of unactivated esters using SmI2–H2O

(2011) Michal Szostak et al.   CHEMICAL COMMUNICATIONS

Selective reductive transformations using samarium diiodide-water

(2011) Michal Szostak et al.   CHEMICAL COMMUNICATIONS

Samarium diiodide induced ketyl-(het)arene cyclisations towards novel N-heterocycles

(2011) Christine Beemelmanns et al.   CHEMICAL SOCIETY REVIEWS

Theoretical Treatment of Redox Processes Involving Lanthanide(II) Compounds: Reactivity of Organosamarium(II) and Organothulium(II) Complexes with CO2and Pyridine

(2011) Stéphanie Labouille et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Reductive Cyclization Cascades of Lactones Using SmI2−H2O

(2011) Dixit Parmar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Concise Total Synthesis of (−)-Maoecrystal Z

(2011) Jacob Y. Cha et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of a Crystalline Molecular Complex of Y2+, [(18-crown-6)K][(C5H4SiMe3)3Y]

(2011) Matthew R. MacDonald et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of the (N2)3−Radical from Y2+and Its Protonolysis Reactivity To Form (N2H2)2−via the Y[N(SiMe3)2]3/KC8Reduction System

(2011) Ming Fang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A convenient pathway to Sm(ii)-mediated chemistry in acetonitrile

(2011) Todd Maisano et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Exploiting Sm(ii) and Sm(iii) in SmI2-initiated reaction cascades: application in a tag removal–cyclisation approach to spirooxindole scaffolds

(2011) Susannah C. Coote et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Radical Cyclization Cascades of Unsaturated Meldrum’s Acid Derivatives

(2011) Brice Sautier et al.   ORGANIC LETTERS

Heteroleptic Samarium(II) Complexes by Base-Induced Reduction

(2010) Gerd Meyer   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lewis Base Induced Reductions in Organolanthanide Chemistry

(2010) Daniel Bojer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective α-defluorination of polyfluorinated esters and amides using SmI2/Et3N/H2O

(2010) Jenny Wettergren et al.   CHEMICAL COMMUNICATIONS

Selective Reductions of Cyclic 1,3-Diesters by Using SmI2and H2O

(2010) Karl D. Collins et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Joint Experimental/Theoretical Investigation of the Statistical Olefin/Conjugated Diene Copolymerization Catalyzed by a Hemi-Lanthanidocene [(Cp*)(BH4)LnR]

(2010) Lionel Perrin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Non-classical divalent lanthanide complexes

(2010) François Nief   DALTON TRANSACTIONS

Conversion of Conjugated Enones into Enantiomerically Pure -Hydroxy Ketones or 1,3-Diols - Samarium(II) Bromide Reductions of Protected ,-Dihydroxy Ketones

(2010) Andreas Zörb et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

One- and Two-Electron-Transfer Reactions of (dpp-Bian)Sm(dme)3

(2010) Igor L. Fedushkin et al.   INORGANIC CHEMISTRY

Uncovering the Mechanistic Role of HMPA in the Samarium Barbier Reaction

(2010) Kimberly A. Choquette et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Novel polymerization catalysts and hydride clusters from rare-earth metal dialkyls

(2010) Masayoshi Nishiura et al.   Nature Chemistry

KHMDS Enhanced SmI2-Mediated Reformatsky Type α-Cyanation

(2010) Tobias Ankner et al.   ORGANIC LETTERS

Dynamic Ligand Exchange in Reactions of Samarium Diiodide

(2010) Dhandapani V. Sadasivam et al.   ORGANIC LETTERS

Reduction of nitrogen with neodymium(II) and dysprosium(II) diiodides and selected properties of the resulting nitrides

(2010) A. A. Fagin et al.   RUSSIAN CHEMICAL BULLETIN

A Convenient Synthesis of (E)-α,β-Unsaturated Esters with Total Stereoselectivity Promoted by Catalytic Samarium Diiodide

(2010) José Concellón et al.   SYNLETT

Sm(II)-Mediated Reduction in Water: Importance of the Additive in the Proportionation of SmCl3and Sm

(2010) S. Matsukawa et al.   SYNTHETIC COMMUNICATIONS

A cationic cyclisation route to prenylated indole alkaloids: synthesis of malbrancheamide B and brevianamide B, and progress towards stephacidin A

(2010) Frédéric C. Frebault et al.   TETRAHEDRON

Reductive carboxylation of alkyl halides with CO2 by use of photoinduced SmI2/Sm reduction system

(2010) Akihiro Nomoto et al.   TETRAHEDRON LETTERS

A Dialdehyde Cyclization Cascade: An Approach to Pleuromutilin

(2009) Matthew D. Helm et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Samarium Diiodide Mediated Reactions in Total Synthesis

(2009) K. C. Nicolaou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Broadening the Scope of Photostimulated SmI2Reductions

(2009) Mazal Amiel-Levy et al.   CHEMISTRY-A EUROPEAN JOURNAL

Advances in f element reductive reactivity as a paradigm for expanding lanthanide and actinide science and technology

(2009) William J. Evans   JOURNAL OF ALLOYS AND COMPOUNDS

Toolbox Approach to the Search for Effective Ligands for Catalytic Asymmetric Cr-Mediated Coupling Reactions

(2009) Haibing Guo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dramatic Improvement in Catalyst Loadings and Molar Ratios of Coupling Partners for Ni/Cr-Mediated Coupling Reactions: Heterobimetallic Catalysts

(2009) Xiang Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Concise Enantioselective Synthesis of ent-Malbrancheamide B

(2009) Frederic Frebault et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Studies on the Mechanism, Selectivity, and Synthetic Utility of Lactone Reduction Using SmI2and H2O

(2009) Dixit Parmar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective Reductions of Cyclic 1,3-Diesters Using SmI2and H2O

(2009) Giuditta Guazzelli et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Guidelines for the Use of Proton Donors in SmI2Reactions: Reduction of α-Cyanostilbene

(2009) Mazal Amiel-Levy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Instantaneous Deprotection of Tosylamides and Esters with SmI2/Amine/Water

(2009) Tobias Ankner et al.   ORGANIC LETTERS

Samarium Iodides: Catalysts for the Formation of Carbon-Nitrogen Bonds

(2009) Jacqueline Collin et al.   SYNLETT

SmI2-mediated dialdehyde ‘radical then aldol’ cyclization cascades: a feasibility study

(2009) Matthew D. Helm et al.   TETRAHEDRON

SmI2/H2O/amine promoted reductive cleavage of benzyl-heteroatom bonds: optimization and mechanism

(2009) Tobias Ankner et al.   TETRAHEDRON

SmI2-mediated dialdehyde cyclization cascades

(2009) Matthew D. Helm et al.   TETRAHEDRON LETTERS

Superbulky Ligands and Trapped Electrons: New Perspectives in Divalent Lanthanide Chemistry

(2008) Gerd Meyer   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Remarkable Stability of Metallocenes with Superbulky Ligands: Spontaneous Reduction of SmIII to SmII

(2008) Christian Ruspic et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lanthanum Does Form Stable Molecular Compounds in the +2 Oxidation State

(2008) Peter B. Hitchcock et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dinitrogen Reduction and CH Activation by the Divalent Organoneodymium Complex [(C5H2tBu3)2Nd(μ-I)K([18]crown-6)]

(2008) Florian Jaroschik et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Anhydrous scandium, yttrium, lanthanide and actinide halide complexes with neutral oxygen and nitrogen donor ligands

(2008) Shashank Mishra   COORDINATION CHEMISTRY REVIEWS

Generation of SmIIReductants Using High Intensity Ultrasound

(2008) Joseph A. Teprovich et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

A New Entry to 1,5-Keto Esters and Their 4,4-Dideuterio Derivatives via Methylene Chloride as “Methylene Dianion” Equivalents

(2008) Kuo-Wei Lin et al.   JOURNAL OF ORGANIC CHEMISTRY

A Ring Size-Selective Reduction of Lactones Using SmI2and H2O

(2008) Lorna A. Duffy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Study of Samarium Diiodide-HMPA Initiated 5-exo-trigKetyl−Olefin Coupling: The Role of HMPA in Post-Electron Transfer Steps

(2008) Dhandapani V. Sadasivam et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Evolution of a Synthetic Strategy:  Total Synthesis of (±)-Welwitindolinone A Isonitrile

(2008) Sarah E. Reisman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Samarium(II)−Mediated Linker Cleavage−Cyclization in Fluorous Synthesis:  Reactions of Samarium Enolates

(2008) Karen M. James et al.   ORGANIC LETTERS

New, General, and Practical Preparation of Methyl Ketones via the Direct Coupling of Amides with CH2Cl2Promoted by TiCl4/Mg

(2008) Kuo-Wei Lin et al.   ORGANIC LETTERS

Utility of Dysprosium Diiodide and Metallic Dysprosium as Reductants in Cyclopropanation Reactions of Alkenes with Dichloromethane

(2008) Xu Xiang et al.   ORGANOMETALLICS

Mechanistic Studies on the Roles of Cosolvents and Additives in Samarium(II)-Based Reductions

(2008) Robert Flowers et al.   SYNLETT

Reductive deprotection of propargyl ether by a SmI2–amine–water system and its application to polymer-supported oligosaccharide synthesis

(2008) Shino Manabe et al.   TETRAHEDRON LETTERS

On the potentially excellent reducing ability of a series of low-valent rare earths induced by photoirradiation

(2008) Yuri Tomisaka et al.   TETRAHEDRON LETTERS