Construction of Six-Membered Silacyclic Skeletons via Platinum-Catalyzed Tandem Hydrosilylation/Cyclization with Dihydrosilanes

I2/TBHP-Promoted Approach to α-Keto Esters from Trifluoromethyl β-Diketones and Alcohols via C–C Bond Cleavage

(2017) Xiang Fang et al.   SYNLETT

Advances in Base-Metal-Catalyzed Alkene Hydrosilylation

(2017) Xiaoyong Du et al.   ACS Catalysis

Cobalt-Catalyzed Alkyne Hydrosilylation and Sequential Vinylsilane Hydroboration with Markovnikov Selectivity

(2016) Ziqing Zuo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Chemo-, Regio-, and Stereoselective Cobalt-Catalyzed Markovnikov Hydrosilylation of Alkynes

(2016) Jun Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Enantioselective Silylation of Cyclopropyl C−H Bonds

(2016) Taegyo Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Donor/Acceptor-Stabilized 1-Silaketene: Reversible [2+2] Cycloaddition with Pyridine and Evolution by an Olefin Metathesis Reaction

(2016) Morelia Lopez Reyes et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent Progress in Asymmetric Synthesis and Application of Difunctionalized Silicon-Stereogenic Silanes

(2016) Jonathan O. Bauer et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

[4+2] Cycloadditions of Seven-Membered-Ring trans-Alkenes: Decreasing Reactivity with Increasing Substitution of the Seven-Membered Ring

(2016) John Santucci et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Copper-catalysed enantioselective stereodivergent synthesis of amino alcohols

(2016) Shi-Liang Shi et al.   NATURE

Regio- and Stereoselective Hydrosilylation of Unsymmetrical Alkynes Catalyzed by a Well-Defined, Low-Valent Cobalt Catalyst

(2016) Alejandro Rivera-Hernández et al.   ORGANIC LETTERS

Hydrosilylation of Terminal Alkynes Catalyzed by a ONO-Pincer Iridium(III) Hydride Compound: Mechanistic Insights into the Hydrosilylation and Dehydrogenative Silylation Catalysis

(2016) Jesús J. Pérez-Torrente et al.   ORGANOMETALLICS

Cobalt-Catalyzed Regiodivergent Hydrosilylation of Vinylarenes and Aliphatic Alkenes: Ligand- and Silane-Dependent Regioselectivities

(2016) Chao Wang et al.   ACS Catalysis

Iron- and Cobalt-Catalyzed Alkene Hydrogenation: Catalysis with Both Redox-Active and Strong Field Ligands

(2015) Paul J. Chirik   ACCOUNTS OF CHEMICAL RESEARCH

Transfer Hydrosilylation

(2015) Martin Oestreich   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aromatic Amide-Derived Non-Biaryl Atropisomers as Highly Efficient Ligands in Silver-Catalyzed Asymmetric Cycloaddition Reactions

(2015) Xing-Feng Bai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Platinum(0) olefin complexes of a bulky terphenylphosphine ligand. Synthetic, structural and reactivity studies

(2015) Laura Ortega-Moreno et al.   CHEMICAL COMMUNICATIONS

Development of Ar-BINMOL-Derived Atropisomeric Ligands with Matched Axial and sp3Central Chirality for Catalytic Asymmetric Transformations

(2015) Zheng Xu et al.   CHEMICAL RECORD

Synthesis and behavior of novel sulfonated water-soluble N-heterocyclic carbene (η4-diene) platinum(0) complexes

(2015) Andrea M. Ruiz-Varilla et al.   DALTON TRANSACTIONS

Modular Approach to Reductive Csp2–H and Csp3–H Silylation of Carboxylic Acid Derivatives through Single-Pot, Sequential Transition Metal Catalysis

(2015) Yuanda Hua et al.   JOURNAL OF ORGANIC CHEMISTRY

Reversible Substrate Activation and Catalysis at an Intact Metal–Metal Bond Using a Redox-Active Supporting Ligand

(2015) Talia J. Steiman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu-Catalyzed Silylation of Alkynes: A Traceless 2-Pyridylsulfonyl Controller Allows Access to Either Regioisomer on Demand

(2015) Alfonso García-Rubia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Interligand Interactions Dictate the Regioselectivity of trans-Hydrometalations and Related Reactions Catalyzed by [Cp*RuCl]. Hydrogen Bonding to a Chloride Ligand as a Steering Principle in Catalysis

(2015) Stephan M. Rummelt et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Formal SiH4 chemistry using stable and easy-to-handle surrogates

(2015) Antoine Simonneau et al.   Nature Chemistry

Enantioselective Bromo-oxycyclization of Silanol

(2015) Zilei Xia et al.   ORGANIC LETTERS

Cobalt Complex-Catalyzed Hydrosilylation of Alkenes and Alkynes

(2015) Jian Sun et al.   ACS Catalysis

Recent Advances in the Transition-Metal-Catalyzed Enantioselective Synthesis of Silicon-Stereogenic Organosilanes

(2015) Ryo Shintani   Asian Journal of Organic Chemistry

Modular Synthesis of Ar-BINMOL-Phos for Catalytic Asymmetric Alkynylation of Aromatic Aldehydes with Unexpected Reversal of Enantioselectivity

(2014) Tao Song et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium Nanoflowers Stabilized by a Nitrogen-Rich PEG-Tagged Substrate as Recyclable Catalyst for the Stereoselective Hydrosilylation of Internal Alkynes

(2014) Wusheng Guo et al.   ADVANCED SYNTHESIS & CATALYSIS

Hydrosilylation of Internal Alkynes Catalyzed by Tris- Imidazolium Salt-Stabilized Palladium Nanoparticles

(2014) Marc Planellas et al.   ADVANCED SYNTHESIS & CATALYSIS

Enantioselective Copper-Catalyzed Azide-Alkyne Click Cycloaddition to Desymmetrization of Maleimide-Based Bis(alkynes)

(2014) Tao Song et al.   CHEMISTRY-A EUROPEAN JOURNAL

Endo-Selective Pd-Catalyzed Silyl Methyl Heck Reaction

(2014) Marvin Parasram et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regio- and Stereoselective Hydrosilylation of Alkynes Catalyzed by Three-Coordinate Cobalt(I) Alkyl and Silyl Complexes

(2014) Zhenbo Mo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental and Computational Studies of the Ruthenium-Catalyzed Hydrosilylation of Alkynes: Mechanistic Insights into the Regio- and Stereoselective Formation of Vinylsilanes

(2014) Ruili Gao et al.   ORGANOMETALLICS

An Alternative Mechanistic Paradigm for the β-ZHydrosilylation of Terminal Alkynes: The Role of Acetone as a Silane Shuttle

(2013) Manuel Iglesias et al.   CHEMISTRY-A EUROPEAN JOURNAL

Development of a Novel Multifunctional N,P Ligand for Highly Enantioselective Palladium-Catalyzed Asymmetric Allylic Etherification of Alcohols and Silanols

(2013) Fei Ye et al.   CHEMISTRY-A EUROPEAN JOURNAL

Modulation of Multifunctional N,O,P Ligands for Enantioselective Copper-Catalyzed Conjugate Addition of Diethylzinc and Trapping of the Zinc Enolate

(2013) Fei Ye et al.   Chemistry-An Asian Journal

Ligand-Controlled Remarkable Regio- and Stereodivergence in Intermolecular Hydrosilylation of Internal Alkynes: Experimental and Theoretical Studies

(2013) Shengtao Ding et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Platinum catalysed hydrosilylation of propargylic alcohols

(2013) Catherine A. McAdam et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Desymmetrization Catalyzed by Transition-Metal Complexes: Enantioselective Formation of Silicon-Stereogenic Silanes

(2012) Li-Wen Xu   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Synthesis of Alkenylhydrosilanes

(2012) Kazunobu Igawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Platinum-Catalyzed Hydrosilylations of Internal Alkynes: Harnessing Substituent Effects to Achieve High Regioselectivity

(2012) Douglas A. Rooke et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aryl–aryl interactions as directing motifs in the stereodivergent iron-catalyzed hydrosilylation of internal alkynes

(2012) Christian Belger et al.   CHEMICAL COMMUNICATIONS

Rhodium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzooxasilines via Enantioselective Transmetalation

(2012) Ryo Shintani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Construction of Benzosiloles, Six- and Eight-Membered Silacyclic Skeletons, via a Pd-Catalyzed Intramolecular Mizoroki–Heck Reaction of Vinylsilanes

(2012) Kunbing Ouyang et al.   ORGANIC LETTERS

Selective Hydrosilylation of 1,3-Diynes Catalyzed by Titania-Supported Platinum

(2012) Francisco Alonso et al.   ORGANOMETALLICS

Water-Soluble N-Heterocyclic Carbene Platinum(0) Complexes: Recyclable Catalysts for the Hydrosilylation of Alkynes in Water at Room Temperature

(2012) Gustavo F. Silbestri et al.   ORGANOMETALLICS

Iron Catalysts for Selective Anti-Markovnikov Alkene Hydrosilylation Using Tertiary Silanes

(2012) A. M. Tondreau et al.   SCIENCE

Impregnated Platinum on Magnetite as an Efficient, Fast, and Recyclable Catalyst for the Hydrosilylation of Alkynes

(2012) Rafael Cano et al.   ACS Catalysis

Recent advances and actual challenges in late transition metal catalyzed hydrosilylation of olefins from an industrial point of view

(2011) Dennis Troegel et al.   COORDINATION CHEMISTRY REVIEWS

Directing Group-Controlled Hydrosilylation: Regioselective Functionalization of Alkyne

(2011) Yuuya Kawasaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The recent synthesis and application of silicon-stereogenic silanes: A renewed and significant challenge in asymmetric synthesis

(2010) Li-Wen Xu et al.   CHEMICAL SOCIETY REVIEWS

Asymmetric Si–O coupling of alcohols

(2010) Andreas Weickgenannt et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

TBDPS and Br-TBDPS Protecting Groups as Efficient Aryl Group Donors in Pd-Catalyzed Arylation of Phenols and Anilines

(2009) Chunhui Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A 14-VE Platinum(0) Phosphabarrelene Complex in the Hydrosilylation of Alkynes

(2009) Matthias Blug et al.   ORGANOMETALLICS