Modular Synthesis of Ar-BINMOL-Phos for Catalytic Asymmetric Alkynylation of Aromatic Aldehydes with Unexpected Reversal of Enantioselectivity

Chiral Magnesium(II) Binaphtholates as Cooperative Brønsted/Lewis Acid-Base Catalysts for the Highly Enantioselective Addition of Phosphorus Nucleophiles to α,β-Unsaturated Esters and Ketones

(2013) Manabu Hatano et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperative Catalysis of Metal and OH⋅⋅⋅O/sp3-CH⋅⋅⋅O Two-Point Hydrogen Bonds in Alcoholic Solvents: Cu-Catalyzed Enantioselective Direct Alkynylation of Aldehydes with Terminal Alkynes

(2013) Takaoki Ishii et al.   CHEMISTRY-A EUROPEAN JOURNAL

Modulation of Multifunctional N,O,P Ligands for Enantioselective Copper-Catalyzed Conjugate Addition of Diethylzinc and Trapping of the Zinc Enolate

(2013) Fei Ye et al.   Chemistry-An Asian Journal

Catalytic Asymmetric Enyne Addition to Aldehydes and Rh(I)-Catalyzed Stereoselective Domino Pauson–Khand/[4 + 2] Cycloaddition

(2013) Wei Chen et al.   JOURNAL OF ORGANIC CHEMISTRY

New silver(I)–monophosphine complex derived from chiral Ar-BINMOL: synthesis and catalytic activity in asymmetric vinylogous Mannich reaction

(2013) Long-Sheng Zheng et al.   TETRAHEDRON

Chiral Ar-BINMOL-derived salan as fluorescent sensor for recognition of CuCl and cascade discrimination of α-amino acids

(2013) Fei Li et al.   TETRAHEDRON LETTERS

Aromatic Interactions as Control Elements in Stereoselective Organic Reactions

(2012) Elizabeth H. Krenske et al.   ACCOUNTS OF CHEMICAL RESEARCH

Enantiocontrolled Synthesis of Tertiary α-Hydroxy-α-ynyl Esters by Dimethylzinc-Mediated Addition of Alkynes to α-Keto Esters

(2012) Rebeca Infante et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Catalytic Alkynylation of Acetaldehyde: Application to the Synthesis of (+)-Tetrahydropyrenophorol

(2012) Barry M. Trost et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Hydrogenation of 2,4-Disubstituted 1,5-Benzodiazepines Using Cationic Ruthenium Diamine Catalysts: An Unusual Achiral Counteranion Induced Reversal of Enantioselectivity

(2012) Zi-Yuan Ding et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Effect of Multinuclear Copper/Aluminum Complexes in Highly Asymmetric Conjugate Addition of Trimethylaluminum to Acyclic Enones

(2012) Kohei Endo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Addition of 1,3-Diynes to Aldehydes Catalyzed by a Zinc-Amino Alcohol Complex

(2012) Bing Zheng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Development of Zn-ProPhenol-Catalyzed Asymmetric Alkyne Addition: Synthesis of Chiral Propargylic Alcohols

(2012) Barry M. Trost et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Chiral Cu-Salan Catalyst with a Rotatable Aromatic π-Wall: Molecular Recognition-Oriented Asymmetric Henry Transformation of Aromatic Aldehydes

(2012) Fei Li et al.   Chemistry-An Asian Journal

Synthesis of Ar-BINMOL Ligands by [1,2]-Wittig Rearrangement to Probe Their Catalytic Activity in 1,2-Addition Reactions of Aldehydes with Grignard Reagents

(2012) Long-Sheng Zheng et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Catalytic Asymmetric Addition of Alkyllithium Reagents to Aromatic Aldehydes

(2012) Emilio Fernández-Mateos et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Chiral-Anion-Dependent Inversion of Diastereo- and Enantioselectivity in Carbonyl Crotylation via Ruthenium-Catalyzed Butadiene Hydrohydroxyalkylation

(2012) Emma L. McInturff et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The effects of solvent on switchable stereoselectivity: copper-catalyzed asymmetric conjugate additions using D2-symmetric biphenyl phosphoramidite ligands

(2012) Han Yu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Multinuclear Cu-Catalysts Based on SPINOL-PHOS in Asymmetric Conjugate Addition of Organozinc Reagents

(2012) Kohei Endo et al.   ORGANIC LETTERS

One catalyst for both enantiomers: uncovering the inversion of enantioselectivity in cinchona-mediated desymmetrization of glutaric meso-anhydrides

(2012) Trpimir Ivšić et al.   TETRAHEDRON

Chiral sulfoxide–olefin ligands: tunable stereoselectivity in Rh-catalyzed asymmetric 1,4-additions

(2012) Guihua Chen et al.   TETRAHEDRON

A Lewis acid-promoted reduction of acylsilanes to α-hydroxysilanes by diethylzinc

(2012) Guang Gao et al.   TETRAHEDRON LETTERS

Catalytic enantioselective addition of organoaluminum reagents to aldehydes

(2012) Emilio Fernández-Mateos et al.   TETRAHEDRON-ASYMMETRY

An Achiral-Acid-Induced Switch in the Enantioselectivity of a Chiral cis-Diamine-Based Organocatalyst for Asymmetric Aldol and Mannich Reactions

(2011) Shin A. Moteki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Sulfoxide-Olefin Ligands: Completely Switchable Stereoselectivity in Rhodium-Catalyzed Asymmetric Conjugate Additions

(2011) Guihua Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Addition of Trimethylsilylacetylene to Aldehydes Catalyzed by a Zinc-Amino-Alcohol Complex

(2011) Zhi-Yuan Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Neighboring Lithium-Assisted [1,2]-Wittig Rearrangement: Practical Access to Diarylmethanol-Based 1,4-Diols and Optically Active BINOL Derivatives with Axial and sp3-Central Chirality

(2011) Guang Gao  et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Enantioselective Addition of MeMgBr and Other Grignard Reagents to Aldehydes

(2011) Emilio Fernández-Mateos et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Ar-BINMOLs with Axial and sp3 Central Chirality - Characterization, Chiroptical Properties, and Application in Asymmetric Catalysis

(2011) Guang Gao et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Switching of Enantioselectivity in the Catalytic Addition of Diethylzinc to Aldehydes by Regioisomeric Chiral 1,3-Amino Sulfonamide Ligands

(2011) Takuji Hirose et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Alkynylation of Aldehydes with 1-Haloalkynes Catalyzed by Tethered Bis(8-quinolinato) Chromium Complex

(2011) Dmitry L. Usanov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

From Highly Enantioselective Catalytic Reaction of 1,3-Diynes with Aldehydes to Facile Asymmetric Synthesis of Polycyclic Compounds

(2011) Mark Turlington et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand design for dual enantioselective control in Cu-catalyzed asymmetric conjugate addition of R2Zn to cyclic enone

(2011) Misato Yoshimura et al.   TETRAHEDRON

Chiral alkaline-earth metal catalysts for asymmetric bond-forming reactions

(2011) Yasuhiro Yamashita et al.   Chemical Science

Inversion of the Enantioselectivity in the Hydrogenation of (E)-2,3-diphenylpropenoic Acids over Pd Modified by Cinchonidine Silyl Ethers

(2011) György Szőllősi et al.   ACS Catalysis

Multinuclear Catalyst for Copper-Catalyzed Asymmetric Conjugate Addition of Organozinc Reagents

(2010) Kohei Endo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reversal of Enantioselectivity by Tuning the Conformational Flexibility of Phase-Transfer Catalysts

(2010) Ming-Qing Hua et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Iron-Catalyzed Hydrosilane Reduction of Ketones: Effect of Zinc Metal upon the Absolute Configuration

(2010) Tomohiko Inagaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unusual Reversal of Enantioselectivity in the Proline-Mediated α-Amination of Aldehydes Induced by Tertiary Amine Additives

(2010) Donna G. Blackmond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Direct Alkynylation Catalyzed by Chiral Ru−Bis(oxazolinyl)phenyl Complexes

(2010) Jun-ichi Ito et al.   ORGANIC LETTERS

Highly enantioselective addition of phenylethynylzinc to aldehydes using aziridine-functionalized tridentate sulfinyl ligands

(2010) Michał Rachwalski et al.   TETRAHEDRON-ASYMMETRY

Copper(I)-catalyzed enantioselective alkynylation of α-imino esters: ligand-to-metal ratio effects and mechanistic studies

(2010) Fangzhi Peng et al.   TETRAHEDRON-ASYMMETRY

Investigations of enantioreversal in both direct and directed enantioselective aldol reactions catalyzed by CuCl2[(−)-sparteine] and NiCl2[(−)-sparteine] complexes

(2010) H. Maheswaran et al.   TETRAHEDRON-ASYMMETRY

The Enantioselective Addition of Alkyne Nucleophiles to Carbonyl Groups

(2009) Barry M. Trost et al.   ADVANCED SYNTHESIS & CATALYSIS

Unexpected Inversions in Asymmetric Reactions: Reactions with Chiral Metal Complexes, Chiral Organocatalysts, and Heterogeneous Chiral Catalysts

(2009) Mihály Bartók   CHEMICAL REVIEWS

Highly Enantioselective Zinc/Amino Alcohol-Catalyzed Alkynylation of Aldehydes

(2009) Jiang-Chun Zhong et al.   CHEMISTRY-A EUROPEAN JOURNAL

3,3′-Anisyl-Substituted BINOL, H4BINOL, and H8BINOL Ligands: Asymmetric Synthesis of Diverse Propargylic Alcohols and Their Ring-Closing Metathesis to Chiral Cycloalkenes

(2009) Yang Yue et al.   JOURNAL OF ORGANIC CHEMISTRY

Invertible Enantioselectivity in 6′-Deoxy-6′-acylamino-β-isocupreidine-Catalyzed Asymmetric Aza-Morita−Baylis−Hillman Reaction: Key Role of Achiral Additive

(2009) Nacim Abermil et al.   ORGANIC LETTERS

AgAsF6/Sm(OTf)3Promoted Reversal of Enantioselectivity for the Asymmetric Friedel−Crafts Alkylations of Indoles with β,γ-Unsaturated α-Ketoesters

(2009) Yanling Liu et al.   ORGANIC LETTERS

Studies on highly regio- and stereoselective fluorohydroxylation reaction of 3-aryl-1,2-allenyl phosphine oxides with Selectfluor

(2009) Guangke He et al.   TETRAHEDRON

Highly enantioselective addition of terminal alkynes to aldehydes catalyzed by a new chiral β-sulfonamide alcohol/Ti(OiPr)4/Et2Zn/R3N catalyst system

(2008) Li Qiu et al.   CHIRALITY

Mechanistic Insights in the Reversal of Enantioselectivity of Chiral Catalysts by Achiral Catalysts in Asymmetric Autocatalysis

(2008) François Lutz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

π-Stacking Effect on Levoglucosenone Derived Internal Chiral Auxiliaries. A Case of Complete Enantioselectivity Inversion on the Diels−Alder Reaction

(2008) Ariel M. Sarotti et al.   ORGANIC LETTERS

Catalytic Asymmetric Alkynylation and Arylation of Aldehydes by an H8-Binaphthyl-Based Amino Alcohol Ligand

(2007) Jiwu Ruan et al.   ADVANCED SYNTHESIS & CATALYSIS

Reversal in enantioselectivity for the palladium-catalyzed asymmetric allylic substitution with novel metallocene-based planar chiral diphosphine ligands

(2007) Fang Xie et al.   TETRAHEDRON LETTERS