An Achiral-Acid-Induced Switch in the Enantioselectivity of a Chiral cis-Diamine-Based Organocatalyst for Asymmetric Aldol and Mannich Reactions

Acid controlled diastereoselectivity in asymmetric aldol reaction of cycloketones with aldehydes using enamine-based organocatalysts

(2011) Jinsuo Gao et al.   CHEMICAL COMMUNICATIONS

Diastereodivergent Asymmetric Sulfa-Michael Additions of α-Branched Enones using a Single Chiral Organic Catalyst

(2011) Xu Tian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dynamic Control of Chiral Space in a Catalytic Asymmetric Reaction Using a Molecular Motor

(2011) J. Wang et al.   SCIENCE

Reversal of Enantioselectivity by Tuning the Conformational Flexibility of Phase-Transfer Catalysts

(2010) Ming-Qing Hua et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Iron-Catalyzed Hydrosilane Reduction of Ketones: Effect of Zinc Metal upon the Absolute Configuration

(2010) Tomohiko Inagaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Solvent-Dependent Enantiodivergent Mannich-Type Reaction: Utilizing a Conformationally Flexible Guanidine/Bisthiourea Organocatalyst

(2010) Yoshihiro Sohtome et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Design of Structurally Rigidtrans-Diamine-Based Tf-Amide Organocatalysts with a Dihydroanthracene Framework for Asymmetric Conjugate Additions of Heterosubstituted Aldehydes to Vinyl Sulfones

(2010) Shin A. Moteki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Unusual Reversal of Enantioselectivity in the Proline-Mediated α-Amination of Aldehydes Induced by Tertiary Amine Additives

(2010) Donna G. Blackmond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Remarkable Levels of Enantioswitching in Catalytic Asymmetric Hydroboration

(2010) Sean M. Smith et al.   ORGANIC LETTERS

Reversal of Enantioselectivity between the Copper(I)- and Silver(I)-Catalyzed 1,3-Dipolar Cycloaddition Reactions Using a Brucine-Derived Amino Alcohol Ligand

(2009) Hun Young Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unexpected Inversions in Asymmetric Reactions: Reactions with Chiral Metal Complexes, Chiral Organocatalysts, and Heterogeneous Chiral Catalysts

(2009) Mihály Bartók   CHEMICAL REVIEWS

N-Primary-Amine-Terminal β-Turn Tetrapeptides as Organocatalysts for Highly Enantioselective Aldol Reaction

(2009) Feng-Chun Wu et al.   JOURNAL OF ORGANIC CHEMISTRY

Invertible Enantioselectivity in 6′-Deoxy-6′-acylamino-β-isocupreidine-Catalyzed Asymmetric Aza-Morita−Baylis−Hillman Reaction: Key Role of Achiral Additive

(2009) Nacim Abermil et al.   ORGANIC LETTERS

Chiral Organic Ion Pair Catalysts Assembled Through a Hydrogen-Bonding Network

(2009) D. Uraguchi et al.   SCIENCE

Inversion of enantioselectivity in quinine-mediated desymmetrization of glutaric meso-anhydrides

(2009) Trpimir Ivšić et al.   TETRAHEDRON-ASYMMETRY

Proline-Catalyzed Highly Enantioselective andanti-Selective Mannich Reaction of Unactivated Ketones: Synthesis of Chiral α-Amino Acids

(2008) Björn T. Hahn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lessons from Nature: Biomimetic Organocatalytic Carbon−Carbon Bond Formations§

(2008) Dieter Enders et al.   JOURNAL OF ORGANIC CHEMISTRY

Complete Switch of Product Selectivity in Asymmetric Direct Aldol Reaction with Two Different Chiral Organocatalysts from a Common Chiral Source

(2008) Keiji Nakayama et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY